Araştırma Makalesi
BibTex RIS Kaynak Göster
Yıl 2017, Cilt: 18 Sayı: 2, 507 - 520, 30.09.2017
https://doi.org/10.18038/aubtda.296523

Öz

Kaynakça

  • [1] Mark JE, Erman B, Eirich FR. Science and Technology of Rubber, 2nd Ed., Academic Press, New York, 1994; 339.
  • [2] Blow CM, Hepburn C. Rubber Technology and Manufacture, 2nd Ed., Butterworth Scientific, London, 1982.
  • [3] Nabil H, Ismail H, Azura AR. Compounding, mechanical and morphological properties of carbon-black-filled natural rubber/recycled ethylene-propylene-diene-monomer (NR/REPDM) blends. Polym Test 2013; 32: 385–393.
  • [4] Leblane JL. Rubber-filler interactions and rheological properties in filled compounds. Prog Polym Sci 2002; 27: 627-687.
  • [5] Hofmann W. Rubber Technology Handbook, Hanser Publishers, Germany, 1980.
  • [6] Morawetz H. History of Rubber Research. Rubber Chem Technol 2000; 73: 405–426.
  • [7] Alliger G, Sjothun ID. Vulcanization of elastomers, Reinhold Publishing Company, Reinhold 1965; 214.
  • [8] Sau KP, Chaki TK. Electrical and Mechanical Properties of conducting Carbon Black Filled Composites Based on Rubber and Rubber Blends J Appl Polym Sci 1999; 71: 887-895.
  • [9] Steven KH, Richard C. Fundamentals of Curing Elastomers with Peroxides and Coagents, Sartomer Company Inc., 2005.
  • [10] Likozar B, Krajnc M. Modeling the vulcanization of rubber blend. Macromol Symp 2006; 243: 104-113.
  • [11] Suzukı N, Ito N, Yatsuyanag F. Effect of Rubber / Filler Interactions on Deformation Behaviour of Silica Filled SBR Systems. Polymer 2005; 46: 193-201.
  • [12] Pal PK, De SK. Studies of Polymer-Filler Interaction, Network Structure, Physical Properties, and Fracture of Silica-and Clay-Filled EPDM Rubber in the Presence of a Silane Coupling Agent. Rubber Chem Technol 1983; 56: 737-773.
  • [13] Haisheng T, Avraam II. Comparative Study of Silica-, Nanoclay and Carbon Black-Filled EPDM Rubbers. J Appl Polym Sci 2008; 109: 767–774.
  • [14] Ismail H, Ishak S, Hamid ZAA. Comparison Effect of Mica and Talc as Filler in EPDM Composites on Curing, Tensile and Thermal Properties. Prog Rubber, Plast Recy Technol 2013; 29: 109-122.
  • [15] Siriwardena S, Ismail H, Ishiaku US. White Rice Husk Ash Filled Ethylene-Propylene-Diene Terpolymer/Polypropylene Blends: Effect of Dynamic Vulcanization and Filler Loading. Polym-Plast Technol Eng 2001; 40: 519–538.
  • [16] Siriwardena S, Ismail H, Ishiaku US, Perera MCS. Mechanical and Morphological Properties of White Rice Husk Ash Filled Polypropylene/Ethylene-Propylene-DieneTerpolymer Thermoplastic Elastomer Composites. J Appl Polym Sci 2002; 85: 438–453.
  • [17] Planes E, Chazeau L, Vigier G, Fournier J, Stevenson-Royaud I. Influence of fillers on mechanical properties of ATH filled EPDM during ageing by gamma irradiation. Polym Degrad Stabil 2010; 95: 1029-1038.
  • [18] Wazzan AA. Influence of Fillers and Curing Systems on the Physico-Mechanical Properties and Stability of EPDM Vulcanizates. Int J Polym Mater 2005; 54:783–794.
  • [19] Das A, De D, Naskar N, Debnath SC. Effect of Vulcanization Technique on the Physical Properties of Silica-Filled EPDM Rubber. J Appl Polym Sci 2006; 99: 1132–1139.
  • [20] Abtahi M, Bakhshandeh GR, Farahani TD. Effect of TAC (Triallyl Cyanorate) on Curing Characteristics and Mechanical Properties of Silica Filled EPDM Rubber. Polym-Plast Technol Eng 2006; 45: 183–189.
  • 21] Siriwardena S, Ismail H, Ishiaku US. Effect of mixing sequence in the preparation of white rice husk ash filled polypropylene/ethylene–propylene–diene monomer blend. Polym Test 2001; 20: 105–113.
  • [22] Nabil H, Ismail* H, Azura AR. Compounding, mechanical and morphological properties of carbon-black-filled natural rubber/recycled ethylenepropylene-diene-monomer (NR/R-EPDM) blends. Polym Test 2013; 32: 385–393.
  • [23] Siriwardena S, Ismail H, Ishiaku US. A comparison of white rice husk ash and silica as fillers in ethylene–propylene–diene terpolymer vulcanizates. Polym Int 2001; 50: 707-713.
  • [24] ASTM, Standard Test Methods for Rubber—Viscosity, Stress Relaxation, and Pre-Vulcanization Characteristics (Mooney Viscometer, In ASTM Annual Book of American Society for Testing and Materials Standards, Easton, MD, USA, D1646-15.
  • [25] ASTM , Standard Test Methods for Rubber Products—Chemical Analysis, , In ASTM Annual Book of American Society for Testing and Materials Standards, Easton, MD, USA, D297- 15.
  • [26] ASTM, Standard Test Method for Rubber Property—Abrasion Resistance (Rotary Drum Abrader), In ASTM Annual Book of Ame. Soc. for Testing and Materials Standards, Easton, MD, USA, D5963 - 15.
  • [27] ASTM, Standard Test Method for Rubber Property—Durometer Hardness, In ASTM Annual Book of American Society for Testing and Materials Standards, Easton, MD, USA, D2240 - 15.
  • [28] ASTM, Standard Test Methods for Vulcanized Rubber and Thermoplastic Elastomers_Tension , In ASTM Annual Book of American Society for Testing and Materials Standards, Easton, MD, USA, D412-15.
  • [29] Kang D, Kim D, Yoon SH, Kim D, Barry C, Mead J. Properties and Dispersion of EPDM/Modified-Organoclay Nanocomposites. Macromol Mater Eng 2007; 292: 329–338.
  • [30] Wu YP, Ma Y, Wang YQ, Zhang LQ. Effects of Characteristics of Rubber, Mixing and Vulcanization on the Structure and Properties of Rubber/Clay Nanocomposites by Melt Blending. Macromol Mater Eng 2004; 289: 890–894.
  • [31] Moldovan Z, Ionescu F, Vasilescu I, LiŃescu S, Radu GL. Characterization of Some Microstructured Polymer Blends By Mechanical Tests and ATR-FTIR Spectrometry. Analele UniversităŃii din Bucuresti – Chimie, Anul XVI (serie nouă) 2007; 1: 49 – 57.

PREPARATION AND CHARACTERIZATION OF EPDM RUBBER MIXTURE FOR A HEAT RESISTANT CONVEYOR BELT COVER

Yıl 2017, Cilt: 18 Sayı: 2, 507 - 520, 30.09.2017
https://doi.org/10.18038/aubtda.296523

Öz



In this paper, the
EPDM rubber-based dough recipe for a conveyor belt used in high temperature
conditions was developed. As a first step, the silica loading effect on the mechanical and rheological properties
was determined.  After selecting the
proper coating dough recipe, dough properties were investigated for filler
mica, instead of silica, and the influence of paraffinic oil was tested for
both silica and mica fillers. The properties of the EPDM rubber blend were
investigated with
rheometer
tests on the semi-finished materials and with mechanical and physical tests (tensile
strength, elongation at break, density, hardness, abrasion, heat ageing tests) on
the finished coating materials after a vulcanization process. Thermal
degradation behaviors of materials were analyzed by the thermal gravimetric analysis
(TGA) system, and determination of chemical structure was analyzed by Fourier
transform infrared spectroscopy (FTIR)
. The physico-mechanical
characteristics of EPDM rubber blends were increased with silica loadings.
EPDM rubber
demonstrates thermal resistance in the temperature range of 150oC –
160oC under normal conditions. As a result of the studies conducted,
the heat resistance of the coating rubber material was raised to 200oC
by adding silica and paraffinic oil with a higher flash point into the EPDM dough
mixture formulae.

Kaynakça

  • [1] Mark JE, Erman B, Eirich FR. Science and Technology of Rubber, 2nd Ed., Academic Press, New York, 1994; 339.
  • [2] Blow CM, Hepburn C. Rubber Technology and Manufacture, 2nd Ed., Butterworth Scientific, London, 1982.
  • [3] Nabil H, Ismail H, Azura AR. Compounding, mechanical and morphological properties of carbon-black-filled natural rubber/recycled ethylene-propylene-diene-monomer (NR/REPDM) blends. Polym Test 2013; 32: 385–393.
  • [4] Leblane JL. Rubber-filler interactions and rheological properties in filled compounds. Prog Polym Sci 2002; 27: 627-687.
  • [5] Hofmann W. Rubber Technology Handbook, Hanser Publishers, Germany, 1980.
  • [6] Morawetz H. History of Rubber Research. Rubber Chem Technol 2000; 73: 405–426.
  • [7] Alliger G, Sjothun ID. Vulcanization of elastomers, Reinhold Publishing Company, Reinhold 1965; 214.
  • [8] Sau KP, Chaki TK. Electrical and Mechanical Properties of conducting Carbon Black Filled Composites Based on Rubber and Rubber Blends J Appl Polym Sci 1999; 71: 887-895.
  • [9] Steven KH, Richard C. Fundamentals of Curing Elastomers with Peroxides and Coagents, Sartomer Company Inc., 2005.
  • [10] Likozar B, Krajnc M. Modeling the vulcanization of rubber blend. Macromol Symp 2006; 243: 104-113.
  • [11] Suzukı N, Ito N, Yatsuyanag F. Effect of Rubber / Filler Interactions on Deformation Behaviour of Silica Filled SBR Systems. Polymer 2005; 46: 193-201.
  • [12] Pal PK, De SK. Studies of Polymer-Filler Interaction, Network Structure, Physical Properties, and Fracture of Silica-and Clay-Filled EPDM Rubber in the Presence of a Silane Coupling Agent. Rubber Chem Technol 1983; 56: 737-773.
  • [13] Haisheng T, Avraam II. Comparative Study of Silica-, Nanoclay and Carbon Black-Filled EPDM Rubbers. J Appl Polym Sci 2008; 109: 767–774.
  • [14] Ismail H, Ishak S, Hamid ZAA. Comparison Effect of Mica and Talc as Filler in EPDM Composites on Curing, Tensile and Thermal Properties. Prog Rubber, Plast Recy Technol 2013; 29: 109-122.
  • [15] Siriwardena S, Ismail H, Ishiaku US. White Rice Husk Ash Filled Ethylene-Propylene-Diene Terpolymer/Polypropylene Blends: Effect of Dynamic Vulcanization and Filler Loading. Polym-Plast Technol Eng 2001; 40: 519–538.
  • [16] Siriwardena S, Ismail H, Ishiaku US, Perera MCS. Mechanical and Morphological Properties of White Rice Husk Ash Filled Polypropylene/Ethylene-Propylene-DieneTerpolymer Thermoplastic Elastomer Composites. J Appl Polym Sci 2002; 85: 438–453.
  • [17] Planes E, Chazeau L, Vigier G, Fournier J, Stevenson-Royaud I. Influence of fillers on mechanical properties of ATH filled EPDM during ageing by gamma irradiation. Polym Degrad Stabil 2010; 95: 1029-1038.
  • [18] Wazzan AA. Influence of Fillers and Curing Systems on the Physico-Mechanical Properties and Stability of EPDM Vulcanizates. Int J Polym Mater 2005; 54:783–794.
  • [19] Das A, De D, Naskar N, Debnath SC. Effect of Vulcanization Technique on the Physical Properties of Silica-Filled EPDM Rubber. J Appl Polym Sci 2006; 99: 1132–1139.
  • [20] Abtahi M, Bakhshandeh GR, Farahani TD. Effect of TAC (Triallyl Cyanorate) on Curing Characteristics and Mechanical Properties of Silica Filled EPDM Rubber. Polym-Plast Technol Eng 2006; 45: 183–189.
  • 21] Siriwardena S, Ismail H, Ishiaku US. Effect of mixing sequence in the preparation of white rice husk ash filled polypropylene/ethylene–propylene–diene monomer blend. Polym Test 2001; 20: 105–113.
  • [22] Nabil H, Ismail* H, Azura AR. Compounding, mechanical and morphological properties of carbon-black-filled natural rubber/recycled ethylenepropylene-diene-monomer (NR/R-EPDM) blends. Polym Test 2013; 32: 385–393.
  • [23] Siriwardena S, Ismail H, Ishiaku US. A comparison of white rice husk ash and silica as fillers in ethylene–propylene–diene terpolymer vulcanizates. Polym Int 2001; 50: 707-713.
  • [24] ASTM, Standard Test Methods for Rubber—Viscosity, Stress Relaxation, and Pre-Vulcanization Characteristics (Mooney Viscometer, In ASTM Annual Book of American Society for Testing and Materials Standards, Easton, MD, USA, D1646-15.
  • [25] ASTM , Standard Test Methods for Rubber Products—Chemical Analysis, , In ASTM Annual Book of American Society for Testing and Materials Standards, Easton, MD, USA, D297- 15.
  • [26] ASTM, Standard Test Method for Rubber Property—Abrasion Resistance (Rotary Drum Abrader), In ASTM Annual Book of Ame. Soc. for Testing and Materials Standards, Easton, MD, USA, D5963 - 15.
  • [27] ASTM, Standard Test Method for Rubber Property—Durometer Hardness, In ASTM Annual Book of American Society for Testing and Materials Standards, Easton, MD, USA, D2240 - 15.
  • [28] ASTM, Standard Test Methods for Vulcanized Rubber and Thermoplastic Elastomers_Tension , In ASTM Annual Book of American Society for Testing and Materials Standards, Easton, MD, USA, D412-15.
  • [29] Kang D, Kim D, Yoon SH, Kim D, Barry C, Mead J. Properties and Dispersion of EPDM/Modified-Organoclay Nanocomposites. Macromol Mater Eng 2007; 292: 329–338.
  • [30] Wu YP, Ma Y, Wang YQ, Zhang LQ. Effects of Characteristics of Rubber, Mixing and Vulcanization on the Structure and Properties of Rubber/Clay Nanocomposites by Melt Blending. Macromol Mater Eng 2004; 289: 890–894.
  • [31] Moldovan Z, Ionescu F, Vasilescu I, LiŃescu S, Radu GL. Characterization of Some Microstructured Polymer Blends By Mechanical Tests and ATR-FTIR Spectrometry. Analele UniversităŃii din Bucuresti – Chimie, Anul XVI (serie nouă) 2007; 1: 49 – 57.
Toplam 31 adet kaynakça vardır.

Ayrıntılar

Konular Mühendislik
Bölüm Araştırma Makalesi
Yazarlar

Alev Akpinar Borazan

Yayımlanma Tarihi 30 Eylül 2017
Yayımlandığı Sayı Yıl 2017 Cilt: 18 Sayı: 2

Kaynak Göster

APA Akpinar Borazan, A. (2017). PREPARATION AND CHARACTERIZATION OF EPDM RUBBER MIXTURE FOR A HEAT RESISTANT CONVEYOR BELT COVER. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, 18(2), 507-520. https://doi.org/10.18038/aubtda.296523
AMA Akpinar Borazan A. PREPARATION AND CHARACTERIZATION OF EPDM RUBBER MIXTURE FOR A HEAT RESISTANT CONVEYOR BELT COVER. AUBTD-A. Haziran 2017;18(2):507-520. doi:10.18038/aubtda.296523
Chicago Akpinar Borazan, Alev. “PREPARATION AND CHARACTERIZATION OF EPDM RUBBER MIXTURE FOR A HEAT RESISTANT CONVEYOR BELT COVER”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18, sy. 2 (Haziran 2017): 507-20. https://doi.org/10.18038/aubtda.296523.
EndNote Akpinar Borazan A (01 Haziran 2017) PREPARATION AND CHARACTERIZATION OF EPDM RUBBER MIXTURE FOR A HEAT RESISTANT CONVEYOR BELT COVER. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18 2 507–520.
IEEE A. Akpinar Borazan, “PREPARATION AND CHARACTERIZATION OF EPDM RUBBER MIXTURE FOR A HEAT RESISTANT CONVEYOR BELT COVER”, AUBTD-A, c. 18, sy. 2, ss. 507–520, 2017, doi: 10.18038/aubtda.296523.
ISNAD Akpinar Borazan, Alev. “PREPARATION AND CHARACTERIZATION OF EPDM RUBBER MIXTURE FOR A HEAT RESISTANT CONVEYOR BELT COVER”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering 18/2 (Haziran 2017), 507-520. https://doi.org/10.18038/aubtda.296523.
JAMA Akpinar Borazan A. PREPARATION AND CHARACTERIZATION OF EPDM RUBBER MIXTURE FOR A HEAT RESISTANT CONVEYOR BELT COVER. AUBTD-A. 2017;18:507–520.
MLA Akpinar Borazan, Alev. “PREPARATION AND CHARACTERIZATION OF EPDM RUBBER MIXTURE FOR A HEAT RESISTANT CONVEYOR BELT COVER”. Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering, c. 18, sy. 2, 2017, ss. 507-20, doi:10.18038/aubtda.296523.
Vancouver Akpinar Borazan A. PREPARATION AND CHARACTERIZATION OF EPDM RUBBER MIXTURE FOR A HEAT RESISTANT CONVEYOR BELT COVER. AUBTD-A. 2017;18(2):507-20.