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Plazma Sprey Yöntemiyle AISI 304 Paslanmaz Çelik Üzerinde Üretilen Ti3SiC2 MAX Fazlı Kaplamanın Karakterizasyonu

Yıl 2019, Cilt: 8 Sayı: 1, 206 - 213, 12.03.2019
https://doi.org/10.17798/bitlisfen.453085

Öz

Bu çalışmada, plazma sprey yöntemi ile AISI 304
paslanmaz çelik üzerinde üretilen Ti3SiC2 MAX fazlı
kaplamanın mikroyapı, aşınma ve korozyon özellikleri araştırılmıştır. Ti3SiC2
fazını üretmek için başlangıç malzemesi olarak Ti ve SiC tozları
kullanılmıştır. Ti tozuna ağırlıkça 35 SiC ilave edildikten sonra elde edilen
toz karışımı atmosfer kontrollü plazma sprey tabancası ile alt tabaka üzerine
kaplanmıştır. Kaplamanın mikroyapı ve faz oluşumunu incelemek için optik
mikroskop, taramalı elektron mikroskobu ve XRD kullanılmıştır. Mikroyapı
incelemeleri kaplama mikroyapısının lamelli bir yapıya sahip olduğunu göstermiştir.
XRD analizlerine göre Ti3SiC2 MAX fazı kaplama
tabakasında tespit edilmiştir. Mikrosertlikler, kaplama tabakasından alt
tabakaya doğru bir hat boyunca ölçülmüştür. Kaplama ve alt malzemenin aşınma
özellikleri, çizik testi ile tespit edilmiştir. Kaplama tabakasının sürtünme
katsayısı alt malzemeye göre düşük çıkmıştır. Alt malzeme ve kaplamanın
korozyon özellikleri %3,5 NaCl çözeltisinde potansiyodinamik ölçümler yapılarak
belirlenmiştir. Korozyon sonuçları, kaplama tabakasının alt malzemeye göre 3,5
katlık bir korozyon direncine sahip olduğunu göstermiştir. 

Kaynakça

  • 1. Barsoum M. W. 2000. The MN+1AXN phases: A new class of solids: Thermodynamically stable nanolaminates. Progress in Solid State Chemistry, 28: 201-281. 2. Sun Z.M., Hashimoto H., Zhang Z.F., Yang S.L., Tada S., 2006. Synthesis and Characterization of a Metallic Ceramic Material--Ti3SiC2. Materials Transactions, 47(01): 170-174.
  • 3. Amini S., Ni C., Barsoum M.W., 2009. Processing, microstructural characterization and mechanical properties of a Ti2AlC/nanocrystalline Mg-matrix composite. Composites Science and Technology, 69(3–4): 414-420.
  • 4. Palmquist J.P., Li S., Persson P.O.A., Emmerlich J., Wilhelmsson O., Hogberg H., Katsnelson M.I., Johansson B., Ahuja R., Eriksson O., Hultman L., Jansson U., 2004. Mn+1AXn phases in the Ti-Si-C system studied by thin-film synthesis and ab initio calculations. Phys. Rev. B, 70(16): 165401-1-165401-13.
  • 5. Lin Z., Zhuo M., Zhou Y., Li M., Wang J., 2006. Microstructures and Theoretical Bulk Modulus of Layered Ternary Tantalum Aluminum Carbides. Journal of the American Ceramic Society, 89: 3765–3769.
  • 6. Bouhemadou A., 2009. Structural, electronic and elastic properties of MAX phases M2GaN (M=Ti, V and Cr). Solid State Sciences, 11(11): 1875-1881.
  • 7. Music D., Sun Z., Schneider J.M., 2005. Electronic structure of Sc2AC (A=Al, Ga, In, Tl). Solid State Communications, 133(6): 381-383.
  • 8. Music D., Sun Z., Voevodin A.A., Schneider J.M., 2006. Electronic structure and shearing in nanolaminated ternary carbides. Solid State Communications, 139(4): 139-143.
  • 9. Bouhemadou A., Khenata R., Chegaar M., 2007. Structural and elastic properties of Zr2AlX and Ti2AlX (X = C and N) under pressure effect. The European Physical Journal B, 56(3): 209-215.
  • 10. Bouhemadou A., 2008. Prediction study of structural and elastic properties under pressure effect of M2SnC (M=Ti, Zr, Nb, Hf). Physica B: Condensed Matter, 403(17): 2707-2713..
  • 11. Sun Z.M., Yang S., Hashimoto H., Tada S., Abe T., 2004. Synthesis and Consolidation of Ternary Compound Ti3SiC2 from Green Compact of Mixed Powders. Materials Transactions, 45(2): 373–375.
  • 12. Li C.J., Yang G.J., Ohmori A., 2006. Relationship between particle erosion and lamellar microstructure for plasma-sprayed alumina coatings. Wear, 260: 1166-1172.
  • 13. Lee C.H., Kim H.K., Choi H.S., Ahn H.S., 2000. Phase transformation and bond coat oxidation behavior of plasma-sprayed zirconia thermal barrier coating. Surface and Coatings Technology, 124, 1-12.
  • 14. Heimann R.B., 1996. Plasma-spray coating, VCH, New York.
  • 15. Pawlowski L., 2008. The science and engineering of thermal spray coatings. John Wiley & Sons, Ltd., England.
  • 16. Yılmaz R., Kurt A.O., Demir A., Tatlı Z., 2007. Effects of TiO2 on the Mechanical Properties of the Al2O3-TiO2 Plasma Sprayed Coating. Journal of the European Ceramic Society, 27: 1319-1323.
  • 17. EI-Raghy T., Barsoum M.W., 1999. Processing and Mechanical Properties of Ti3SiC2: I, Reaction Path and Microstructure Evolution. J. Am. Ceram Soc., 82(10): 2849–2854.
  • 18. Kosolapova T.Y., 1990. Handbook of High Temperature Compounds: Properties, Production, Applications, Hemisphere Publishing Corp., New York
  • 19. Sun Z.M., Zhang Z.F., Hashimoto H., Abe T., 2002. Ternary Compound Ti3SiC2: Part I. Pulse Discharge Sintering Synthesis. Materials Transactions, 43(3): 428-431.
  • 20. Stern M., Geary A. L., 1957. Electrochemical Polarization I . A Theoretical Analysis of the Shape of Polarization Curves. Journal of the Electrochemical Society, 104: 56-63.
  • 21. Sun J., Fu Q. G., Guo L. P., Liu Y., Huo C. X., Li H. J., 2016. Effect of filler on the oxidation protective ability of MoSi2 coating for Mo substrate by halide activated pack cementation. Materials & Design 92, 602-609.
  • 22. Bakhsheshi-Rad H. R., Hamzah E., Ismail A. F., Daroonparvar M., Yajid M. A. M., Medraj M., 2016. Preparation and characterization of NiCrAlY/nano-YSZ/PCL composite coatings obtained by combination of atmospheric plasma spraying and dip coating on Mg–Ca alloy Journal of Alloys and Compounds, 658: 440-452.
Yıl 2019, Cilt: 8 Sayı: 1, 206 - 213, 12.03.2019
https://doi.org/10.17798/bitlisfen.453085

Öz

Kaynakça

  • 1. Barsoum M. W. 2000. The MN+1AXN phases: A new class of solids: Thermodynamically stable nanolaminates. Progress in Solid State Chemistry, 28: 201-281. 2. Sun Z.M., Hashimoto H., Zhang Z.F., Yang S.L., Tada S., 2006. Synthesis and Characterization of a Metallic Ceramic Material--Ti3SiC2. Materials Transactions, 47(01): 170-174.
  • 3. Amini S., Ni C., Barsoum M.W., 2009. Processing, microstructural characterization and mechanical properties of a Ti2AlC/nanocrystalline Mg-matrix composite. Composites Science and Technology, 69(3–4): 414-420.
  • 4. Palmquist J.P., Li S., Persson P.O.A., Emmerlich J., Wilhelmsson O., Hogberg H., Katsnelson M.I., Johansson B., Ahuja R., Eriksson O., Hultman L., Jansson U., 2004. Mn+1AXn phases in the Ti-Si-C system studied by thin-film synthesis and ab initio calculations. Phys. Rev. B, 70(16): 165401-1-165401-13.
  • 5. Lin Z., Zhuo M., Zhou Y., Li M., Wang J., 2006. Microstructures and Theoretical Bulk Modulus of Layered Ternary Tantalum Aluminum Carbides. Journal of the American Ceramic Society, 89: 3765–3769.
  • 6. Bouhemadou A., 2009. Structural, electronic and elastic properties of MAX phases M2GaN (M=Ti, V and Cr). Solid State Sciences, 11(11): 1875-1881.
  • 7. Music D., Sun Z., Schneider J.M., 2005. Electronic structure of Sc2AC (A=Al, Ga, In, Tl). Solid State Communications, 133(6): 381-383.
  • 8. Music D., Sun Z., Voevodin A.A., Schneider J.M., 2006. Electronic structure and shearing in nanolaminated ternary carbides. Solid State Communications, 139(4): 139-143.
  • 9. Bouhemadou A., Khenata R., Chegaar M., 2007. Structural and elastic properties of Zr2AlX and Ti2AlX (X = C and N) under pressure effect. The European Physical Journal B, 56(3): 209-215.
  • 10. Bouhemadou A., 2008. Prediction study of structural and elastic properties under pressure effect of M2SnC (M=Ti, Zr, Nb, Hf). Physica B: Condensed Matter, 403(17): 2707-2713..
  • 11. Sun Z.M., Yang S., Hashimoto H., Tada S., Abe T., 2004. Synthesis and Consolidation of Ternary Compound Ti3SiC2 from Green Compact of Mixed Powders. Materials Transactions, 45(2): 373–375.
  • 12. Li C.J., Yang G.J., Ohmori A., 2006. Relationship between particle erosion and lamellar microstructure for plasma-sprayed alumina coatings. Wear, 260: 1166-1172.
  • 13. Lee C.H., Kim H.K., Choi H.S., Ahn H.S., 2000. Phase transformation and bond coat oxidation behavior of plasma-sprayed zirconia thermal barrier coating. Surface and Coatings Technology, 124, 1-12.
  • 14. Heimann R.B., 1996. Plasma-spray coating, VCH, New York.
  • 15. Pawlowski L., 2008. The science and engineering of thermal spray coatings. John Wiley & Sons, Ltd., England.
  • 16. Yılmaz R., Kurt A.O., Demir A., Tatlı Z., 2007. Effects of TiO2 on the Mechanical Properties of the Al2O3-TiO2 Plasma Sprayed Coating. Journal of the European Ceramic Society, 27: 1319-1323.
  • 17. EI-Raghy T., Barsoum M.W., 1999. Processing and Mechanical Properties of Ti3SiC2: I, Reaction Path and Microstructure Evolution. J. Am. Ceram Soc., 82(10): 2849–2854.
  • 18. Kosolapova T.Y., 1990. Handbook of High Temperature Compounds: Properties, Production, Applications, Hemisphere Publishing Corp., New York
  • 19. Sun Z.M., Zhang Z.F., Hashimoto H., Abe T., 2002. Ternary Compound Ti3SiC2: Part I. Pulse Discharge Sintering Synthesis. Materials Transactions, 43(3): 428-431.
  • 20. Stern M., Geary A. L., 1957. Electrochemical Polarization I . A Theoretical Analysis of the Shape of Polarization Curves. Journal of the Electrochemical Society, 104: 56-63.
  • 21. Sun J., Fu Q. G., Guo L. P., Liu Y., Huo C. X., Li H. J., 2016. Effect of filler on the oxidation protective ability of MoSi2 coating for Mo substrate by halide activated pack cementation. Materials & Design 92, 602-609.
  • 22. Bakhsheshi-Rad H. R., Hamzah E., Ismail A. F., Daroonparvar M., Yajid M. A. M., Medraj M., 2016. Preparation and characterization of NiCrAlY/nano-YSZ/PCL composite coatings obtained by combination of atmospheric plasma spraying and dip coating on Mg–Ca alloy Journal of Alloys and Compounds, 658: 440-452.
Toplam 21 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Bölüm Araştırma Makalesi
Yazarlar

Serkan Islak

Cihan Özorak

Özkan Eski

Yayımlanma Tarihi 12 Mart 2019
Gönderilme Tarihi 13 Ağustos 2018
Kabul Tarihi 30 Ekim 2018
Yayımlandığı Sayı Yıl 2019 Cilt: 8 Sayı: 1

Kaynak Göster

IEEE S. Islak, C. Özorak, ve Ö. Eski, “Plazma Sprey Yöntemiyle AISI 304 Paslanmaz Çelik Üzerinde Üretilen Ti3SiC2 MAX Fazlı Kaplamanın Karakterizasyonu”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, c. 8, sy. 1, ss. 206–213, 2019, doi: 10.17798/bitlisfen.453085.



Bitlis Eren Üniversitesi
Fen Bilimleri Dergisi Editörlüğü

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