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Year 2025, Volume: 10 Issue: 1, 403 - 417, 01.04.2025

Kadhim Makki Naser , Awatif Hameed Dadoosh , Shireen Mudhafar Ali Alkhalil

https://doi.org/10.28978/nesciences.1651183

Abstract

References

  • Al-Abdullah, O., & Al-Qudour, M. B. (2013). Removal of cadmium from solution using soft phosphate rock under dynamic system conditions. Jordanian Journal of Agricultural Sciences. 9(3).
  • Al-Awsi, W. S. A., & Aliwi, I. A. (2015). Adsorption and release of lead and cadmium in calcareous soils treated with used engine oils. Al-Qadisiyah Journal of Agricultural Sciences. 1(5).
  • Aldaini, L. J. K., & Naser, K. M. (2020). Evaluation Of the Efficiency of Some Mineralogical and Organic Materials to Remove Some Heavy Metals from Contaminated Soil. Plant Archives, 20(1), 915-921.
  • Al-Dayni, L. J. K., & Al-Azzawi K. M. N. (2019). Evaluation of the efficiency of some organic and mineral materials in reducing the accumulation of some heavy metals in the soil and growth of corn (Zea mays L). Iraqi Journal of Soil Sciences. 19(1).
  • Al-Jatlawi, Al-B. A., & Hadid, H. A. (2017). The effect of some heavy metals on biological properties of some fish species on shore of Misurata city, Libya, Academy of Graduate Studies - Misurata Branch. 72-1
  • AL-Rubaie, I. M. R., Dadoosh, A. H., & Nasser, K. M. (2022). Adsorption of Phosphorous and Zinc, and their interaction and processing power on Bentonite. Iranian Journal of Ichthyology, 9, 250-257.
  • Anzeze, D. A., Onyari, J. M., Shiundu, P. M., & Gichuki, J. W. (2014). Adsorption of Pb (II) ions from aqueous solutions by water hyacinth (Eichhornia crassipes): equilibrium and kinetic studies. International Journal of Environmental Pollution and Remediation (IJEPR), 2(1), 89-95.
  • Asrari, E., & Rezaee, A. R. (2023). Cadmium removal from industrial sewage by using Bentonite and Kaolinite absorbent gravels. EQA-International Journal of Environmental Quality, 54, 36-40.
  • Awda, M. M. (2018). Use of white radish and carrot plants in bioremediation of soil contaminated with some heavy metals. Master's thesis, College of Agriculture, University of Baghdad.
  • Balaid, W. N., Al-Ahar, R. A., Saleh, H. M. B., & Nabil, M. (2019). Estimation of level of lead, cadmium and iron in shawarma in some areas of Tripoli city. Journal of Applied Sciences, 1, 107-120.
  • Dhar, A. K., Himu, H. A., Bhattacharjee, M., Mostufa, M. G., & Parvin, F. (2023). Insights on applications of bentonite clays for the removal of dyes and heavy metals from wastewater: a review. Environmental Science and Pollution Research, 30(3), 5440-5474.
  • Etuk, H. S., Ebong, G. A., Ekot, A. E., Ekpo, B. O., & Ayi, A. A. (2024). Mineral and elemental compositions of suspended particulate matter (SPM) and sediments from major rivers in the Southeastern Nigeria. International Journal of Aquatic Research and Environmental Studies, 4(1), 71-89. http://doi.org/10.70102/IJARES/V4I1/7
  • Hamil, G., Abdel S. K., Al-Orfali, H. (2016). Study of concentration of heavy metals in gourd fruit, Faculty of Science, Sabha University, 8.
  • Harbuzaru, B. (2003). Preparation de Structurants Organiques Et Leur Engagement En Synthese Hydrothermale De Zeolithes (Doctoral dissertation, Université de Haute Alsace-Mulhouse). France. 15-28.
  • Hassoon, H. A., & Najem, A. M. (2017). Removal of some trace’s heavy metals from aqueous solutions by water Hyacinth leaves powder. Iraqi Journal of Science, 611-618.
  • Ibrahem, H. S., & Naser, K. M. (2020). Sequential extraction of zinc and nickel elements in contaminated soils. Plant Archives (09725210), 20(1), 320-324.
  • Khan, W. U. D., Wei, X., Ali, H. H., Zulfiqar, F., Chen, J., Iqbal, R., ... & El Sabagh, A. (2022). Investigating the role of bentonite clay with different soil amendments to minimize the bioaccumulation of heavy metals in Solanum melongena L. under the irrigation of tannery wastewater. Frontiers in Plant Science, 13, 958978. https://doi.org/10.3389/fpls.2022.958978
  • Lei, Z., Xu, S. T., Monreal, C. M., Mclaughlin, N. B., Zhao, B. P., Liu, J. H., & Hao, G. C. (2022). Bentonite-humic acid improves soil organic carbon, microbial biomass, enzyme activities and grain quality in a sandy soil cropped to maize (Zea mays L.) in a semi-arid region. Journal of Integrative Agriculture, 21(1), 208-221.
  • Lu, X., Kruatrachue, M., Pokethitiyook, P., & Homyok, K. (2004). Removal of cadmium and zinc by water hyacinth, Eichhornia crassipes. Science asia, 30(93), 103.
  • Mahdiraji, E. A., & Ramezani, N. (2019). The Influences of Soil Ionization in the Grounding System and Corona Phenomena on the Injection Lightning Current of 1000 KV UHV Transmission Line. International Academic Journal of Science and Engineering, 6(1),39–50. https://doi.org/10.9756/IAJSE/V6I1/1910004
  • Maleki, S., & Karimi-Jashni, A. (2017). Effect of ball milling process on the structure of local clay and its adsorption performance for Ni (II) removal. Applied clay science, 137, 213-224.
  • Manahan, S. E. (2002). Toxicological chemistry and biochemistry. CRC Press.
  • Mignardi, S., Corami, A., & Ferrini, V. (2012). Evaluation of the effectiveness of phosphate treatment for the remediation of mine waste soils contaminated with Cd, Cu, Pb, and Zn. Chemosphere, 86(4), 354-360.
  • Mitchell, J. K., & Soga, K. (2005). Fundamentals of soil behavior (Vol. 3, p. 558). New York: John Wiley & Sons.
  • Naser, K. M., Shref, A. M., & Kudher, M. F. (2020). The effect of adding some organic and mineral substances to calcareous soil on adsorption and desorption of copper and its removal efficiency from soil. Plant Archives, 20(1), 549-555.
  • Nezamzadeh-Ejhieh, A., & Amiri, M. (2013). CuO supported Clinoptilolite towards solar photocatalytic degradation of p-aminophenol. Powder Technology, 235, 279-288.
  • Ofiera, L. M., Bose, P., & Kazner, C. (2024). Removal of heavy metals and bulk organics towards application in modified constructed wetlands using activated carbon and zeolites. Water, 16(3), 511.
  • Salkić, Z., Lugović, B., & Babajić, E. (2020). Petrography and mineral chemistry of oligocene shoshonitic dacites from the central Bosnia. Archives for Technical Sciences, 1(22), 1–10.
  • Shamsham, S., & Al-Sabai, A. (2017). Study of the possibility of applying Freundlich and Langmuir equations to adsorption of zinc and copper elements on zeolite. Al-Baath University Journal. 39(21).
  • Shubber, M. D., & Kebria, D. Y. (2023). Thermal recycling of bentonite waste as a novel and a low-cost adsorbent for heavy metals removal. Journal of ecological engineering, 24(5).
  • Supriyadi, S., Rahman, F. A., Yuhardi, E., & Umam, C. (2023). Serapan N, P, dan K pada jagung Madura-3 di tanah lempung liat berpasir diameliorasi biochar dan bentonit-teraktivasi asam. Jurnal Tanah dan Sumberdaya Lahan, 10(2), 185-190.
  • Talib, N. N. (2023). Comparison of some ornamental plants in technology of bioreclamation of soils contaminated with some heavy metals (Pb, Cd and Ni). Master's thesis. College of Agricultural Engineering Sciences. University of Baghdad.
  • Trgo, M., & Vukojević-medvidović, N. (2005). The effect of concentration and pH on selectivity of ion exchange in system natural zeolite—Na+/Zn2+ aqueous solutions. In Studies in Surface Science and Catalysis (Vol. 158, pp. 1051-1056). Elsevier.
  • Tunguz, V., Petrović, B., Malešević, Z., & Petronić, S. (2019). Soil and radionuclides of Eastern Herzegovina. Archives for Technical Sciences, 1(20), 87–92.
  • Vij, P., & Prashant, P. M. (2024). Analyzing Soil Pollution by Image Processing and Machine Learning at Contaminated Agricultural Field. Natural and Engineering Sciences, 9(2), 335-346. https://doi.org/10.28978/nesciences.1575484
  • Zhao, Z., Jiang, G., & Mao, R. (2014). Effects of particle sizes of rock phosphate on immobilizing heavy metals in lead zinc mine soils. Journal of soil science and plant nutrition, 14(2), 258-266.

Comparison of Some Soil Mineral’s Ability to Adsorb and Release Lead and Rates of its Removal From its Aqueous Solutions

Year 2025, Volume: 10 Issue: 1, 403 - 417, 01.04.2025

Kadhim Makki Naser , Awatif Hameed Dadoosh , Shireen Mudhafar Ali Alkhalil

https://doi.org/10.28978/nesciences.1651183

Abstract

To study the comparative use of some soil minerals (zeolite, bentonite, phosphate rock, and limestone) in the adsorption and release of lead and its removal rates from its aqueous solutions using adsorption equations. Two laboratory experiments were carried out for the adsorption and release of lead. The adsorption experiment took 0.5 g of some of the above soil minerals. Lead was added as Pb (NO3)2 at levels of 3.0, 2.0, 1.5, 1.0, 0.5, and 0.0 mmol L-1 containing a concentration of 0.01M of calcium chloride. The experimental unit’s number was 72, the concentration of dissolved lead in the equilibrium solution was estimated and the amount of lead adsorbed was calculated. As for the lead release experiment, samples for the adsorption experiment were treated after separating filtrates from them with a calcium chloride solution with a concentration of 0.01 M. The amount of lead released was estimated. The percentage of lead removal was calculated. Results showed an increased concentration of dissolved lead in the equilibrium solution directly with increased levels of lead added to all materials. Materials were graded in concentrations of dissolved, adsorbed lead and values of maximum adsorption capacity of lead on different soil minerals surfaces as follows: zeolite > bentonite > phosphate rock > limestone, which reached 5000, 384.61, 769.23, and 2500 mg Pb kg-1, respectively. Binding energy was 0.0062, 0.0056, 0.0019, and 0.0049 L g-1, respectively. The amount of lead released from different adsorption materials varied, with the largest amount released in zeolite amounting to 322.10, 528.20, 696.90, 777.20, and 967.40 mg Pb kg-1 zeolite then bentonite, quantity reached 187.2, 272.8, 314.2, 324.0, and 375.6 mg Pb kg-1 bentonite, then phosphate rock, concentrations reached 65.80, 69.80, 77.60, 91.00, and 123.00 mg Pb kg-1 phosphate rock. Limestone came in fourth and last place in terms of the amount of lead released, concentrations were 25.10, 29.30, 35.00, 38.70, and 40.90 mg Pb L-1 for lead addition treatments of 0.5, 1.0, 1.5, 2.0 and 3.0 mmol L-1, respectively. Soil minerals used varied in their efficiency in removing lead from its aqueous solutions. Zeolite came in first place. Removal rate of lead reached 180.69%, then bentonite 95.47%, phosphate rock 18.48%, and finally limestone 58%.

Keywords

Some soil minerals Lead Adsorption and release

References

  • Al-Abdullah, O., & Al-Qudour, M. B. (2013). Removal of cadmium from solution using soft phosphate rock under dynamic system conditions. Jordanian Journal of Agricultural Sciences. 9(3).
  • Al-Awsi, W. S. A., & Aliwi, I. A. (2015). Adsorption and release of lead and cadmium in calcareous soils treated with used engine oils. Al-Qadisiyah Journal of Agricultural Sciences. 1(5).
  • Aldaini, L. J. K., & Naser, K. M. (2020). Evaluation Of the Efficiency of Some Mineralogical and Organic Materials to Remove Some Heavy Metals from Contaminated Soil. Plant Archives, 20(1), 915-921.
  • Al-Dayni, L. J. K., & Al-Azzawi K. M. N. (2019). Evaluation of the efficiency of some organic and mineral materials in reducing the accumulation of some heavy metals in the soil and growth of corn (Zea mays L). Iraqi Journal of Soil Sciences. 19(1).
  • Al-Jatlawi, Al-B. A., & Hadid, H. A. (2017). The effect of some heavy metals on biological properties of some fish species on shore of Misurata city, Libya, Academy of Graduate Studies - Misurata Branch. 72-1
  • AL-Rubaie, I. M. R., Dadoosh, A. H., & Nasser, K. M. (2022). Adsorption of Phosphorous and Zinc, and their interaction and processing power on Bentonite. Iranian Journal of Ichthyology, 9, 250-257.
  • Anzeze, D. A., Onyari, J. M., Shiundu, P. M., & Gichuki, J. W. (2014). Adsorption of Pb (II) ions from aqueous solutions by water hyacinth (Eichhornia crassipes): equilibrium and kinetic studies. International Journal of Environmental Pollution and Remediation (IJEPR), 2(1), 89-95.
  • Asrari, E., & Rezaee, A. R. (2023). Cadmium removal from industrial sewage by using Bentonite and Kaolinite absorbent gravels. EQA-International Journal of Environmental Quality, 54, 36-40.
  • Awda, M. M. (2018). Use of white radish and carrot plants in bioremediation of soil contaminated with some heavy metals. Master's thesis, College of Agriculture, University of Baghdad.
  • Balaid, W. N., Al-Ahar, R. A., Saleh, H. M. B., & Nabil, M. (2019). Estimation of level of lead, cadmium and iron in shawarma in some areas of Tripoli city. Journal of Applied Sciences, 1, 107-120.
  • Dhar, A. K., Himu, H. A., Bhattacharjee, M., Mostufa, M. G., & Parvin, F. (2023). Insights on applications of bentonite clays for the removal of dyes and heavy metals from wastewater: a review. Environmental Science and Pollution Research, 30(3), 5440-5474.
  • Etuk, H. S., Ebong, G. A., Ekot, A. E., Ekpo, B. O., & Ayi, A. A. (2024). Mineral and elemental compositions of suspended particulate matter (SPM) and sediments from major rivers in the Southeastern Nigeria. International Journal of Aquatic Research and Environmental Studies, 4(1), 71-89. http://doi.org/10.70102/IJARES/V4I1/7
  • Hamil, G., Abdel S. K., Al-Orfali, H. (2016). Study of concentration of heavy metals in gourd fruit, Faculty of Science, Sabha University, 8.
  • Harbuzaru, B. (2003). Preparation de Structurants Organiques Et Leur Engagement En Synthese Hydrothermale De Zeolithes (Doctoral dissertation, Université de Haute Alsace-Mulhouse). France. 15-28.
  • Hassoon, H. A., & Najem, A. M. (2017). Removal of some trace’s heavy metals from aqueous solutions by water Hyacinth leaves powder. Iraqi Journal of Science, 611-618.
  • Ibrahem, H. S., & Naser, K. M. (2020). Sequential extraction of zinc and nickel elements in contaminated soils. Plant Archives (09725210), 20(1), 320-324.
  • Khan, W. U. D., Wei, X., Ali, H. H., Zulfiqar, F., Chen, J., Iqbal, R., ... & El Sabagh, A. (2022). Investigating the role of bentonite clay with different soil amendments to minimize the bioaccumulation of heavy metals in Solanum melongena L. under the irrigation of tannery wastewater. Frontiers in Plant Science, 13, 958978. https://doi.org/10.3389/fpls.2022.958978
  • Lei, Z., Xu, S. T., Monreal, C. M., Mclaughlin, N. B., Zhao, B. P., Liu, J. H., & Hao, G. C. (2022). Bentonite-humic acid improves soil organic carbon, microbial biomass, enzyme activities and grain quality in a sandy soil cropped to maize (Zea mays L.) in a semi-arid region. Journal of Integrative Agriculture, 21(1), 208-221.
  • Lu, X., Kruatrachue, M., Pokethitiyook, P., & Homyok, K. (2004). Removal of cadmium and zinc by water hyacinth, Eichhornia crassipes. Science asia, 30(93), 103.
  • Mahdiraji, E. A., & Ramezani, N. (2019). The Influences of Soil Ionization in the Grounding System and Corona Phenomena on the Injection Lightning Current of 1000 KV UHV Transmission Line. International Academic Journal of Science and Engineering, 6(1),39–50. https://doi.org/10.9756/IAJSE/V6I1/1910004
  • Maleki, S., & Karimi-Jashni, A. (2017). Effect of ball milling process on the structure of local clay and its adsorption performance for Ni (II) removal. Applied clay science, 137, 213-224.
  • Manahan, S. E. (2002). Toxicological chemistry and biochemistry. CRC Press.
  • Mignardi, S., Corami, A., & Ferrini, V. (2012). Evaluation of the effectiveness of phosphate treatment for the remediation of mine waste soils contaminated with Cd, Cu, Pb, and Zn. Chemosphere, 86(4), 354-360.
  • Mitchell, J. K., & Soga, K. (2005). Fundamentals of soil behavior (Vol. 3, p. 558). New York: John Wiley & Sons.
  • Naser, K. M., Shref, A. M., & Kudher, M. F. (2020). The effect of adding some organic and mineral substances to calcareous soil on adsorption and desorption of copper and its removal efficiency from soil. Plant Archives, 20(1), 549-555.
  • Nezamzadeh-Ejhieh, A., & Amiri, M. (2013). CuO supported Clinoptilolite towards solar photocatalytic degradation of p-aminophenol. Powder Technology, 235, 279-288.
  • Ofiera, L. M., Bose, P., & Kazner, C. (2024). Removal of heavy metals and bulk organics towards application in modified constructed wetlands using activated carbon and zeolites. Water, 16(3), 511.
  • Salkić, Z., Lugović, B., & Babajić, E. (2020). Petrography and mineral chemistry of oligocene shoshonitic dacites from the central Bosnia. Archives for Technical Sciences, 1(22), 1–10.
  • Shamsham, S., & Al-Sabai, A. (2017). Study of the possibility of applying Freundlich and Langmuir equations to adsorption of zinc and copper elements on zeolite. Al-Baath University Journal. 39(21).
  • Shubber, M. D., & Kebria, D. Y. (2023). Thermal recycling of bentonite waste as a novel and a low-cost adsorbent for heavy metals removal. Journal of ecological engineering, 24(5).
  • Supriyadi, S., Rahman, F. A., Yuhardi, E., & Umam, C. (2023). Serapan N, P, dan K pada jagung Madura-3 di tanah lempung liat berpasir diameliorasi biochar dan bentonit-teraktivasi asam. Jurnal Tanah dan Sumberdaya Lahan, 10(2), 185-190.
  • Talib, N. N. (2023). Comparison of some ornamental plants in technology of bioreclamation of soils contaminated with some heavy metals (Pb, Cd and Ni). Master's thesis. College of Agricultural Engineering Sciences. University of Baghdad.
  • Trgo, M., & Vukojević-medvidović, N. (2005). The effect of concentration and pH on selectivity of ion exchange in system natural zeolite—Na+/Zn2+ aqueous solutions. In Studies in Surface Science and Catalysis (Vol. 158, pp. 1051-1056). Elsevier.
  • Tunguz, V., Petrović, B., Malešević, Z., & Petronić, S. (2019). Soil and radionuclides of Eastern Herzegovina. Archives for Technical Sciences, 1(20), 87–92.
  • Vij, P., & Prashant, P. M. (2024). Analyzing Soil Pollution by Image Processing and Machine Learning at Contaminated Agricultural Field. Natural and Engineering Sciences, 9(2), 335-346. https://doi.org/10.28978/nesciences.1575484
  • Zhao, Z., Jiang, G., & Mao, R. (2014). Effects of particle sizes of rock phosphate on immobilizing heavy metals in lead zinc mine soils. Journal of soil science and plant nutrition, 14(2), 258-266.
There are 36 citations in total.

Details

Primary Language English
Subjects Water Invertebrates
Journal Section Articles
Authors

Kadhim Makki Naser 0000-0002-8612-8990

Awatif Hameed Dadoosh 0000-0002-9267-0436

Shireen Mudhafar Ali Alkhalil 0009-0005-8293-1910

Publication Date April 1, 2025
Submission Date March 4, 2025
Acceptance Date March 22, 2025
Published in Issue Year 2025 Volume: 10 Issue: 1

Cite

APA Naser, K. M., Dadoosh, A. H., & Alkhalil, S. M. A. (2025). Comparison of Some Soil Mineral’s Ability to Adsorb and Release Lead and Rates of its Removal From its Aqueous Solutions. Natural and Engineering Sciences, 10(1), 403-417. https://doi.org/10.28978/nesciences.1651183

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