Research Article
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Year 2019, Volume: 2 Issue: 2, 47 - 51, 06.12.2019

Abstract

References

  • Aramendia MA, Borau V, Jimenez C, Marinas JM, Romero FJ 1999. Synthesis and characterization of magnesium phosphates and their catalytic properties in the conversion of 2-hexanol. Journal of Colloid and Interface Science, 217: 288–298.
  • Assaaoudi H, Fang Z, Butler IS, Ryan DH, Kozinski JA 2007. Characterization of a new magnesium hydrogen orthophosphate salt, Mg3.5H2(PO4)3, synthesized in supercritical water. Solid State Sciences 9: 385 – 393.
  • Boonchom B 2008. Kinetics and Thermodynamic Properties of the Thermal Decomposition of Manganese Dihydrogenphosphate Dihydrate. Journal of Chemical Engineering Data, 53: 1533–1538.
  • Boonchom B 2009. Kinetic and thermodynamic studies of MgHPO4·3H2O by non-isothermal decomposition data. Journal of Thermal Analysis and Calorimetry, 98: 863–871.
  • Boonchom B, Danvirutai C 2008. A simple synthesis and thermal decomposition kinetics of MnHPO4·H2O rod-like microparticles obtained by spontaneous precipitation route. Journal Of Optoelectronics And Advanced Materials, 10(3): 492 – 499.
  • Boonchom B, Puttawong S 2010. Thermodynamics and kinetics of the dehydration reaction of FePO42H2O, Physica B, 405: 2350–2355.
  • Debnath S, Saxena SK, Nagabhatla V 2016. Facile synthesis of crystalline nanoporous Mg3(PO4)2 and its application to aerobic oxidation of alcohols. Catalysis Communications 84: 129–133.
  • Gopinath P, Ramalingam V, Breslow R 2015. Magnesium pyrophosphates in enzyme mimics of nucleotide synthases and kinases and in their prebiotic chemistry. Proceedings of the National Academy of Sciences of the United Sciences, 112(39): 12011–12014.
  • Kanazawa T, Umegaki T, Shimizu M 1979. The synthesis of Mg3(PO4)2·8H2O and its polymorphism. Bulletin of the Chemical Society of Japan, 52(12): 3713–3717.
  • Kongshaug KO, Fjellvag H, Lillerud 2001. The synthesis and crystal structure of a hydrated magnesium phosphate Mg3(PO4)2·4H2O. Solid State Sciences, 3: 353–360.
  • Lopez FA, Tayibi H, Diaz IG, Alguacil FJ 2015. Thermal dehydration kinetics of phosphogypsum. Materiales de Construction, 65(319): 1-14.
  • Lu X, Chen B 2016. Experimental study of magnesium phosphate cements modified by metakaolin. Construction and Building Materials, 123: 719–726.
  • Mousa S 2010. Study on synthesis of magnesium phosphate materials. Phosphorus Research Bulletin, 24: 16 – 21.
  • Naqvi SR, Tariq R, Hameed Z, Ali I, Naqvi M, Chen WH, Ceylan S, Rashid H, Ahmad J, Taqvi SA, Shahbaz M 2018. Pyrolysis of high ash sewage sludge: kinetics and thermodynamic analysis using Coats-Redfern method, Renewable Energy, (In Press) doi: 10.1016/j.renene.2018.07.094
  • Pokorny P, Tej P, Szelag P 2016. Discussion about magnesium phosphating. Metalurgija, 55(3): 507–510.Qiao F, Chau CK, Li Z 2010. Property evaluation of magnesium phosphate cement mortar as patch repair material. Construction and Building Materials, 24: 695–700.
  • Rouzic M, Chaussadent T, Platret G, Stefan L 2017. Mechanisms of k-struvite formation in magnesium phosphate cements. Cement and Concrete Research, 91: 117–122.
  • Sadiq M, Abdennouri M, Barka N, Baalala M, Lamonier C, Bensitel M 2015. Influence of the Crystal Phase of Magnesium Phosphates Catalysts on the Skeletal Isomerization of 3,3-dimethylbut-1-ene. Canadian Chemical Transactions, 3(2): 225–233.
  • Sadiq M, Bensitel M, Lamonier C, Leglise J 2008. Influence of the nature of precipitating basic agent on the synthesis of catalytic magnesium phosphate materials. Solid State Sciences, 10: 434–437.
  • Sronsri C, Boonchom B 2018. Determination of thermokinetic parameters and thermodynamic functions from thermoforming of LiMnPO4. Journal of Thermal Analysis and Calorimetry, 134(3): 1575 – 1587.
  • Wu F, Wei J, Guo H, Chen F, Hong H, Liu C 2008. Self-setting bioactive calcium–magnesium phosphate cement with high strength and degradability for bone regeneration. Acta Biomaterialia, 4: 1873–1884.
  • Yang Q, Zhu B, Wu X 2000. Characteristics and durability test of magnesium phosphate cement-based material for rapid repair of concrete. Materials and Structures, 33: 229–234.
  • Yu C, Wu Q, Yang J 2017. Effect of seawater for mixing on properties of potassium magnesium phosphate cement paste. Construction and Building Materials, 155: 217–227.
  • Yu X, Jiang J 2018. Mineralization and cementing properties of bio-carbonate cement, bio-phosphate cement, and bio-carbonate/phosphate cement: a review. Environmental Science and Pollution Research, 25: 21483–21497.
  • Yu XN, Qian CX, Sun LZ 2016. Chemosynthesis of nano-magnesium phosphates and its characterization. Digest Journal of Nanomaterials and Biostructures, 11(4): 1099–1103.
  • Zhang S, Li L, Lv X 2016. Synthesis and characterization of a novel Mg3(PO4)2 ceramic with low dielectric constant. Journal of Materials Science: Materials in Electronics, DOI: 10.1007/s10854-016-5703-y
  • Zhang Z, Tang W 2015. Tunable Blue–Red Emission and Energy-Transfer Properties of Mg3(PO4)2:Eu2+,Mn2+ Phosphors. Eyropen Journal of Inorganic Chemistry, 2015: 3940–3948.
  • Zhou H. Luchini TJF, Bhaduri SB 2012. Microwave assisted synthesis of amorphous magnesium phosphate nanospheres. Journal of Materials Science: Materials in Medicine, 23:2831–2837.

Thermal kinetics and thermodynamics of the dehydration reaction of Mg3(PO4)2·22H2O

Year 2019, Volume: 2 Issue: 2, 47 - 51, 06.12.2019

Abstract

Mg3(PO4)2·22H2O
lost its crystal water in the temperature range of 40 - 200°C and the calcined
sample was identified as Mg3(PO4)2, was a
notable for its further treatments in optical and electrical applications.
Dehydration process was studied using non-isothermal thermogravimetry (TG)
applying model-fitting method. Different mechanism models (chemical reaction
order, diffusion and phase interfacial reaction) were applied. The activation
energies calculated for the dehydration reaction; and average of activation
energy was found as 160 kJ/mol.  The
better kinetic model of the dehydration reaction for Mg3(PO4)2·22H2O
was selected as F3 (chemical reaction - third order). The thermodynamic
functions (ΔH, ΔG and ΔS) of the dehydration reaction were calculated by the
activated complex theory and found that the process was endothermic,
non-spontaneous and fast.

References

  • Aramendia MA, Borau V, Jimenez C, Marinas JM, Romero FJ 1999. Synthesis and characterization of magnesium phosphates and their catalytic properties in the conversion of 2-hexanol. Journal of Colloid and Interface Science, 217: 288–298.
  • Assaaoudi H, Fang Z, Butler IS, Ryan DH, Kozinski JA 2007. Characterization of a new magnesium hydrogen orthophosphate salt, Mg3.5H2(PO4)3, synthesized in supercritical water. Solid State Sciences 9: 385 – 393.
  • Boonchom B 2008. Kinetics and Thermodynamic Properties of the Thermal Decomposition of Manganese Dihydrogenphosphate Dihydrate. Journal of Chemical Engineering Data, 53: 1533–1538.
  • Boonchom B 2009. Kinetic and thermodynamic studies of MgHPO4·3H2O by non-isothermal decomposition data. Journal of Thermal Analysis and Calorimetry, 98: 863–871.
  • Boonchom B, Danvirutai C 2008. A simple synthesis and thermal decomposition kinetics of MnHPO4·H2O rod-like microparticles obtained by spontaneous precipitation route. Journal Of Optoelectronics And Advanced Materials, 10(3): 492 – 499.
  • Boonchom B, Puttawong S 2010. Thermodynamics and kinetics of the dehydration reaction of FePO42H2O, Physica B, 405: 2350–2355.
  • Debnath S, Saxena SK, Nagabhatla V 2016. Facile synthesis of crystalline nanoporous Mg3(PO4)2 and its application to aerobic oxidation of alcohols. Catalysis Communications 84: 129–133.
  • Gopinath P, Ramalingam V, Breslow R 2015. Magnesium pyrophosphates in enzyme mimics of nucleotide synthases and kinases and in their prebiotic chemistry. Proceedings of the National Academy of Sciences of the United Sciences, 112(39): 12011–12014.
  • Kanazawa T, Umegaki T, Shimizu M 1979. The synthesis of Mg3(PO4)2·8H2O and its polymorphism. Bulletin of the Chemical Society of Japan, 52(12): 3713–3717.
  • Kongshaug KO, Fjellvag H, Lillerud 2001. The synthesis and crystal structure of a hydrated magnesium phosphate Mg3(PO4)2·4H2O. Solid State Sciences, 3: 353–360.
  • Lopez FA, Tayibi H, Diaz IG, Alguacil FJ 2015. Thermal dehydration kinetics of phosphogypsum. Materiales de Construction, 65(319): 1-14.
  • Lu X, Chen B 2016. Experimental study of magnesium phosphate cements modified by metakaolin. Construction and Building Materials, 123: 719–726.
  • Mousa S 2010. Study on synthesis of magnesium phosphate materials. Phosphorus Research Bulletin, 24: 16 – 21.
  • Naqvi SR, Tariq R, Hameed Z, Ali I, Naqvi M, Chen WH, Ceylan S, Rashid H, Ahmad J, Taqvi SA, Shahbaz M 2018. Pyrolysis of high ash sewage sludge: kinetics and thermodynamic analysis using Coats-Redfern method, Renewable Energy, (In Press) doi: 10.1016/j.renene.2018.07.094
  • Pokorny P, Tej P, Szelag P 2016. Discussion about magnesium phosphating. Metalurgija, 55(3): 507–510.Qiao F, Chau CK, Li Z 2010. Property evaluation of magnesium phosphate cement mortar as patch repair material. Construction and Building Materials, 24: 695–700.
  • Rouzic M, Chaussadent T, Platret G, Stefan L 2017. Mechanisms of k-struvite formation in magnesium phosphate cements. Cement and Concrete Research, 91: 117–122.
  • Sadiq M, Abdennouri M, Barka N, Baalala M, Lamonier C, Bensitel M 2015. Influence of the Crystal Phase of Magnesium Phosphates Catalysts on the Skeletal Isomerization of 3,3-dimethylbut-1-ene. Canadian Chemical Transactions, 3(2): 225–233.
  • Sadiq M, Bensitel M, Lamonier C, Leglise J 2008. Influence of the nature of precipitating basic agent on the synthesis of catalytic magnesium phosphate materials. Solid State Sciences, 10: 434–437.
  • Sronsri C, Boonchom B 2018. Determination of thermokinetic parameters and thermodynamic functions from thermoforming of LiMnPO4. Journal of Thermal Analysis and Calorimetry, 134(3): 1575 – 1587.
  • Wu F, Wei J, Guo H, Chen F, Hong H, Liu C 2008. Self-setting bioactive calcium–magnesium phosphate cement with high strength and degradability for bone regeneration. Acta Biomaterialia, 4: 1873–1884.
  • Yang Q, Zhu B, Wu X 2000. Characteristics and durability test of magnesium phosphate cement-based material for rapid repair of concrete. Materials and Structures, 33: 229–234.
  • Yu C, Wu Q, Yang J 2017. Effect of seawater for mixing on properties of potassium magnesium phosphate cement paste. Construction and Building Materials, 155: 217–227.
  • Yu X, Jiang J 2018. Mineralization and cementing properties of bio-carbonate cement, bio-phosphate cement, and bio-carbonate/phosphate cement: a review. Environmental Science and Pollution Research, 25: 21483–21497.
  • Yu XN, Qian CX, Sun LZ 2016. Chemosynthesis of nano-magnesium phosphates and its characterization. Digest Journal of Nanomaterials and Biostructures, 11(4): 1099–1103.
  • Zhang S, Li L, Lv X 2016. Synthesis and characterization of a novel Mg3(PO4)2 ceramic with low dielectric constant. Journal of Materials Science: Materials in Electronics, DOI: 10.1007/s10854-016-5703-y
  • Zhang Z, Tang W 2015. Tunable Blue–Red Emission and Energy-Transfer Properties of Mg3(PO4)2:Eu2+,Mn2+ Phosphors. Eyropen Journal of Inorganic Chemistry, 2015: 3940–3948.
  • Zhou H. Luchini TJF, Bhaduri SB 2012. Microwave assisted synthesis of amorphous magnesium phosphate nanospheres. Journal of Materials Science: Materials in Medicine, 23:2831–2837.
There are 27 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Articles
Authors

Fatma Tuğçe Şenberber 0000-0002-3257-1524

Emek Möröydor Derun 0000-0002-8587-2013

Publication Date December 6, 2019
Acceptance Date August 26, 2019
Published in Issue Year 2019 Volume: 2 Issue: 2

Cite

APA Şenberber, F. T., & Möröydor Derun, E. (2019). Thermal kinetics and thermodynamics of the dehydration reaction of Mg3(PO4)2·22H2O. Eurasian Journal of Biological and Chemical Sciences, 2(2), 47-51.
AMA Şenberber FT, Möröydor Derun E. Thermal kinetics and thermodynamics of the dehydration reaction of Mg3(PO4)2·22H2O. Eurasian J. Bio. Chem. Sci. December 2019;2(2):47-51.
Chicago Şenberber, Fatma Tuğçe, and Emek Möröydor Derun. “Thermal Kinetics and Thermodynamics of the Dehydration Reaction of Mg3(PO4)2·22H2O”. Eurasian Journal of Biological and Chemical Sciences 2, no. 2 (December 2019): 47-51.
EndNote Şenberber FT, Möröydor Derun E (December 1, 2019) Thermal kinetics and thermodynamics of the dehydration reaction of Mg3(PO4)2·22H2O. Eurasian Journal of Biological and Chemical Sciences 2 2 47–51.
IEEE F. T. Şenberber and E. Möröydor Derun, “Thermal kinetics and thermodynamics of the dehydration reaction of Mg3(PO4)2·22H2O”, Eurasian J. Bio. Chem. Sci., vol. 2, no. 2, pp. 47–51, 2019.
ISNAD Şenberber, Fatma Tuğçe - Möröydor Derun, Emek. “Thermal Kinetics and Thermodynamics of the Dehydration Reaction of Mg3(PO4)2·22H2O”. Eurasian Journal of Biological and Chemical Sciences 2/2 (December 2019), 47-51.
JAMA Şenberber FT, Möröydor Derun E. Thermal kinetics and thermodynamics of the dehydration reaction of Mg3(PO4)2·22H2O. Eurasian J. Bio. Chem. Sci. 2019;2:47–51.
MLA Şenberber, Fatma Tuğçe and Emek Möröydor Derun. “Thermal Kinetics and Thermodynamics of the Dehydration Reaction of Mg3(PO4)2·22H2O”. Eurasian Journal of Biological and Chemical Sciences, vol. 2, no. 2, 2019, pp. 47-51.
Vancouver Şenberber FT, Möröydor Derun E. Thermal kinetics and thermodynamics of the dehydration reaction of Mg3(PO4)2·22H2O. Eurasian J. Bio. Chem. Sci. 2019;2(2):47-51.