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Synthesis of Ternary Chalcogenides in Cu-As-Se Systems by the Solvothermal Method in Organic Medium and Production of Nano-and Microparticles

Year 2024, Volume: 11 Issue: 2, 483 - 490, 15.05.2024
https://doi.org/10.18596/jotcsa.1231804

Abstract

Ternary selenides CuAsSe2 and Cu3AsSe3 were synthesized by the solvothermal method from H [CuCl2]-As2Se3-C2H6O2 system. Nano and microparticles were obtained, and their physical and chemical properties were studied. During syntheses, sodium metaarsenite and copper (I) chloride are mixed in ethylene glycol, and a solution of Na2SeSO3 is added as a selenidation reagent according to stoichiometry. These solutions were added to an experimental vessel, placed in a Teflon cuvette, sealed, and placed in a microwave electric heater. The samples are kept in the oven at 413-443 K for 10 hours. After the process, the precipitate is filtered through a glass filter, washed first with dilute hydrochloric acid and distilled water, and finally with ethyl alcohol, and dried in a vacuum at 333-343 K. The productivity of the samples was 90-92 %. Compounds formed at a temperature of 453-473 K dissolve. Nanoparticles of compounds obtained at a temperature of 413-433 K have an irregular shape. Nanoparticles obtained at a temperature of 443 K are in the form of plates. The results of the X-ray phase analysis showed that the compounds correspond to cubic zirconia and belong to the Pm3m spatial structure. Lattice parameters of CuAsSe2 compound: a = 5.513 Å, Z = 2 and lattice parameters of Cu3AsSe3 compound: a = 5.76 Å, Z = 1. Based on DTA results, the CuAsSe2 compound melts congruently at 743 K, while the Cu3AsSe3 compound decomposes at 773 K.

Supporting Institution

Based on the presentation at the XXXIII İnternational Scientific Symposium.

Thanks

Based on the presentation at the framework of scientific and cultural relations between Kyrgyzstan and Azerbaijan, organized by the Elger Science and Education Center, the conference was held with Kyrgyz Jusup Balasagun Kyrgyz National University XXXIII İnternational Scientific Symposium.

References

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  • 2. Melnikova NV, Mollaev AY, Kheifets OL, et al. Influence of high pressures on electrical and thermoelectric properties of Cu-Ge-As-Se glasses. Azerbaijan Journal of Physics 2015;21:3-8. ISSN 1028-8546.
  • 3. Kumar V, Tripathy SK, Jha V. Second-order nonlinear optical properties of AIBIIIC2VI chalcopyrite semiconductors. Appl. Phys. Lett. 2012 Nov 08;101:192105. Available from: URL
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  • 6. Zeng Y, Joo PH, Yang K, et al. Computation-motivated design of ternary plasmonic copper chalcogenide nanocrystals. Chem. Mater. 2021;33:117–125. Available from: URL
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  • 8. Alan O, Pranati S, Stephanie T, et al. Topochemical Solid-State Reactivity: Redox-Induced Direct Structural Transformation from CuSe2 to CuInSe2. Chem. Mater. 2015 Oct 2;27(20):7179–7186. Available from: URL 9. Shuqin X, Jian L, Philip SS. Structure of Cu–As–Se glasses investigated by neutron diffraction with copper isotope substitution. Physical review. B, Condensed matter. 2008 Aug.;78(6):064207-8. Available from: URL 10. Cui S, Boussard C, Calvez L, et al. Comprehensive study of tellurium-based glass ceramics for thermoelectric application. Advances in Applied Ceramics. 2015;114:42-47. Available from: URL
  • 11. Blachnik R, Kurz G. Compounds in the system Cu2Se and As2Se3. Journal of Solid State Chemistry 1984 Nov;55:218-224. Available from: URL
  • 12. Rzayev BZ. New studies in the field of sulfur compounds of arsenic. Baku: Elm, 2002;94 p.
  • 13. Cynthia GZ. Handbook of Electrochemistry. New Mexico, USA, 2007;879. Available from: URL 14. Suleymanova T. Production of nanoparticles of AgAsSe2 and Ag3AsSe3 compounds. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018;4:103–10. Available from: URL
  • 15. Analytical Methods for Atomic Absorption Spectroscopy. 1996. The Perkin-Elmer Corporation. Printed in the United States of America. Manual Part No. 0303-0152.310 p.
Year 2024, Volume: 11 Issue: 2, 483 - 490, 15.05.2024
https://doi.org/10.18596/jotcsa.1231804

Abstract

References

  • 1. Keiji T, Koichi S. Amorphous chalcogenide semiconductors and related materials. Springer. 2011;195-228. Available from: URL
  • 2. Melnikova NV, Mollaev AY, Kheifets OL, et al. Influence of high pressures on electrical and thermoelectric properties of Cu-Ge-As-Se glasses. Azerbaijan Journal of Physics 2015;21:3-8. ISSN 1028-8546.
  • 3. Kumar V, Tripathy SK, Jha V. Second-order nonlinear optical properties of AIBIIIC2VI chalcopyrite semiconductors. Appl. Phys. Lett. 2012 Nov 08;101:192105. Available from: URL
  • 4. Saipulaeva LA, Gabibov FS, Melnikova NV, et al. Photoelectric and electric properties of four-component copper chalcogenides. J. Exp. Theor. Phys. 2012 Nov;115:918-924. Available from: URL 5. Melnikova NV, Saipulaeva LA, Khokhlachev PP, et al. Effect of pressures on the electrical properties of multicomponent copper and silver chalcogenides. Phys. Solid State 2015 Nov 28;57:2025-2029. Available from: URL
  • 6. Zeng Y, Joo PH, Yang K, et al. Computation-motivated design of ternary plasmonic copper chalcogenide nanocrystals. Chem. Mater. 2021;33:117–125. Available from: URL
  • 7. Kokenyesi S. Amorphous chalcogenide nano-multilayers: research and development. Journal of Optoelectronics and Advanced Materials. 2006 Dec;8:2093–2096. Available from: URL
  • 8. Alan O, Pranati S, Stephanie T, et al. Topochemical Solid-State Reactivity: Redox-Induced Direct Structural Transformation from CuSe2 to CuInSe2. Chem. Mater. 2015 Oct 2;27(20):7179–7186. Available from: URL 9. Shuqin X, Jian L, Philip SS. Structure of Cu–As–Se glasses investigated by neutron diffraction with copper isotope substitution. Physical review. B, Condensed matter. 2008 Aug.;78(6):064207-8. Available from: URL 10. Cui S, Boussard C, Calvez L, et al. Comprehensive study of tellurium-based glass ceramics for thermoelectric application. Advances in Applied Ceramics. 2015;114:42-47. Available from: URL
  • 11. Blachnik R, Kurz G. Compounds in the system Cu2Se and As2Se3. Journal of Solid State Chemistry 1984 Nov;55:218-224. Available from: URL
  • 12. Rzayev BZ. New studies in the field of sulfur compounds of arsenic. Baku: Elm, 2002;94 p.
  • 13. Cynthia GZ. Handbook of Electrochemistry. New Mexico, USA, 2007;879. Available from: URL 14. Suleymanova T. Production of nanoparticles of AgAsSe2 and Ag3AsSe3 compounds. Journal of the Turkish Chemical Society, Section A: Chemistry. 2018;4:103–10. Available from: URL
  • 15. Analytical Methods for Atomic Absorption Spectroscopy. 1996. The Perkin-Elmer Corporation. Printed in the United States of America. Manual Part No. 0303-0152.310 p.
There are 11 citations in total.

Details

Primary Language English
Subjects Inorganic Chemistry
Journal Section RESEARCH ARTICLES
Authors

Turac Suleymanova 0000-0003-1564-8080

Publication Date May 15, 2024
Submission Date January 10, 2023
Acceptance Date November 29, 2023
Published in Issue Year 2024 Volume: 11 Issue: 2

Cite

Vancouver Suleymanova T. Synthesis of Ternary Chalcogenides in Cu-As-Se Systems by the Solvothermal Method in Organic Medium and Production of Nano-and Microparticles. JOTCSA. 2024;11(2):483-90.