Research Article
BibTex RIS Cite

EFFECTS of LOW REACTION RATE on ZNO THIN FILMS PRODUCED by a CHEMICAL BATH DEPOSITION METHOD

Year 2022, Issue: 050, 124 - 136, 30.09.2022

Abstract

In the presented study, while ZnO thin films were deposited onto glass substrates, chemical bath deposition method was used and Na2S2O3 was used as an inhibitor to reduce the reaction rate. Four different samples were produced using 0, 4, 8 and 16mM Na2S2O3, respectively. The images obtained from the scanning electron microscope showed that the amount of nano flowers on the film surfaces decreased due to the increase in the amount of inhibitor. The X-ray diffraction results were consistent with the ASTM card and showed that all the films were crystallized in a hexagonal structure. UV measurements showed that the absorbance value of the sample obtained without the use of inhibitor was up to four times higher than the other samples. It was observed that the energy band gaps of the films increased up to 4.24 eV depending on the amount of inhibitor. Visual analysis showed that all films adhered very well to the glass surface.

Supporting Institution

Bilecik Şeyh Edebali Üniversitesi

Project Number

2020-02.BŞEÜ.11-01

Thanks

The authors thank the Scientific Research Projects Coordinatorship of Bilecik Şeyh Edebali University for their support for the project titled Production of ZnO Films by Chemical Deposition Method, numbered 2020-02.BŞEÜ.11-01.

References

  • [1] Temel, S., Gokmen, F. O., and Yaman, E., (2017), Effects of Deposition Time on Structural and Morphological Properties of Synthesized ZnO Nanoflowers Without Using Complexing Agent, European Scientific Journal, ESJ, 13(27), 28
  • [2] Wang, J. X., Sun, X. W., Yang, Y., Kyaw, K. K. A., Huang, X. Y., Yin, J. Z., … Demir, H. V., (2011), Free-standing ZnO–CuO composite nanowire array films and their gas sensing properties, Nanotechnology, 22(32), 325704.
  • [3] Shukla, V., and Patel, A., (2020), Effect of doping concentration on optical and electrical properties of intrinsic n-type ZnO ( i-ZnO ) and ( Cu , Na and K ) doped p-type ZnO thin films grown by chemical bath deposition method, Nanosystems Physics Chemistry Mathematics, 11(4), 391–400.
  • [4] Saraç, U., and Baykul, M. C., (2021), The influence of seed layer electroplating time on structural properties, optical energy bandgap, diameter, growth orientation and surface roughness of ZnO nanorods, Journal of Materials Science: Materials in Electronics, 32(22), 26578–26587.
  • [5] Wang, H., Liu, Y., Li, M., Huang, H., Xu, H., and Shen, H., (2011), Fabrication of three-dimensional ZnO with hierarchical structure via an electrodeposition process, Applied Physics A, 25, 463–466.
  • [6] Edinger, S., (2017), Comparison of chemical bath-deposited ZnO films doped with Al , Ga and In, Journal of Materials Science, 52(16), 9410–9423.
  • [7] Of, O., (2013), Structural Properties of ZnO Thin Films Obtained by Chemical Bath Deposition Technique, Journal of Nano- and Electronic Physics, 5(1), 4–7.
  • [8] Önal, M., and Altıokka, B., (2020), Effect of stirring on chemically deposited ZnO thin films, Acta Physica Polonica A, 137(6), 1209–1213.
  • [9] Kumar, S., Kang, H. C. J. T. W., Seth, R., Panwar, S., and Shinde, S. K., (2019), Variation in chemical bath pH and the corresponding precursor concentration for optimizing the optical , structural and morphological properties of ZnO thin films, Journal of Materials Science: Materials in Electronics, (0123456789),
  • [10] Fortunato, M., Chandraiahgari, C. R., Bellis, G. De, Ballirano, P., Soltani, P., Kaciulis, S., … Sarto, M. S., (2018), Piezoelectric Thin Films of Grown by Chemical Bath Deposition, IEEE Transactions on Nanotechnology, 17(2), 311–319.
  • [11] Janotti, A., and Walle, C. G. Van De, (2009), Fundamentals of zinc oxide as a semiconductor, Reports on progress in physics, (December),
  • [12] I, T. S., and Brien, P. O., (1995), Deposition and characterisation of ZnO thin films grown by chemical bath deposition, Thin solid films, 271, 35–38.
  • [13] Ramamoorthy, K., Arivanandhan, M., Sankaranarayanan, K., and Sanjeeviraja, C., (2004), Highly textured ZnO thin films : a novel economical preparation and approachment for optical devices , UV lasers and green LEDs, , 85, 257–262.
  • [14] Avila-garcı, A., and Ortega-lo, M., (2003), Improved efficiency of the chemical bath deposition method during growth of ZnO thin films, Materials Research Bulletin, 38, 1241–1248.
  • [15] Masuda, S., Kitamura, K., Okumura, Y., Miyatake, S., Tabata, H., and Kawai, T., (2003), Transparent thin film transistors using ZnO as an active channel layer and their electrical properties, Journal of Applied Physics, 93(3), 1624–1630.
  • [16] Drici, A., Djeteli, G., Tchangbedji, G., Derouiche, H., Jondo, K., Napo, K., … Gbagba, M., (2004), Structured ZnO thin films grown by chemical bath deposition for photovoltaic applications, Physica status solidi (a), 1536(7), 1528–1536.
  • [17] Ouerfelli, J., Regragui, M., Morsli, M., Djeteli, G., and Jondo, K., (1954), Properties of ZnO thin films deposited by chemical bath deposition and post, Journal of Physics D: Applied Physics, 1954.
  • [18] Bundesanstalt, P. T., (2008), Electrodeposition of ZnO nanorods for device, Applied Physics A, 599(3), 595–599.
  • [19] Yuan, Z., (2015), Low-Temperature Growth of Well-Aligned ZnO Nanorod Arrays by Chemical Bath Deposition for Schottky Diode Application, Journal of Electronic Materials, 44(4), 1187–1191.
  • [20] Önal, M., and Altıokka, B., (2020), Optimization of EDTA – Ammonia Ratio for Chemically Deposited Layers of ZnO Nanoparticles, Crystallography Reports, 65(7), 1237–1241.
  • [21] Yildizay, H., (2022), Effects of inhibitor on chemically deposited ZnO thin films, Emerging Materials Research, Volume 11(1),
  • [22] Mohammed, I. M. S., Gubari, G. M. M., Sonawane, M. E., Kasar, R. R., Patil, S. A., Mishra, M. K., … Sharma, R., (2021), Influence of pH on the physical properties of CdS thin film and its photosensor application, Applied Physics A: Materials Science and Processing, 127(8), 1–10.
  • [23] Jambure, S. B., Patil, S. J., Deshpande, A. R., and Lokhande, C. D., (2014), A comparative study of physico-chemical properties of CBD and SILAR grown ZnO thin films, Materials Research Bulletin, 49(1), 420–425.
  • [24] Shaikh, S. K., Inamdar, S. I., Ganbavle, V. V., and Rajpure, K. Y., (2016), Chemical bath deposited ZnO thin film based UV photoconductive detector, Journal of Alloys and Compounds, 664, 242–249.
  • [25] Bhowmik, R., Murty, M. N., and Srinadhu, E. S., (2008), Magnetic modulation in mechanical alloyed Cr1.4Fe0.6O3oxide, PMC Physics B, 1(1),
  • [26] Rahul, Verma, A. K., Tripathi, R. S. N., and Vishwakarma, S. R., (2012), Electrical and optical characterization of electron beam evaporated indium antimonide thin films, National Academy Science Letters, 35(5), 367–372.
  • [27] Bal, I., Baykul, M. C., and Saraç, U., (2021), The effect of solution temperature on chemically manufactured cds samples, Chalcogenide Letters, 18(1), 1–10.
  • [28] Berruet, M., and Va, M., (2010), Materials Science in Semiconductor Processing Electrodeposition of single and duplex layers of ZnO with different morphologies and electrical properties, Materials science in semiconductor processing, 13, 239–244.
  • [29] Khan, Z. R., Khan, M. S., Zulfequar, M., and Shahid Khan, M., (2011), Optical and Structural Properties of ZnO Thin Films Fabricated by Sol-Gel Method, Materials Sciences and Applications, 02(05), 340–345
Year 2022, Issue: 050, 124 - 136, 30.09.2022

Abstract

Project Number

2020-02.BŞEÜ.11-01

References

  • [1] Temel, S., Gokmen, F. O., and Yaman, E., (2017), Effects of Deposition Time on Structural and Morphological Properties of Synthesized ZnO Nanoflowers Without Using Complexing Agent, European Scientific Journal, ESJ, 13(27), 28
  • [2] Wang, J. X., Sun, X. W., Yang, Y., Kyaw, K. K. A., Huang, X. Y., Yin, J. Z., … Demir, H. V., (2011), Free-standing ZnO–CuO composite nanowire array films and their gas sensing properties, Nanotechnology, 22(32), 325704.
  • [3] Shukla, V., and Patel, A., (2020), Effect of doping concentration on optical and electrical properties of intrinsic n-type ZnO ( i-ZnO ) and ( Cu , Na and K ) doped p-type ZnO thin films grown by chemical bath deposition method, Nanosystems Physics Chemistry Mathematics, 11(4), 391–400.
  • [4] Saraç, U., and Baykul, M. C., (2021), The influence of seed layer electroplating time on structural properties, optical energy bandgap, diameter, growth orientation and surface roughness of ZnO nanorods, Journal of Materials Science: Materials in Electronics, 32(22), 26578–26587.
  • [5] Wang, H., Liu, Y., Li, M., Huang, H., Xu, H., and Shen, H., (2011), Fabrication of three-dimensional ZnO with hierarchical structure via an electrodeposition process, Applied Physics A, 25, 463–466.
  • [6] Edinger, S., (2017), Comparison of chemical bath-deposited ZnO films doped with Al , Ga and In, Journal of Materials Science, 52(16), 9410–9423.
  • [7] Of, O., (2013), Structural Properties of ZnO Thin Films Obtained by Chemical Bath Deposition Technique, Journal of Nano- and Electronic Physics, 5(1), 4–7.
  • [8] Önal, M., and Altıokka, B., (2020), Effect of stirring on chemically deposited ZnO thin films, Acta Physica Polonica A, 137(6), 1209–1213.
  • [9] Kumar, S., Kang, H. C. J. T. W., Seth, R., Panwar, S., and Shinde, S. K., (2019), Variation in chemical bath pH and the corresponding precursor concentration for optimizing the optical , structural and morphological properties of ZnO thin films, Journal of Materials Science: Materials in Electronics, (0123456789),
  • [10] Fortunato, M., Chandraiahgari, C. R., Bellis, G. De, Ballirano, P., Soltani, P., Kaciulis, S., … Sarto, M. S., (2018), Piezoelectric Thin Films of Grown by Chemical Bath Deposition, IEEE Transactions on Nanotechnology, 17(2), 311–319.
  • [11] Janotti, A., and Walle, C. G. Van De, (2009), Fundamentals of zinc oxide as a semiconductor, Reports on progress in physics, (December),
  • [12] I, T. S., and Brien, P. O., (1995), Deposition and characterisation of ZnO thin films grown by chemical bath deposition, Thin solid films, 271, 35–38.
  • [13] Ramamoorthy, K., Arivanandhan, M., Sankaranarayanan, K., and Sanjeeviraja, C., (2004), Highly textured ZnO thin films : a novel economical preparation and approachment for optical devices , UV lasers and green LEDs, , 85, 257–262.
  • [14] Avila-garcı, A., and Ortega-lo, M., (2003), Improved efficiency of the chemical bath deposition method during growth of ZnO thin films, Materials Research Bulletin, 38, 1241–1248.
  • [15] Masuda, S., Kitamura, K., Okumura, Y., Miyatake, S., Tabata, H., and Kawai, T., (2003), Transparent thin film transistors using ZnO as an active channel layer and their electrical properties, Journal of Applied Physics, 93(3), 1624–1630.
  • [16] Drici, A., Djeteli, G., Tchangbedji, G., Derouiche, H., Jondo, K., Napo, K., … Gbagba, M., (2004), Structured ZnO thin films grown by chemical bath deposition for photovoltaic applications, Physica status solidi (a), 1536(7), 1528–1536.
  • [17] Ouerfelli, J., Regragui, M., Morsli, M., Djeteli, G., and Jondo, K., (1954), Properties of ZnO thin films deposited by chemical bath deposition and post, Journal of Physics D: Applied Physics, 1954.
  • [18] Bundesanstalt, P. T., (2008), Electrodeposition of ZnO nanorods for device, Applied Physics A, 599(3), 595–599.
  • [19] Yuan, Z., (2015), Low-Temperature Growth of Well-Aligned ZnO Nanorod Arrays by Chemical Bath Deposition for Schottky Diode Application, Journal of Electronic Materials, 44(4), 1187–1191.
  • [20] Önal, M., and Altıokka, B., (2020), Optimization of EDTA – Ammonia Ratio for Chemically Deposited Layers of ZnO Nanoparticles, Crystallography Reports, 65(7), 1237–1241.
  • [21] Yildizay, H., (2022), Effects of inhibitor on chemically deposited ZnO thin films, Emerging Materials Research, Volume 11(1),
  • [22] Mohammed, I. M. S., Gubari, G. M. M., Sonawane, M. E., Kasar, R. R., Patil, S. A., Mishra, M. K., … Sharma, R., (2021), Influence of pH on the physical properties of CdS thin film and its photosensor application, Applied Physics A: Materials Science and Processing, 127(8), 1–10.
  • [23] Jambure, S. B., Patil, S. J., Deshpande, A. R., and Lokhande, C. D., (2014), A comparative study of physico-chemical properties of CBD and SILAR grown ZnO thin films, Materials Research Bulletin, 49(1), 420–425.
  • [24] Shaikh, S. K., Inamdar, S. I., Ganbavle, V. V., and Rajpure, K. Y., (2016), Chemical bath deposited ZnO thin film based UV photoconductive detector, Journal of Alloys and Compounds, 664, 242–249.
  • [25] Bhowmik, R., Murty, M. N., and Srinadhu, E. S., (2008), Magnetic modulation in mechanical alloyed Cr1.4Fe0.6O3oxide, PMC Physics B, 1(1),
  • [26] Rahul, Verma, A. K., Tripathi, R. S. N., and Vishwakarma, S. R., (2012), Electrical and optical characterization of electron beam evaporated indium antimonide thin films, National Academy Science Letters, 35(5), 367–372.
  • [27] Bal, I., Baykul, M. C., and Saraç, U., (2021), The effect of solution temperature on chemically manufactured cds samples, Chalcogenide Letters, 18(1), 1–10.
  • [28] Berruet, M., and Va, M., (2010), Materials Science in Semiconductor Processing Electrodeposition of single and duplex layers of ZnO with different morphologies and electrical properties, Materials science in semiconductor processing, 13, 239–244.
  • [29] Khan, Z. R., Khan, M. S., Zulfequar, M., and Shahid Khan, M., (2011), Optical and Structural Properties of ZnO Thin Films Fabricated by Sol-Gel Method, Materials Sciences and Applications, 02(05), 340–345
There are 29 citations in total.

Details

Primary Language English
Journal Section Research Articles
Authors

Metehan Önal 0000-0001-7128-7123

Barış Altıokka 0000-0001-8891-973X

Project Number 2020-02.BŞEÜ.11-01
Publication Date September 30, 2022
Submission Date June 3, 2022
Published in Issue Year 2022 Issue: 050

Cite

IEEE M. Önal and B. Altıokka, “EFFECTS of LOW REACTION RATE on ZNO THIN FILMS PRODUCED by a CHEMICAL BATH DEPOSITION METHOD”, JSR-A, no. 050, pp. 124–136, September 2022.