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Fonksiyonelleştirilmiş schiff bazı olarak (E) -tert-butil (2-((3,5-di-tertbutil-2-hidroksibenziliden)amino)etil)karbamat’ın sentezi, moleküler yapı, spektroskopik ve hesaplamalı çalışmaları

Year 2018, Issue: 3, 27 - 32, 31.12.2018

Pınar Şen Salih Zeki Yıldız Ömer Tamer Sibel Demir Kanmazalp Necmi Dege

Abstract

Bu çalışma, Schiff baz türevi olarak yeni bir bileşiğin, (E) -tert-butil (2 -((3,5-di-tert-butil-2-hidroksibenziliden) amino) etil) karbamat’ın sentezini ve karakterizasyonunu içermektedir. Bu bileşik, simetrik olmayan katalizör olarak potansiyel bir aday olan simetrik olmayan metal komplekslerinin hazırlanması için bir ligand olarak seçilmiştir. Bileşiğin spektroskopik özellikleri FT-IR, 1 H NMR, 13C NMR, kütle ve element analizleriyle incelenmiştir. Bileşiğin moleküler yapısı, ayrıca X-ışını tek kristalli verileri kullanılarak doğrulanmıştır. Molekül, (100) boyunca uzanan zincirleri oluşturan moleküller arası N-H ··· O hidrojen bağları ile stabilizedir. Ayrıca bileşiğin, moleküler yapı, titreşim frekansları ve 1H ve 13C NMR kimyasal kaymaları, B3LYP yöntemi kullanılarak 6-311 ++ G (dp) temel seti ile hesaplanmıştır.

Keywords

Sentez Kristal yapı Schiff bazı amin monoBoc koruma teorik hesaplama

References

  • Referans1 Doç. Dr. Çiğdem Yüksektepe Ataol :yuksekc85@gmail.com-Çankırı Karatekin üniversitesi
  • Referans2 Dr. Öğretim Üyesi Ayşin Zülfikaroğlu: aysin.zulfikaroglu@amasya.edu.tr: Amasya Üniversitesi
  • Referans2 Dr. Zeynep Demircioğlu: zeynep.kelesoglu@omu.edu.tr: Sinop Üniversitesi

Synthesis, molecular structure, spectroscopic and computational studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl) carbamate as a functionalized schiff base

Year 2018, Issue: 3, 27 - 32, 31.12.2018

Pınar Şen Salih Zeki Yıldız Ömer Tamer Sibel Demir Kanmazalp Necmi Dege

Abstract

This
work presents the synthesis and characterization of a novel compound, (E)-tert-butyl
(2-((3,5-di-tert-butyl-2-hydroxybenzylidene)amino)ethyl)carbamate as the
Schiff base derivative. This compound 
have been selected as a ligand for the preparation of unsymmetrical
metal complexes which is a potential candidate as unsymmetrical catalyst. The
spectroscopic properties of the compound were examined by
FT-IR, 1H NMR, 13C NMR, 
MS and elemental analyses. The molecular structure
of the compound was also confirmed using X-ray single-crystal data. The
molecule is stabilized through intermolecular N—H···O hydrogen bonds, which
form chains extending along [100]. And also it has
been calculated; molecular structure, vibrational frequencies and 1H
and 13C NMR chemical shifts of the title compound by using B3LYP
method with 6-311++G(dp) basis set, as well.

Keywords

Synthesis Crystal structure Schiff base amine mono-Boc-protection theoretical calculation

References

  • Referans1 Doç. Dr. Çiğdem Yüksektepe Ataol :yuksekc85@gmail.com-Çankırı Karatekin üniversitesi
  • Referans2 Dr. Öğretim Üyesi Ayşin Zülfikaroğlu: aysin.zulfikaroglu@amasya.edu.tr: Amasya Üniversitesi
  • Referans2 Dr. Zeynep Demircioğlu: zeynep.kelesoglu@omu.edu.tr: Sinop Üniversitesi
There are 3 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Article
Authors

Pınar Şen

Salih Zeki Yıldız

Ömer Tamer

Sibel Demir Kanmazalp This is me

Necmi Dege

Publication Date December 31, 2018
Published in Issue Year 2018 Issue: 3

Cite

APA Şen, P., Yıldız, S. Z., Tamer, Ö., Kanmazalp, S. D., et al. (2018). Synthesis, molecular structure, spectroscopic and computational studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl) carbamate as a functionalized schiff base. Karadeniz Chemical Science and Technology(3), 27-32.
AMA Şen P, Yıldız SZ, Tamer Ö, Kanmazalp SD, Dege N. Synthesis, molecular structure, spectroscopic and computational studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl) carbamate as a functionalized schiff base. Karadeniz Chem. Sci. Tech. December 2018;(3):27-32.
Chicago Şen, Pınar, Salih Zeki Yıldız, Ömer Tamer, Sibel Demir Kanmazalp, and Necmi Dege. “Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-Tert-Butyl (2-((3,5-Di-Tert-Butyl-2-Hydroxybenzylidene) amino)ethyl) Carbamate As a Functionalized Schiff Base”. Karadeniz Chemical Science and Technology, no. 3 (December 2018): 27-32.
EndNote Şen P, Yıldız SZ, Tamer Ö, Kanmazalp SD, Dege N (December 1, 2018) Synthesis, molecular structure, spectroscopic and computational studies of (E)-tert-butyl (2-(3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl) carbamate as a functionalized schiff base. Karadeniz Chemical Science and Technology 3 27–32.
IEEE P. Şen, S. Z. Yıldız, Ö. Tamer, S. D. Kanmazalp, and N. Dege, “Synthesis, molecular structure, spectroscopic and computational studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl) carbamate as a functionalized schiff base”, Karadeniz Chem. Sci. Tech., no. 3, pp. 27–32, December 2018.
ISNAD Şen, Pınar et al. “Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-Tert-Butyl (2-((3,5-Di-Tert-Butyl-2-Hydroxybenzylidene) amino)ethyl) Carbamate As a Functionalized Schiff Base”. Karadeniz Chemical Science and Technology 3 (December 2018), 27-32.
JAMA Şen P, Yıldız SZ, Tamer Ö, Kanmazalp SD, Dege N. Synthesis, molecular structure, spectroscopic and computational studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl) carbamate as a functionalized schiff base. Karadeniz Chem. Sci. Tech. 2018;:27–32.
MLA Şen, Pınar et al. “Synthesis, Molecular Structure, Spectroscopic and Computational Studies of (E)-Tert-Butyl (2-((3,5-Di-Tert-Butyl-2-Hydroxybenzylidene) amino)ethyl) Carbamate As a Functionalized Schiff Base”. Karadeniz Chemical Science and Technology, no. 3, 2018, pp. 27-32.
Vancouver Şen P, Yıldız SZ, Tamer Ö, Kanmazalp SD, Dege N. Synthesis, molecular structure, spectroscopic and computational studies of (E)-tert-butyl (2-((3,5-di-tert-butyl-2-hydroxybenzylidene) amino)ethyl) carbamate as a functionalized schiff base. Karadeniz Chem. Sci. Tech. 2018(3):27-32.
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