Research Article
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Determination of kinetic parameters and thermodynamic properties of melon seed pyrolysis

Year 2021, Volume: 10 Issue: 2, 723 - 736, 27.07.2021
https://doi.org/10.28948/ngumuh.910277

Abstract

The aim of this study is to examine the behaviour of melon seed pyrolysis and to calculate its kinetic parameters along with thermodynamic properties. The thermogravimetric analysis experiments were conducted from ambient temperature to 800°C under nitrogen atmosphere at the heating rates of 5, 10, 20 and 40°C/min. It was determined that the pyrolysis process underwent through four stages where the second and third stages were the active pyrolysis stages. Kinetic calculations were carried out using model-free Flynn-Wall-Ozawa, Kissinger-Akahira-Sunose, Starink and model-based Coats-Redfern methods. The apparent activation energy values of the second and third stages were calculated to be in the ranges of 123.9–215.5 and 141.9– 234.2 kJ/mol, respectively. The Coats-Redfern method demonstrated that the second and third stages fit the reaction mechanisms of F1.65 and D5, respectively. Moreover, the enthalpy, entropy and Gibbs energy changes of the active pyrolysis stages performed at 10°C/min heating rate were determined using the results calculated from the model-free kinetic methods. The results obtained in the present study will be useful to provide necessary information needed for the design of melon seed pyrolysis processes.

References

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Kavun çekirdeği pirolizine ait kinetik parametrelerin ve termodinamik özelliklerin belirlenmesi

Year 2021, Volume: 10 Issue: 2, 723 - 736, 27.07.2021
https://doi.org/10.28948/ngumuh.910277

Abstract

Bu çalışmanın amacı, kavun çekirdeği pirolizinin davranışını incelemek ve kinetik parametreleri ile termodinamik özelliklerini hesaplamaktır. Termogravimetrik analiz deneyleri azot atmosferinde çevre sıcaklığından 800°C’ye 5, 10, 20 ve 40°C/dk ısıtma hızlarında çalışılmıştır. Piroliz prosesinin, ikinci ve üçüncü basamakları aktif piroliz basamağı olan dört basamakta gerçekleştiği tespit edilmiştir. Kinetik hesaplamalar model içermeyen Flynn-Wall-Ozawa, Kissinger-Akahira-Sunose, Starink ve model bazlı Coats-Redfern yöntemi ile gerçekleştirilmiştir. İkinci ve üçüncü basamaklara ait görünen aktivasyon enerjisi değerlerinin sırasıyla, 123.9– 215.5 ve 141.9–234.2 kJ/mol aralıklarında olduğu hesaplanmıştır. Coats-Redfern yöntemi, ikinci ve üçüncü basamakların sırasıyla F1.65 ve D5 reaksiyon mekanizmalarına uyduğunu ortaya koymuştur. Ayrıca, 10°C/dk ısıtma hızında gerçekleştirilen piroliz prosesinin aktif piroliz basamakları için, model içermeyen kinetik yöntemlerden hesaplanan sonuçlar kullanılarak entalpi, entropi ve Gibbs enerji değişimleri hesaplanmıştır. Mevcut çalışmada elde edilen sonuçlar, kavun çekirdeği piroliz proseslerinin tasarlanmasında gerekli olan bilgileri sağlamada faydalı olacaktır.

References

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  • K. Li, L. Zhang, L. Zhu and X. Zhu, Comparative study on pyrolysis of lignocellulosic and algal biomass using pyrolysis-gas chromatography/mass spectrometry. Bioresource Technology, 234, 48-52, 2017. https://doi.org/10.1016/j.biortech.2017.03.014
  • S. Sobek and S. Werl,. Kinetic modelling of waste wood devolatilization during pyrolysis based on thermogravimetric data and solar pyrolysis reactor performance. Fuel, 261, 116459, 1-15, 2020. https://doi.org/10.1016/j.fuel.2019.116459
  • G. Mishra, J. Kumar and T. Bhaskar. Kinetic studies on the pyrolysis of pinewood. Bioresource Technology, 182, 282-288, 2015. https://doi.org/10.1016/j.biortech. 2015.01.087
  • N. Ertaş and M. Aslan, A study on the potential of using melon wastes in biscuit production. Kahramanmaraş Sütçü İmam Üniversitesi Tarım ve Doğa Dergisi, 23 (5), 1216-1224, 2020. https://doi.org/10.18016/ ksutarimdoga.vi.681812
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  • M. Ünlü, R. Kurum ve A. Ünlü, Örtüaltı kavun (Cucumis melo ssp. melo) yetiştiriciliği için geliştirilen hibritlerin verim ve meyve bakımından değerlendirilmesi. Akademik Ziraat Dergisi, 6, 121-126, 2017. https://dergipark.org.tr/tr/pub/azd/issue/ 32275/363353
  • A. Ahmed, E. A. Afolabi, M. U. Garba, U. Musa, M. Alhassan and K. Ishaq, Effect of particle size on thermal decomposition and devolatilization kinetics of melon seed shell. Chemical Engineering Communications, 206(9), 1228-1240, 2019. https://doi.org/10.1080/00986445.2018.1555530
  • B. B. Nyakuma, F. Roozbahani, O. Oladokun, Y. A. Dodo, A. S. Elnafaty and T. John-Paul Ivase, Kinetic analysis of melon seed husk using non-isothermal thermogravimetric analysis. Materials Today: Proceedings, 5, 11(2), 23249-23257, 2018. https://doi.org/10.1016/j.matpr.2018.11.057
  • Ş. Bayram and E. Güneş, Nutrients and cucurbita eaten from the seed. International Journal of Environmental Pollution and Environmental Modelling, 3 (1), 27-33, 2020. https://dergipark.org.tr/tr/pub/ijepem/issue/ 54371/789209
  • S. Sabancı, C. Celebi and F. Icier, Rheological properties of sübye. traditional beverage. Akademik Gıda, 12 (1), 11-15, 2014. https://dergipark.org.tr/ tr/download/article-file/1186530
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  • İ. Çelik ve K. Pozan, Kavun çekirdeği tozunun eriştenin bazı özelliklerine etkisi. Gıda, 45 (5), 907-916, 2020. https://dergipark.org.tr/tr/pub/gida/issue/56397/700627
  • T. Xu, F. Xu, Z. Hu, Z. Chen and B. Xiao, Non-isothermal kinetics of biomass-pyrolysis-derived-tar (BPDT) thermal decomposition via thermogravimetric analysis. Energy Conversion and Management, 138, 452-460, 2017. https://doi.org/10.1016/j.enconman. 2017.02.013
  • Th. Damartzis, D. Vamvuka, S. Sfakiotakis and A. Zabaniotou, Thermal degradation studies and kinetic modeling of cardoon (Cynara cardunculus) pyrolysis using thermogravimetric analysis (TGA). Bioresource Technology, 102, 6230-6238, 2011. https://doi.org/ 10.1016/ j.biortech.2011.02.060
  • A. A. Jain, A. Mehra and V. V. Ranade, Processing of TGA data: Analysis of isoconversional and model fitting methods. Fuel, 165, 490-498, 2016. https://doi.org/10.1016/j.fuel.2015.10.042
  • G. Chen, S. He, Z. Cheng, Y. Guan, B. Yan, W. Ma and D. Y. C. Leung, Comparison of kinetic analysis methods in thermal decomposition of cattle manure by themogravimetric analysis. Bioresource Technology, 243, 69-77, 2017. https://doi.org/10.1016/j.biortech. 2017.06.007
  • S. O. Giwa and T. O. Akanbi, A review on food uses and the prospect of egusi melon for biodiesel production. Bioenergy Research, 13, 1031–1045, 2020. https://doi.org/10.1007/s12155-020-10145-4
  • B. B. Nyakuma, Thermogravimetric and kinetic analysis of melon (Citrullus colocynthis l.) seed husk using the distributed activation energy model. Environmental and Climate Technologies, 15 (1), 77-89, 2015. https://doi.org/10.1515/rtuect-2015-0007
  • K. Açıkalın, Thermogravimetric analysis of walnut shell as pyrolysis feedstock. Journal of Thermal Analysis and Calorimetry, 105, 145-150, 2011. https://doi.org/10.1007/s10973-010-1267-x
  • K. Açıkalın, Pyrolytic characteristics and kinetics of pistachio shell by thermogravimetric analysis. Journal of Thermal Analysis and Calorimetry, 109, 227-235, 2012. https://doi.org/10.1007/s10973-011-1714-3
  • G. Gözke and K. Açıkalın, Pyrolysis characteristics and kinetics of sour cherry stalk and flesh via thermogravimetric analysis using isoconversional methods. Journal of Thermal Analysis and Calorimetry, 2020. https://doi.org/10.1007/s10973-020-10055-9
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There are 53 citations in total.

Details

Primary Language Turkish
Subjects Chemical Engineering
Journal Section Chemical Engineering
Authors

Korkut Açıkalın 0000-0002-2698-5595

Gözde Gözke 0000-0003-4576-8761

Publication Date July 27, 2021
Submission Date April 5, 2021
Acceptance Date May 27, 2021
Published in Issue Year 2021 Volume: 10 Issue: 2

Cite

APA Açıkalın, K., & Gözke, G. (2021). Kavun çekirdeği pirolizine ait kinetik parametrelerin ve termodinamik özelliklerin belirlenmesi. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 10(2), 723-736. https://doi.org/10.28948/ngumuh.910277
AMA Açıkalın K, Gözke G. Kavun çekirdeği pirolizine ait kinetik parametrelerin ve termodinamik özelliklerin belirlenmesi. NOHU J. Eng. Sci. July 2021;10(2):723-736. doi:10.28948/ngumuh.910277
Chicago Açıkalın, Korkut, and Gözde Gözke. “Kavun çekirdeği Pirolizine Ait Kinetik Parametrelerin Ve Termodinamik özelliklerin Belirlenmesi”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 10, no. 2 (July 2021): 723-36. https://doi.org/10.28948/ngumuh.910277.
EndNote Açıkalın K, Gözke G (July 1, 2021) Kavun çekirdeği pirolizine ait kinetik parametrelerin ve termodinamik özelliklerin belirlenmesi. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 10 2 723–736.
IEEE K. Açıkalın and G. Gözke, “Kavun çekirdeği pirolizine ait kinetik parametrelerin ve termodinamik özelliklerin belirlenmesi”, NOHU J. Eng. Sci., vol. 10, no. 2, pp. 723–736, 2021, doi: 10.28948/ngumuh.910277.
ISNAD Açıkalın, Korkut - Gözke, Gözde. “Kavun çekirdeği Pirolizine Ait Kinetik Parametrelerin Ve Termodinamik özelliklerin Belirlenmesi”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 10/2 (July 2021), 723-736. https://doi.org/10.28948/ngumuh.910277.
JAMA Açıkalın K, Gözke G. Kavun çekirdeği pirolizine ait kinetik parametrelerin ve termodinamik özelliklerin belirlenmesi. NOHU J. Eng. Sci. 2021;10:723–736.
MLA Açıkalın, Korkut and Gözde Gözke. “Kavun çekirdeği Pirolizine Ait Kinetik Parametrelerin Ve Termodinamik özelliklerin Belirlenmesi”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, vol. 10, no. 2, 2021, pp. 723-36, doi:10.28948/ngumuh.910277.
Vancouver Açıkalın K, Gözke G. Kavun çekirdeği pirolizine ait kinetik parametrelerin ve termodinamik özelliklerin belirlenmesi. NOHU J. Eng. Sci. 2021;10(2):723-36.

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