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Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması

Year 2024, Volume: 13 Issue: 1, 223 - 235, 15.01.2024

Abdülvahap Çakmak

https://doi.org/10.28948/ngumuh.1284143

Abstract

Bu çalışmada, hacimsel olarak %15 oranında biyodizel içeren dizel-biyodizel yakıt karışımına (B15) alüminyum oksit (Al2O3) nanoparçacıkları ile bütil hidroksi tolüen (BHT), tersiyer bütil hidrokinon (TBHQ) ve karanfil esansiyel yağı (KEY) antioksidan katkı maddelerinin eklenmesinin yanma karakteristikleri, motor performansı ve egzoz emisyonlarına etkileri deneysel olarak incelenmiştir. Al2O3 nanoparçacıkları 100 ppm konsantrasyonunda ve antioksidan katkı maddelerinin her biri 2000 ppm konsantrasyonunda B15 yakıtına eklenmiştir. Elde edilen katkılı yakıtlar ile katkı içermeyen dizel ve B15 yakıtı dört zamanlı ve tek silindirli bir dizel motorda test edilmiştir. Al2O3 nanoparçacıklarının tek başına yakıt katkısı olarak kullanıldığında motor performansının iyileştiği, CO, HC ve is emisyonlarının azaldığı ancak aynı çalışma şartlarında NOX emisyonunun ortalama %30.36 oranında arttığı belirlenmiştir. Al2O3 nanoparçacıklarının ve antioksidan katkı maddelerinin birlikte kullanılması durumunda NOX emisyonu ortalama %7.63 oranında azalmış ve B15 yakıtına çok yakın motor performans değerleri elde edilmiştir. NOX emisyonunun azaltılmasında TBHQ antioksidan katkı maddesinin diğer antioksidanlara göre daha etkili olduğu belirlenmiştir.

Keywords

Antioksidan Biyodizel Dizel motor Yakıt katkısı Nanoparçacık

Thanks

Biyodizel yakıtının temini için Kolza Biyodizel A.Ş.'ye ve yakıt numunelerinin analizi için sağladıkları teknik destekten dolayı OYAK Güzel Enerji Akaryakıt A.Ş. Samsun Yakıt Analiz Laboratuvarı çalışanlarına teşekkür ederiz.

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Investigation of the effects of Al2O3 nanoparticles and various antioxidant additives on a diesel engine characteristic

Year 2024, Volume: 13 Issue: 1, 223 - 235, 15.01.2024

Abdülvahap Çakmak

https://doi.org/10.28948/ngumuh.1284143

Abstract

In this study, the effects of the addition of aluminium oxide (AI2O3) nanoparticles and butyl hydroxytoluene (BHT), tertiary butyl hydroquinone (TBHQ) and clove essential oil (CEO) antioxidant additives to a diesel-biodiesel fuel mixture (B15) containing 15% by volume biodiesel on combustion characteristics, engine performance and exhaust emissions were investigated experimentally. Al2O3 nanoparticles at the dosage of 100 ppm and each of the antioxidant additives at a concentration of 2000 ppm were added to the B15 fuel. The obtained test fuels with additives and the additive-free diesel and B15 fuel were tested in a four-stroke and single-cylinder diesel engine. It is determined that when Al2O3 nanoparticles are used alone as a fuel additive, engine performance improves, CO, HC and soot emissions decrease, but NOx emission increases by an average of 30.36% under the same operating conditions. It is found that when Al2O3 nanoparticles and antioxidant additives are added together to fuel, NOx emission decreases by 7.63% on average and engine performance values are very close to those of B15 fuel. It is concluded that the TBHQ antioxidant additive is more effective than other antioxidants in NOx emission reduction.

Keywords

Antioxidant Biodiesel Diesel engine Fuel additive Nanoparticle

References

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  • M. A. Fazal, M. R. Jakeria, A. Haseeb and S. Rubaiee, Effect of antioxidants on the stability and corrosiveness of palm biodiesel upon exposure of different metals. Energy, 135, 220–226, 2017. https://doi.org/10.1016/j.energy.2017.06.128.
  • M. A. Fazal, A. Haseeb and H. H. Masjuki, Comparative corrosive characteristics of petroleum diesel and palm biodiesel for automotive materials. Fuel Processing Technology, 91, 1308–15, 2010. https://doi.org/10.1016/j.fuproc.2010.04.016.
  • R. K. Saluja, V. Kumar and R. Sham, Stability of biodiesel – A review. Renewable and Sustainable Energy Reviews, 62, 866–81, 2016. https://doi.org/10.1016/j.rser.2016.05.001.
  • M. Sui and F. Li, Effect of TEPA on oxidation stability and metal ion content of biodiesel. Renewable Energy, 143, 352–358, 2019. https://doi.org/10.1016/j.renene.2019.04.128.
  • G. Uğuz, A. Çakmak, C. da. Bento and N. Karakullukçu, Experimental investigation of fuel properties and engine operation with natural and synthetic antioxidants added to biodiesel. Biofuels, 14, 405–420, 2023. https://doi:10.1080/17597269.2022.2156049.
  • E. A. Decker, J. Alamed and I. A. Castro, Interaction between polar components and the degree of unsaturation of fatty acids on the oxidative stability of emulsions. Journal of the American Oil Chemists' Society, 87, 771–780, 2010. https://doi.org/10.1007/s11746-010-1556-3.
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  • F. Zhang, J. Li, S. Yang and Y. Bi, Inhibitory effect of antioxidants on biodiesel crystallization: Revealing the role of antioxidants. Fuel, 297, 120782, 2021. https://doi.org/10.1016/j.fuel.2021.120782.
  • J. B. Heywood, Internal combustion engine fundamentals. McGraw-Hill, New York, 1988.
  • C. P. Fenimore, The ratio NO2 NO in fuel-lean flames. Combustion and Flame, 25, 85–90, 1975. https://doi.org/10.1016/0010-2180(75)90071-1.
  • E. Ileri and G. Koçar, Experimental investigation of the effect of antioxidant additives on NOx emissions of a diesel engine using biodiesel. Fuel, 125, 44–49, 2014. https://doi.org/10.1016/j.fuel.2014.02.007.
  • H. Hosseinzadeh-Bandbafha, D. Kumar, B. Singh, H. Shahbeig, S. S. Lam and M. Aghbashlo, Biodiesel antioxidants and their impact on the behavior of diesel engines: A comprehensive review. Fuel Processing Technology, 232, 107264, 2022. https://doi.org/10.1016/j.fuproc.2022.107264.
  • M. G. Bidir, N. K. Millerjothi, M. S. Adaramola and F. Y. Hagos, The role of nanoparticles on biofuel production and as an additive in ternary blend fuelled diesel engine: A review. Energy Reports, 7, 3614–27, 2021. https://doi.org/10.1016/j.egyr.2021.05.084.
  • I. Sezer, Effect of nano materials additives on fuel properties and combustion characteristics. Journal of the Faculty of Engineering and Architecture of Gazi University, 34, 115–35 2019. https://doi.org/10.17341/gazimmfd.416469.
  • A. Tuan Hoang, M. Xuan Le, S. Nižetić, Z. Huang, Ü. Ağbulut and I. Veza, Understanding behaviors of compression ignition engine running on metal nanoparticle additives-included fuels: A control comparison between biodiesel and diesel fuel. Fuel, 326, 124981, 2022;. doi:https://doi.org/10.1016/j.fuel.2022.124981.
  • A. Yakın, R. Behcet, H. Solmaz and S. Halis, Testing sodium borohydride as a fuel additive in internal combustion gasoline engine. Energy, 254, 124300. 2022. https://doi.org/10.1016/j.energy.2022.124300.
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There are 63 citations in total.

Details

Primary Language Turkish
Subjects Mechanical Engineering
Journal Section Research Articles
Authors

Abdülvahap Çakmak 0000-0003-1434-6697

Early Pub Date December 11, 2023
Publication Date January 15, 2024
Submission Date April 16, 2023
Acceptance Date November 24, 2023
Published in Issue Year 2024 Volume: 13 Issue: 1

Cite

APA Çakmak, A. (2024). Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 13(1), 223-235. https://doi.org/10.28948/ngumuh.1284143
AMA Çakmak A. Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması. NOHU J. Eng. Sci. January 2024;13(1):223-235. doi:10.28948/ngumuh.1284143
Chicago Çakmak, Abdülvahap. “Al2O3 nanoparçacıklarının Ve çeşitli Antioksidan Katkı Maddelerinin Dizel Motor Karakteristiklerine Etkilerinin araştırılması”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 13, no. 1 (January 2024): 223-35. https://doi.org/10.28948/ngumuh.1284143.
EndNote Çakmak A (January 1, 2024) Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 13 1 223–235.
IEEE A. Çakmak, “Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması”, NOHU J. Eng. Sci., vol. 13, no. 1, pp. 223–235, 2024, doi: 10.28948/ngumuh.1284143.
ISNAD Çakmak, Abdülvahap. “Al2O3 nanoparçacıklarının Ve çeşitli Antioksidan Katkı Maddelerinin Dizel Motor Karakteristiklerine Etkilerinin araştırılması”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 13/1 (January 2024), 223-235. https://doi.org/10.28948/ngumuh.1284143.
JAMA Çakmak A. Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması. NOHU J. Eng. Sci. 2024;13:223–235.
MLA Çakmak, Abdülvahap. “Al2O3 nanoparçacıklarının Ve çeşitli Antioksidan Katkı Maddelerinin Dizel Motor Karakteristiklerine Etkilerinin araştırılması”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, vol. 13, no. 1, 2024, pp. 223-35, doi:10.28948/ngumuh.1284143.
Vancouver Çakmak A. Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması. NOHU J. Eng. Sci. 2024;13(1):223-35.
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