The Preparation of Controlled Release Fertilizer Based on Gelatin Hydrogel Including Ammonium Nitrate and Investigation of its Influence on Vegetable Growth
Yıl 2018,
Sayı: 2, 17 - 24, 19.08.2018
Mehlika Pulat
Nese Yoltay Saglam
Öz
A controlled release
fertilizer (CRF) systems
based on gelatin hydrogel was prepared to improve
fertilizer use efficiency and minimize its negative impact on environment. Gelatin hydrogel was synthesized by using
glutaraldehyde (GA) as crosslinker and its swelling/degradation behaviors were
investigated. Ammonium nitrate (AN) was loaded into the gelatin hydrogel and
its releasing was followed. Release of AN from gelatin beads versus time was
followed, and it is found that the release gently increased at first and then
complied between 40-50 h. The releasing date shows that the prepared AN/gelatin
hydrogel system could be named as a CRF. The efficiency of gelatin hydrogel
beads including AN were examined on the vegetable growing using cucumber seeds.
Plant growth and stem elongations measurements presents the formed hydrogel
beads could be successfully used as a CRF system. It
can be concluded that the CRF system produced in this study is much promising
in utilizing a natural resource like gelatin in the production of matrix
material, which could significantly reduce the production costs and offer a
quite environmental friendly alternative technique.
Kaynakça
- Al-Zahrani S.M. (1999). Controlled-release of fertilizers: modelling and simulation. Int. J. Eng. Sci. 37, 1299-1307.
Bajpai A.K., Giri A. (2002). Swelling dynamics of a macromolecular hydrophilic network and evaluation of its potential for controlled release of agrochemicals. React. Func. Polym. 53, 125-141.
Bigi A., Cojazzi G., Panzavolta S., Rubini K., Roveri N. (2001). Mechanical and ther¬mal properties of gelatin films at different degrees of glutaraldehyde crosslinking. Biomat. 22, 763-768.
Chandra R., Rustgi R. (1998). Biodegradable polymers. Prog. Polym. Sci .23, 273-1335.
Chen K., Ku Y., Lin H., Yan T., Sheu D., Chen T., Lin F. (2005). Preparation and char¬acterization of pH-sensitive poly (N-vinyl 2-pyrrolidone/itaconic acid) copolymer hydrogels. Mat. Chem. Phys. 91, 484-489.
Corradini E., De Moura M.R., Mattoso L.H.C. (2010). A preliminary study of the incorpo¬ration of NPK fertilizer into chitosan nanoparticles. Exp. Polymer Lett. 4, 509-515.
Jayarambabu N, Siva Kumari B, Venkateswara Rao K, Prabhu YT.(2016). Enhancement of growth ın maıze by bıogenıc- synthesızed mgo nanopartıcles, International Journal of Pure and Applied Zoology, 4, 3: 262-270.
Ni B., Liu M., Lu S. (2007). Multifunctional slow-release urea fertilizer from ethylcellulose and superabsorbent coated formulations. Chem. Eng. J. 155, 892-898.
Pulat M., Asıl D. (2009). Fluconazole release through semi-ipn hydrogels based on chitosan, AA, and citraconic acid. J. Appl. Polym. Sci. 113, 2613-2619.
Pulat M., Tan N., Onurdağ F.K. (2011). Swelling dynamics of IPN hydrogels including acrylamide-acrylic acid-chitosan and evaluation of their potential for controlled release of piperacillin-tazobactam. J. Appl. Polym. Sci. 120, 441-450.
Pulat M., Akalın G.O. (2013). Preparation and characterization of gelatin hydrogel support for immobilization of C. Rugosa lipase. Artif. Cells Nanomed. Biotechnol. 41, 145-151.
Pulat M., Akalın G.O, Demirkol Karahan N. (2014). Lipase release through semi-interpenetrating polymer network hydrogels based on chitosan, acrylamide, and citraconic acid. Artif. Cells Nanomed. Biotechnol. 42, 121-127.
Rafaat A.I, Eid M., El-Arnaouty M.B. (2012). Radiation synthesis of superabsorbent CMC based hydrogels for agriculture applications. Nucl. Instr. Meth. Phys. Res. B 283, 71-76.
Trenkel M.E. (2007). Controlled release fertilizers: trends and technologies. Pharmaceutica. 5, 1-15
Yıl 2018,
Sayı: 2, 17 - 24, 19.08.2018
Mehlika Pulat
Nese Yoltay Saglam
Kaynakça
- Al-Zahrani S.M. (1999). Controlled-release of fertilizers: modelling and simulation. Int. J. Eng. Sci. 37, 1299-1307.
Bajpai A.K., Giri A. (2002). Swelling dynamics of a macromolecular hydrophilic network and evaluation of its potential for controlled release of agrochemicals. React. Func. Polym. 53, 125-141.
Bigi A., Cojazzi G., Panzavolta S., Rubini K., Roveri N. (2001). Mechanical and ther¬mal properties of gelatin films at different degrees of glutaraldehyde crosslinking. Biomat. 22, 763-768.
Chandra R., Rustgi R. (1998). Biodegradable polymers. Prog. Polym. Sci .23, 273-1335.
Chen K., Ku Y., Lin H., Yan T., Sheu D., Chen T., Lin F. (2005). Preparation and char¬acterization of pH-sensitive poly (N-vinyl 2-pyrrolidone/itaconic acid) copolymer hydrogels. Mat. Chem. Phys. 91, 484-489.
Corradini E., De Moura M.R., Mattoso L.H.C. (2010). A preliminary study of the incorpo¬ration of NPK fertilizer into chitosan nanoparticles. Exp. Polymer Lett. 4, 509-515.
Jayarambabu N, Siva Kumari B, Venkateswara Rao K, Prabhu YT.(2016). Enhancement of growth ın maıze by bıogenıc- synthesızed mgo nanopartıcles, International Journal of Pure and Applied Zoology, 4, 3: 262-270.
Ni B., Liu M., Lu S. (2007). Multifunctional slow-release urea fertilizer from ethylcellulose and superabsorbent coated formulations. Chem. Eng. J. 155, 892-898.
Pulat M., Asıl D. (2009). Fluconazole release through semi-ipn hydrogels based on chitosan, AA, and citraconic acid. J. Appl. Polym. Sci. 113, 2613-2619.
Pulat M., Tan N., Onurdağ F.K. (2011). Swelling dynamics of IPN hydrogels including acrylamide-acrylic acid-chitosan and evaluation of their potential for controlled release of piperacillin-tazobactam. J. Appl. Polym. Sci. 120, 441-450.
Pulat M., Akalın G.O. (2013). Preparation and characterization of gelatin hydrogel support for immobilization of C. Rugosa lipase. Artif. Cells Nanomed. Biotechnol. 41, 145-151.
Pulat M., Akalın G.O, Demirkol Karahan N. (2014). Lipase release through semi-interpenetrating polymer network hydrogels based on chitosan, acrylamide, and citraconic acid. Artif. Cells Nanomed. Biotechnol. 42, 121-127.
Rafaat A.I, Eid M., El-Arnaouty M.B. (2012). Radiation synthesis of superabsorbent CMC based hydrogels for agriculture applications. Nucl. Instr. Meth. Phys. Res. B 283, 71-76.
Trenkel M.E. (2007). Controlled release fertilizers: trends and technologies. Pharmaceutica. 5, 1-15