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Extraction of Heavy Metals using Dithizone Method on Seawater

Yıl 2018, Sayı: 2, 429 - 434, 19.08.2018

Öz

Research
conducted is related to the preparation and characterization of dithizone
method based on extraction of cadmium, lead and zinc trace metals from seawater
samples. Inorganic metals or ions can act back with dithizone to produce
colourful coordination. The dithizone reagent is highly sensitive to the
presence of heavy metals such as plumbum (Pb), cadmium (Cd) and zinc (Zn) as
designated in this study. Inorganic metals or ionic can react with dithizone to
produce colored coordination compounds. The resulting dithizoneate may be
extracted with an organic solvent such as carbon tetrachloride (CCl4).
This study also involves steps such as adjusting the pH value in order to
produce the dithizoneate metal product we need. In this study, metal powders
were dissolved in seawater samples and extracted with dithizone to enhance the
detection and extraction facilities. We analyze trace metals carried out by
plasma atomic emission spectroscopy (ICP-OES) to see the efficiency of
dithizone extraction methods into seawater samples used. Dithizone extraction method used in extracting Pb element indicates a good
performance.

Kaynakça

  • Satyanarayanan M., Balaram V., Gnaneshwar T., Dasaram B., Ramesh S. L., Ramavati Mathur dan Drolia R. K.. 2006. Determination of trace metals in seawater by ICP-MS after preconcentration matrix separation by dithiocarbamate complexes. Indian Journal of Marine Sciences (36): 71-75. Hiraide M., Yoshida Y dan Mizuike A. 1976. Flotation of traces of heavy metals coprecipitated with aluminium hydroxide from water and seawater. Anal. Chim. Acta (81): 185-189. Sturgeon R. E. dan Berman S.S.. 1980. Preconcentration of trace metals from seawater for determination by graphite furnace atomic-absorption spectrometry. Talanta (27): 85-94. Danielsson L.G., Magnusson B., Westerlund S. dan Zhang K.. 1982. Trace metal determination in estuarine waters by electrothermal atomic absorption spectrometry after extraction with dithiocarbamate complexes from freon. Anal. Chim. Acta (144): 183-188. Sachhsenberg S., Klenrike Th., Krumbein W. E. dan Zeeck E., 1992. A back extraction procedure method: Rapid determination of metals in seawater matrices. Fresenius J. Anal. Chem (342): 163-166. Jan T. K. dan Young D. R.. 1978. Determination of microgram amounts of some transition metals in seawater by methyl isobutyl ketone-nitric acid successive extraction and flameless atomic absorption spectrophotometry. Anal. Chem. (50): 1250-1253. Wu J. dan Boyle E. A.. 1997. Low blank preconcentration technique for the determination of lead, copper and cadmium in a small volme seawater by isotope dilution ICPMS. Anal. Chem. (69): 2464-2470. Chandrasekhar K., Chary S. N., Kamala C. T. dan Apama V. 2003. Determination of trace metals in seawater by induced coupled mass spectrometry with preconcentration on silica-immobilized 8-hydroxyquinoline. Anal Chem. (57): 2907-2911. Jong M. L., Edward A., Boyle A., Yolanda Echegoyen-Sanz, Jessica N.,Fitzsimmons, Ruifeng Zhang dan Richard A. Kayser. 2010. Analysis of trace metals (Cu, Cd, Pb, and Fe) in seawater using single batch nitrilotriacetate resin extraction and isotope dilution inductively coupled plasma mass spectrometry. Anal. Chim. Acta. (686): 93-101. Mark L. Wells dan Kenneth W. Bruland. 1998. An improved method for rapid preconcentration and determination of bioactive trace metals in seawater using solid phase extraction and high resolution inductively coupled plasma mass spectrometry. Marine Chemistry (63): 145-153. Tessier A., Campbell P. G. C. dan Bisson M.. 1979. Sequential extraction procedure for the speciation of particulate trace metals. Analytical Chemistry (51): 844-851. Antun Kucak dan Maja Blanusa. 1998. Comparison of two extraction procedures for determination of trace metals in soil by atomic absorption spectrometry. Arh hig rada toksikol (49): 327-334. Bert L. Vanllee dan John G. Gibson. 1948. An improved method for the determination of small quantities of zinc in blood and tissue samples. Microdetermination of Zinc in Blood.: 435-449.
Yıl 2018, Sayı: 2, 429 - 434, 19.08.2018

Öz

Kaynakça

  • Satyanarayanan M., Balaram V., Gnaneshwar T., Dasaram B., Ramesh S. L., Ramavati Mathur dan Drolia R. K.. 2006. Determination of trace metals in seawater by ICP-MS after preconcentration matrix separation by dithiocarbamate complexes. Indian Journal of Marine Sciences (36): 71-75. Hiraide M., Yoshida Y dan Mizuike A. 1976. Flotation of traces of heavy metals coprecipitated with aluminium hydroxide from water and seawater. Anal. Chim. Acta (81): 185-189. Sturgeon R. E. dan Berman S.S.. 1980. Preconcentration of trace metals from seawater for determination by graphite furnace atomic-absorption spectrometry. Talanta (27): 85-94. Danielsson L.G., Magnusson B., Westerlund S. dan Zhang K.. 1982. Trace metal determination in estuarine waters by electrothermal atomic absorption spectrometry after extraction with dithiocarbamate complexes from freon. Anal. Chim. Acta (144): 183-188. Sachhsenberg S., Klenrike Th., Krumbein W. E. dan Zeeck E., 1992. A back extraction procedure method: Rapid determination of metals in seawater matrices. Fresenius J. Anal. Chem (342): 163-166. Jan T. K. dan Young D. R.. 1978. Determination of microgram amounts of some transition metals in seawater by methyl isobutyl ketone-nitric acid successive extraction and flameless atomic absorption spectrophotometry. Anal. Chem. (50): 1250-1253. Wu J. dan Boyle E. A.. 1997. Low blank preconcentration technique for the determination of lead, copper and cadmium in a small volme seawater by isotope dilution ICPMS. Anal. Chem. (69): 2464-2470. Chandrasekhar K., Chary S. N., Kamala C. T. dan Apama V. 2003. Determination of trace metals in seawater by induced coupled mass spectrometry with preconcentration on silica-immobilized 8-hydroxyquinoline. Anal Chem. (57): 2907-2911. Jong M. L., Edward A., Boyle A., Yolanda Echegoyen-Sanz, Jessica N.,Fitzsimmons, Ruifeng Zhang dan Richard A. Kayser. 2010. Analysis of trace metals (Cu, Cd, Pb, and Fe) in seawater using single batch nitrilotriacetate resin extraction and isotope dilution inductively coupled plasma mass spectrometry. Anal. Chim. Acta. (686): 93-101. Mark L. Wells dan Kenneth W. Bruland. 1998. An improved method for rapid preconcentration and determination of bioactive trace metals in seawater using solid phase extraction and high resolution inductively coupled plasma mass spectrometry. Marine Chemistry (63): 145-153. Tessier A., Campbell P. G. C. dan Bisson M.. 1979. Sequential extraction procedure for the speciation of particulate trace metals. Analytical Chemistry (51): 844-851. Antun Kucak dan Maja Blanusa. 1998. Comparison of two extraction procedures for determination of trace metals in soil by atomic absorption spectrometry. Arh hig rada toksikol (49): 327-334. Bert L. Vanllee dan John G. Gibson. 1948. An improved method for the determination of small quantities of zinc in blood and tissue samples. Microdetermination of Zinc in Blood.: 435-449.
Toplam 1 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Leong Kok Seng

Yayımlanma Tarihi 19 Ağustos 2018
Yayımlandığı Sayı Yıl 2018Sayı: 2

Kaynak Göster

APA Kok Seng, L. (2018). Extraction of Heavy Metals using Dithizone Method on Seawater. The Eurasia Proceedings of Science Technology Engineering and Mathematics(2), 429-434.