Preparation of Activated Carbon From Waste Cooked Tea for Using as Chemical Dyes – Filter

Yıl 2018, Sayı: 4, 15 - 20, 04.12.2018

Kafa Khalaf Hammud Ruaa Mohammed Aboob Mustafa Salah Hassan Duraid Essa Zanad Mohammed Hashem Khalil

Öz

Eco-friedly
adsorption material was prepared from waste cooked tea and characterized by
spectroscopic techniques. The target of this work was using this activated
carbon as multi-use filtration disc that may be applied in life and science.
The action of newly multi-adsorption filter disc was evaluated though the
UV-Vis measurements of methylene blue adsorption. This multi-adsorption filter
disc contained activated carbon prepared from waste cooked tea with / or
without silica gel presence. The removal percentage (R%) and adsorption
capacities (Q) values were more than 99% and 
496 mg/g respectively for all repeated times. Presence of silica gel in
filter disc accompanied by our prepared activated carbon was unchangable in dye
removing quantities so silica gel can be dispended and the filter disc was
satisfied with our prepared activated carbon. Also, this multi- adsorption
filter can be introduced as a promising investment in adsorption technology or
equipments. The obtained data showed the privilege of this filter in both cases
especially in the absence of silica gel. Also, the removal percentage and
adsorption capacity demonstrated the superiority of the prepared filter.

Anahtar Kelimeler

Activated carbon, Methylene blue, Adsorption, Filter disc, Pollution

Kaynakça

• AlSlaibi T, Abustan I, Ahmad M and Abu Foul A. (2013a). A Review: Production of Activated Carbon from Agricultural byproducts via Conventional and Microwave Heating. J. Chem. Technol. Biotechnol. 88(7):1183-1190. Al-Slaibi T, Abustan I, Ahmad M and Abu Foul A. (2013b). Cadmium Removal from Aqueous Solution Using Microwaved Olive Stone Activated Carbon. J. Environ. Chem. Eng. 1(3):589- 599. Cabal B, Budinova T, Ania C, Tsyntsarski B, Parra J and Petrova B. (2008). Adsorption of Naphthalene from Aqueous Solution on Activated Carbons Obtained from Bean Pods. J. Hazard Mater. 161(2-3): 1150- 1156. Duran, C., Ozdes, D., Gundogdu, A., Imamoglu, M., and Senturk, H. (2011). Tea – industry waste activated carbon, as a novel adsorbent, for separation preconcentration and speciation of chromium. Anal. Chim. Acta 688(1), 75-83. Fadhil, A., Dheye, M., and Abdul-Qader, A. (2012). Purification of biodiesel using activated carbons produced from spent tea waste. J. Assoc. Arab Univ. Basic Appl. Sci. 11(1), 45-49. Gundogdu, A., Duran, Senturk, Soylak, H., Imamoglu, M., and Onal, Y. (2013). Physicochemical characteristics of a novel activated carbon produced from tea industry waste, J. Anal. App. Pyrol. 2013, 104, 249-259. Hameed B and El-Khaiary M. (2008). Equilibrium, Kinetics, and Mechanism of Malachite Green Adsorption on Activated Carbon Prepared from Bamboo by K2CO3 Activation and Subsequent Gasification with CO2. J. Hazard Mater. 157(2-3):344-351. Hameed B, Tan I and Ahmad A. (2008). Adsorption Isotherm, Kinetic Modeling, and Mechanism of 2,4,6- Trichlorophenol on Conconut Husk Based Activated Carbon. Chem. Eng J. 144(2): 235-244. Hammud K, Kadham E, Raouf A, Neema R, and Al-Sammarrie A. (2016b). FTIR, XRD, AFM, AND SEM Spectroscopic Studiesof Chemically MW- Waste Cooked Tea Activated Carbon. Int. J. Res. Pharm. Chem. 2016b, 6(3), 543-555. Hammud K, Raouf A, Al-Sammarrie A, and Neema R. (2016a). New Chemically Prepared-Waste Cooked Tea Based Activated Carbon: FTIR, XRD, AFM, and SEM Spectroscopic Studies. Int. J. Res. Pharm. Chem. 6(2), 220-229. Klijanienko A Lorenc-Grabowska E and Gryglewicz G. (2008). Development of Mesoporosity during Phosphoric Acid Activation of Wood in Steam Atmosphere. Bioresour Technol. 99(15): 7208-7214. Petrov N, Budinova T, Razvigorova J and Parra P. (2008). Conversion of Olive Waste to Volatiles and Carbon Adsorbents. Biomass Bioenerg. 32(12):1303-1310. Rauof A, Hammud K, Mohammed J, Akosh N, Hamza F, Hassan M, Omran N, Zanad D and Ammen E. (2015). Removal of Benzene and Toluene from their Polluted Aqueous solutions by using Natural Adsorbent. Third Iraq Oil and Gas Conference, Amara, Iraq, 28-29. October. Román S, González J, GonzálezGarcía C and Zamora F. (2008). Control of Pore Development During CO2 and Steam Activation of Olive Stones. Fuel Process. Technol. 89(8):715- 720. Singh C, Sahu J, Mahalik K, Mohanty C, Mohan B and Meikap B. (2008). Studies on the Removal of Pb(II) from Wastewater by Activated Carbon developed from Tamarind Wood Activated with Sulfuric Acid. J. Hazard Mater. 153(1-2):221-228. Tan I, Ahmad A and Hameed B. (2008). Adsorption of basic Dye on HighSurface-Area Activated Carbon Prepared from Coconut Husk: Equilibrium, Kinetic, and Thermodynamic Studies. J. Hazard Mater. 154(1-3):337-346. Ugurlu M, Gurses A and Acikyildiz A. (2008). Comparison of Textile Dyeing Effluent Adsorption on Commercial Activated Carbon and Activated Carbon Prepared from Olive Stone by ZnCl2 Activation. Microporous Mesoporous Mater. 111(1-3):228-235. Urabe Y, Ishikura T and Kaneko K. (2008). Development of Porosity in Carbons from Yeast Grains by Activation with Alkali metal Carbonates. J. Colloid Interface Sci. 319(1):381-383. Zhong Z, Yang Q, Li X, Luo Liu Y, and Zeng G. (2012). Preparation of Peanut hullbased activated carbon by Microwave Induced Phosphoric acid activation and its application in Remazol Brilliant Blue R adsorption. Ind. Crops Prod. 37(1):178-185.