Araştırma Makalesi
BibTex RIS Kaynak Göster
Yıl 2017, Cilt: 30 Sayı: 3, 245 - 254, 20.09.2017

Öz

Kaynakça

  • Murhekar, M. M., Khadsan, R. E. “Synthesis of Schiff bases by organic free solvent method.” J. Chem. Pharm. Res., 3(6):846-849, (2011).

Synthesis, Spectroscopic and Computational Studies of (E)-2-(2,3-dihydroxy)-benzylidene)amino)-6-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile

Yıl 2017, Cilt: 30 Sayı: 3, 245 - 254, 20.09.2017

Öz

Aromatic/heteroaromatic Schiff base was synthesized by the reaction of 2-amino-6-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile with 2,3-dihydroxybenzaldehyde. Titled compound was characterized by elemental analysis, FT-IR, 1H NMR, 13C-APT NMR and single crystal X-ray diffraction methods. Imine compound was crystallized in triclinic crystal system with space group P-1. X-ray studies reveal that our molecule is stabilized by O-H···N and C-H···O hydrogen bonds and intermolecular π∙∙∙π interactions. The molecular structure of Schiff base was optimized by density functional theory (DFT) method using B3LYP/6-311+G(2d,p) quantum set in Gaussian 09W software program. The chemical shifts and geometrical parameters were also computed by the same quantum level and compared with the experimental results of (E)-2-(2,3-dihydroxy)-benzylidene)amino)-6-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile.

Kaynakça

  • Murhekar, M. M., Khadsan, R. E. “Synthesis of Schiff bases by organic free solvent method.” J. Chem. Pharm. Res., 3(6):846-849, (2011).
Toplam 1 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Chemistry
Yazarlar

Naki Çolak

Saliha Altıner Bu kişi benim

Zarife Sibel Şahin

Ayla Balaban Gündüzalp

Yayımlanma Tarihi 20 Eylül 2017
Yayımlandığı Sayı Yıl 2017 Cilt: 30 Sayı: 3

Kaynak Göster

APA Çolak, N., Altıner, S., Şahin, Z. S., Balaban Gündüzalp, A. (2017). Synthesis, Spectroscopic and Computational Studies of (E)-2-(2,3-dihydroxy)-benzylidene)amino)-6-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile. Gazi University Journal of Science, 30(3), 245-254.
AMA Çolak N, Altıner S, Şahin ZS, Balaban Gündüzalp A. Synthesis, Spectroscopic and Computational Studies of (E)-2-(2,3-dihydroxy)-benzylidene)amino)-6-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile. Gazi University Journal of Science. Eylül 2017;30(3):245-254.
Chicago Çolak, Naki, Saliha Altıner, Zarife Sibel Şahin, ve Ayla Balaban Gündüzalp. “Synthesis, Spectroscopic and Computational Studies of (E)-2-(2,3-Dihydroxy)-benzylidene)amino)-6-Methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-Carbonitrile”. Gazi University Journal of Science 30, sy. 3 (Eylül 2017): 245-54.
EndNote Çolak N, Altıner S, Şahin ZS, Balaban Gündüzalp A (01 Eylül 2017) Synthesis, Spectroscopic and Computational Studies of (E)-2-(2,3-dihydroxy)-benzylidene)amino)-6-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile. Gazi University Journal of Science 30 3 245–254.
IEEE N. Çolak, S. Altıner, Z. S. Şahin, ve A. Balaban Gündüzalp, “Synthesis, Spectroscopic and Computational Studies of (E)-2-(2,3-dihydroxy)-benzylidene)amino)-6-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile”, Gazi University Journal of Science, c. 30, sy. 3, ss. 245–254, 2017.
ISNAD Çolak, Naki vd. “Synthesis, Spectroscopic and Computational Studies of (E)-2-(2,3-Dihydroxy)-benzylidene)amino)-6-Methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-Carbonitrile”. Gazi University Journal of Science 30/3 (Eylül 2017), 245-254.
JAMA Çolak N, Altıner S, Şahin ZS, Balaban Gündüzalp A. Synthesis, Spectroscopic and Computational Studies of (E)-2-(2,3-dihydroxy)-benzylidene)amino)-6-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile. Gazi University Journal of Science. 2017;30:245–254.
MLA Çolak, Naki vd. “Synthesis, Spectroscopic and Computational Studies of (E)-2-(2,3-Dihydroxy)-benzylidene)amino)-6-Methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-Carbonitrile”. Gazi University Journal of Science, c. 30, sy. 3, 2017, ss. 245-54.
Vancouver Çolak N, Altıner S, Şahin ZS, Balaban Gündüzalp A. Synthesis, Spectroscopic and Computational Studies of (E)-2-(2,3-dihydroxy)-benzylidene)amino)-6-methyl-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carbonitrile. Gazi University Journal of Science. 2017;30(3):245-54.