BibTex RIS Kaynak Göster

Investigation of Swelling, Adsorption and Mechanical Properties of Sodium Acrylate Based Hydrogel and Cryogels

Yıl 2014, Cilt: 20 Sayı: 7, 258 - 265, 01.07.2014

Öz

In this study, swelling behavior (swelling capacity, equilibrium swelling ratio and swelling kinetics), basic dye (methylene blue) adsorption and mechanical properties of sodium acrylate based hydrogel and cryogels were comparatively investigated. Kinetic parameters were determined using linear and non-linear methods. In addition, the surface morphologies of cryogel and hydrogel structures were characterized using by Scanning Electron Microscopy (SEM). All results obtained from analyses were comparatively evaluated.

Kaynakça

  • Byrne ME, Park K, Peppas NA. “Molecular Imprinting Within Hydrogels”. Advanced Drug Delivery Reviews, 54(1), 149-161, 2002.
  • Özkahraman B. Sıcaklığa Duyarlı Kopolimerik Hidrojeller ile Sulardan Boyar Madde ve Ağır Metal Uzaklaştırılması. Yüksek Lisans Tezi, İstanbul Üniversitesi, İstanbul, Türkiye, 2009.
  • Ceylan D, Özmen MM, Okay O. “Swelling–Deswelling Kinetics of Ionic Poly(acrylamide) Hydrogels and Cryogels”. Journal of Applied Polymer Science, 99(1), 319- 325, 2006.
  • Kathuria N, Tripathi A, Kar KK, Kumar A. “Synthesis and Characterization of Elastic and Macroporous Chitosan– Gelatin Biomaterialia, 5(1), 406-418, 2009. Tissue Engineering”. Acta
  • Kwon SM, Kim HS, Jin HJ. “Fabrication of Organic Silk Carbon Fibroin/Multiwalled Cryogels by Freeze-Drying Method”. Advanced Materials Research, 47-50, 1105-1108, 2008. Nanotube Composite
  • Petrov P, Utrata-Wesolek A, Trzebicka B, Tsvetanov CB, Dworak A, Aniol J, Sieron A. “Biocompatible Cryogels of Thermosensitive Polyglycidol Derivatives with Ultra- Rapid Swelling Properties”. European Polymer Journal, 47(5), 981-988, 2011.
  • Bereli GN, Şener G, Altıntaş EB, Yavuz H, Denizli A. “Poly(glycidyl methacrylate) Beads Embedded Cryogels for Pseudo-Specific Affinity Depletion of Albumin and Immunoglobulin”. Materials Science and Engineering: C, 30(2), 323-329, 2010.
  • Topuz F, Okay O. “Macroporous Hydrogel Beads of High Toughness and Superfast Responsivity”. Reactive and Functional Polymers, 69(5), 273-280, 2009.
  • Dinu MV, Ozmen MM, Dragan ES, Okay O. “Freezing as a Path to Build Macroporous Structures: Superfast Responsive Polyacrylamide Hydrogels”. Polymer, 48(1), 195-204, 2007.
  • Gordon MJ, Chu KC, Margaritis A, Martin AJ, Ethier CR, Rutt BK. “Measurement of Gd-DTPA Diffusion Through PVA Hydrogel Using a Novel Magnetic Resonance Imaging Method”. Biotechnology and Bioengineering, 65(4), 459- 467, 1999.
  • Chu KC, Jordan KJ, Battista JI, Dyk JV, Rutt BK. “Polyvinyl Alcohol–Fricke Hydrogel and Cryogel: Two New Gel Dosimetry Systems With Low Fe3+ Diffusion”. Physics in Medicine and Biology, 45(4), 955-969, 2000.
  • Altunina LK, Manzhai BN, Fufaeva MS. “Mechanical and Thermal Properties of Cryogels and Foamed Cryogels Produced From Aqueous Solutions of Poly(vinyl alcohol)”, Russian Journal of Applied Chemistry, 79(10), 1669-1672, 2006.
  • Özmen MM, Dinu MV, Dragan ES, Okay O. “Preparation of Macroporous Acrylamide‐Based Hydrogels: Cryogelation Under Isothermal Conditions”. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 44(11), 1195- 1202, 2007.
  • Srivastava A, Jain E, Kumar A. “The Physical Characterization (N-isopropylacrylamide) Cryogel: Mechanical Strength and Swelling/de-Swelling Kinetics”, Materials Science and Engineering: A, 464(1-2), 93-100, 2007. Poly
  • Dispinar T, Camp WV, De Cock LJ, De Geest BG, Du Prez, FE. “Redox-Responsive Degradable Peg Cryogels as Potential Macromolecular Bioscience, 12(3), 383-394, 2012. in Tissue Engineering”.
  • Shukla NB, Madras G. “Reversible Swelling/Deswelling Characteristics of Ethylene Glycol Dimethacrylate Cross- Linked acrylamide) Superabsorbents”. Industrial & Engineering Chemistry Research, 50(19), 10918-10927, 2011.
  • acid-co-sodium acrylateco
  • Berillo D, Elowsson L, Kirsebom H. “Oxidized Dextran as Crosslinker for Chitosan Cryogel Scaffolds and Formation of Polyelectrolyte Complexes Between Chitosan and Gelatin”. Macromolecular Bioscience, 12(8), 1090-1099, 2012.
  • Al E, Güçlü G, İyim TB, Emik S, Özgümüş S. “Synthesis and Properties Montmorillonite Superabsorbent
  • Hydrogels”. Journal of Applied Polymer Science, 109(1), 16-22, 2008. Acid/Na- Nanocomposite
  • Lopes CMA, Felisberti MI. “Mechanical Behavior and Biocompatibility of Poly(1-vinyl-2-pyrrolidinone)-Gelatin IPN hydrogels”. Biomaterials, 24(7), 1279-1284, 2003.
  • Jin S, Bian F, Lin M, Chen S, Liu H. “Swelling Mechanism of Porous P(VP-co-MAA)/PNIPAM Semi-IPN Hydrogels With Various Pore Size Prepared by a Freeze Treatment”. Polymer International, 58(2), 142-148, 2009.
  • Escobar JL, Garcia D, Valerino A, Zaldivar D, Hernaez release dimethylacrylamide) hydrogels”. Journal of Applied Polymer Science. 91(6), 3433-3437, 2004. sodium acrylamide-co-N,N
  • Muniz EC, Geuskens G. “Compressive Elastic Modulus of Polyacrylamide Hydrogels and Semi-IPNs with poly(N- Isopropylacrylamide)”. Macromolecules, 34(13), 4480- 4484, 2001.
  • Paulino AT, Guilherme MR, Reis AV, Campase GM, Muniz, EC, Nozaki J. “Removal of Methylene Blue Dye From an Aqueous Supported on Modified Polysaccharide”. Journal of Colloid and Interface Science, 301(1), 55-62, 2006.
  • Superabsorbent Hydrogel
  • Chen H, Wang A. “Adsorption Characteristics of Cu(II) From poly(acrylamide)/attapulgite composite”. Journal of Hazardous Materials, 165(1-3), 223-231, 2009. Solution Onto
  • Ho YS, “Citation Review of Lagergren Kinetic Rate Equation on Adsorption Reactions”. Scientometrics, 59(1), 171-177, 2004.
  • Ho YS, Chiang CC. “Sorption Studies of Acid Dye by Mixed Sorbents”. Adsorption, 7(2), 139-147, 2001.
  • Chowdhury S, Das Saha, P. “Comparative Analysis of Linear and Nonlinear Methods of Estimating the Pseudo- Second-order Kinetic Parameters for Sorption of Malachite Bioremediation Journal, 15(4), 181-188, 2011. Pretreated Rice Husk”.
  • Lin J, Wang L. “Comparison Between Linear and Non- Linear Forms of Pseudo-first-Order and Pseudo-Second- Order Adsorption Kinetic Models for the Removal of Methylene Blue by Activated Carbon”. Frontiers of Environmental Science&Engineering in China, 3(3), 320- 324, 2009.
  • Knaebel A, Rebre SR, Lequeux F. “Determination of the Elastic Modulus of Superabsorbent gel Beads”. Polymer Gels and Networks, 5(2), 107-121, 1997.
  • Bajpai SK, Johnson S. “Superabsorbent Hydrogels for Removal of Divalent Toxic Ions. Part I: Synthesis and Swelling Characterization”. Reactive and Functional Polymers, 62(3), 271-283, 2005.

Sodyum Akrilat Esaslı Hidrojel ve Kriyojellerin Şişme, Adsorpsiyon ve Mekanik Özelliklerinin İncelenmesi

Yıl 2014, Cilt: 20 Sayı: 7, 258 - 265, 01.07.2014

Öz

Bu çalışmada, sodyum akrilat esaslı hidrojel ve kriyojellerin şişme davranışları (şişme kapasitesi, denge şişme değeri ve şişme kinetiği), boyar madde (metilen mavisi) adsorpsiyonu ve mekanik özellikleri karşılaştırmalı olarak incelenmiştir. Kinetik paramatreler, doğrusal ve doğrusal olmayan metotlar kullanılarak belirlenmiştir. Buna ek olarak, kriyojel ve hidrojel yapıların yüzey morfolojileri, taramalı elektron mikroskobu (SEM) kullanılarak karakterize edilmiştir. Analizlerden elde edilen tüm sonuçlar karşılaştırmalı olarak değerlendirilmiştir.

Kaynakça

  • Byrne ME, Park K, Peppas NA. “Molecular Imprinting Within Hydrogels”. Advanced Drug Delivery Reviews, 54(1), 149-161, 2002.
  • Özkahraman B. Sıcaklığa Duyarlı Kopolimerik Hidrojeller ile Sulardan Boyar Madde ve Ağır Metal Uzaklaştırılması. Yüksek Lisans Tezi, İstanbul Üniversitesi, İstanbul, Türkiye, 2009.
  • Ceylan D, Özmen MM, Okay O. “Swelling–Deswelling Kinetics of Ionic Poly(acrylamide) Hydrogels and Cryogels”. Journal of Applied Polymer Science, 99(1), 319- 325, 2006.
  • Kathuria N, Tripathi A, Kar KK, Kumar A. “Synthesis and Characterization of Elastic and Macroporous Chitosan– Gelatin Biomaterialia, 5(1), 406-418, 2009. Tissue Engineering”. Acta
  • Kwon SM, Kim HS, Jin HJ. “Fabrication of Organic Silk Carbon Fibroin/Multiwalled Cryogels by Freeze-Drying Method”. Advanced Materials Research, 47-50, 1105-1108, 2008. Nanotube Composite
  • Petrov P, Utrata-Wesolek A, Trzebicka B, Tsvetanov CB, Dworak A, Aniol J, Sieron A. “Biocompatible Cryogels of Thermosensitive Polyglycidol Derivatives with Ultra- Rapid Swelling Properties”. European Polymer Journal, 47(5), 981-988, 2011.
  • Bereli GN, Şener G, Altıntaş EB, Yavuz H, Denizli A. “Poly(glycidyl methacrylate) Beads Embedded Cryogels for Pseudo-Specific Affinity Depletion of Albumin and Immunoglobulin”. Materials Science and Engineering: C, 30(2), 323-329, 2010.
  • Topuz F, Okay O. “Macroporous Hydrogel Beads of High Toughness and Superfast Responsivity”. Reactive and Functional Polymers, 69(5), 273-280, 2009.
  • Dinu MV, Ozmen MM, Dragan ES, Okay O. “Freezing as a Path to Build Macroporous Structures: Superfast Responsive Polyacrylamide Hydrogels”. Polymer, 48(1), 195-204, 2007.
  • Gordon MJ, Chu KC, Margaritis A, Martin AJ, Ethier CR, Rutt BK. “Measurement of Gd-DTPA Diffusion Through PVA Hydrogel Using a Novel Magnetic Resonance Imaging Method”. Biotechnology and Bioengineering, 65(4), 459- 467, 1999.
  • Chu KC, Jordan KJ, Battista JI, Dyk JV, Rutt BK. “Polyvinyl Alcohol–Fricke Hydrogel and Cryogel: Two New Gel Dosimetry Systems With Low Fe3+ Diffusion”. Physics in Medicine and Biology, 45(4), 955-969, 2000.
  • Altunina LK, Manzhai BN, Fufaeva MS. “Mechanical and Thermal Properties of Cryogels and Foamed Cryogels Produced From Aqueous Solutions of Poly(vinyl alcohol)”, Russian Journal of Applied Chemistry, 79(10), 1669-1672, 2006.
  • Özmen MM, Dinu MV, Dragan ES, Okay O. “Preparation of Macroporous Acrylamide‐Based Hydrogels: Cryogelation Under Isothermal Conditions”. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 44(11), 1195- 1202, 2007.
  • Srivastava A, Jain E, Kumar A. “The Physical Characterization (N-isopropylacrylamide) Cryogel: Mechanical Strength and Swelling/de-Swelling Kinetics”, Materials Science and Engineering: A, 464(1-2), 93-100, 2007. Poly
  • Dispinar T, Camp WV, De Cock LJ, De Geest BG, Du Prez, FE. “Redox-Responsive Degradable Peg Cryogels as Potential Macromolecular Bioscience, 12(3), 383-394, 2012. in Tissue Engineering”.
  • Shukla NB, Madras G. “Reversible Swelling/Deswelling Characteristics of Ethylene Glycol Dimethacrylate Cross- Linked acrylamide) Superabsorbents”. Industrial & Engineering Chemistry Research, 50(19), 10918-10927, 2011.
  • acid-co-sodium acrylateco
  • Berillo D, Elowsson L, Kirsebom H. “Oxidized Dextran as Crosslinker for Chitosan Cryogel Scaffolds and Formation of Polyelectrolyte Complexes Between Chitosan and Gelatin”. Macromolecular Bioscience, 12(8), 1090-1099, 2012.
  • Al E, Güçlü G, İyim TB, Emik S, Özgümüş S. “Synthesis and Properties Montmorillonite Superabsorbent
  • Hydrogels”. Journal of Applied Polymer Science, 109(1), 16-22, 2008. Acid/Na- Nanocomposite
  • Lopes CMA, Felisberti MI. “Mechanical Behavior and Biocompatibility of Poly(1-vinyl-2-pyrrolidinone)-Gelatin IPN hydrogels”. Biomaterials, 24(7), 1279-1284, 2003.
  • Jin S, Bian F, Lin M, Chen S, Liu H. “Swelling Mechanism of Porous P(VP-co-MAA)/PNIPAM Semi-IPN Hydrogels With Various Pore Size Prepared by a Freeze Treatment”. Polymer International, 58(2), 142-148, 2009.
  • Escobar JL, Garcia D, Valerino A, Zaldivar D, Hernaez release dimethylacrylamide) hydrogels”. Journal of Applied Polymer Science. 91(6), 3433-3437, 2004. sodium acrylamide-co-N,N
  • Muniz EC, Geuskens G. “Compressive Elastic Modulus of Polyacrylamide Hydrogels and Semi-IPNs with poly(N- Isopropylacrylamide)”. Macromolecules, 34(13), 4480- 4484, 2001.
  • Paulino AT, Guilherme MR, Reis AV, Campase GM, Muniz, EC, Nozaki J. “Removal of Methylene Blue Dye From an Aqueous Supported on Modified Polysaccharide”. Journal of Colloid and Interface Science, 301(1), 55-62, 2006.
  • Superabsorbent Hydrogel
  • Chen H, Wang A. “Adsorption Characteristics of Cu(II) From poly(acrylamide)/attapulgite composite”. Journal of Hazardous Materials, 165(1-3), 223-231, 2009. Solution Onto
  • Ho YS, “Citation Review of Lagergren Kinetic Rate Equation on Adsorption Reactions”. Scientometrics, 59(1), 171-177, 2004.
  • Ho YS, Chiang CC. “Sorption Studies of Acid Dye by Mixed Sorbents”. Adsorption, 7(2), 139-147, 2001.
  • Chowdhury S, Das Saha, P. “Comparative Analysis of Linear and Nonlinear Methods of Estimating the Pseudo- Second-order Kinetic Parameters for Sorption of Malachite Bioremediation Journal, 15(4), 181-188, 2011. Pretreated Rice Husk”.
  • Lin J, Wang L. “Comparison Between Linear and Non- Linear Forms of Pseudo-first-Order and Pseudo-Second- Order Adsorption Kinetic Models for the Removal of Methylene Blue by Activated Carbon”. Frontiers of Environmental Science&Engineering in China, 3(3), 320- 324, 2009.
  • Knaebel A, Rebre SR, Lequeux F. “Determination of the Elastic Modulus of Superabsorbent gel Beads”. Polymer Gels and Networks, 5(2), 107-121, 1997.
  • Bajpai SK, Johnson S. “Superabsorbent Hydrogels for Removal of Divalent Toxic Ions. Part I: Synthesis and Swelling Characterization”. Reactive and Functional Polymers, 62(3), 271-283, 2005.
Toplam 33 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Bölüm Makale
Yazarlar

Ayça Bal Bu kişi benim

Bengi Özkahraman Bu kişi benim

Mehmet Koray Gök Bu kişi benim

İşıl Acar Bu kişi benim

Yayımlanma Tarihi 1 Temmuz 2014
Yayımlandığı Sayı Yıl 2014 Cilt: 20 Sayı: 7

Kaynak Göster

APA Bal, A. ., Özkahraman, B. ., Gök, M. K. ., Acar, İ. . (2014). Sodyum Akrilat Esaslı Hidrojel ve Kriyojellerin Şişme, Adsorpsiyon ve Mekanik Özelliklerinin İncelenmesi. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 20(7), 258-265. https://doi.org/10.5505/pajes.2014.08370
AMA Bal A, Özkahraman B, Gök MK, Acar İ. Sodyum Akrilat Esaslı Hidrojel ve Kriyojellerin Şişme, Adsorpsiyon ve Mekanik Özelliklerinin İncelenmesi. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. Temmuz 2014;20(7):258-265. doi:10.5505/pajes.2014.08370
Chicago Bal, Ayça, Bengi Özkahraman, Mehmet Koray Gök, ve İşıl Acar. “Sodyum Akrilat Esaslı Hidrojel Ve Kriyojellerin Şişme, Adsorpsiyon Ve Mekanik Özelliklerinin İncelenmesi”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 20, sy. 7 (Temmuz 2014): 258-65. https://doi.org/10.5505/pajes.2014.08370.
EndNote Bal A, Özkahraman B, Gök MK, Acar İ (01 Temmuz 2014) Sodyum Akrilat Esaslı Hidrojel ve Kriyojellerin Şişme, Adsorpsiyon ve Mekanik Özelliklerinin İncelenmesi. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 20 7 258–265.
IEEE A. . Bal, B. . Özkahraman, M. K. . Gök, ve İ. . Acar, “Sodyum Akrilat Esaslı Hidrojel ve Kriyojellerin Şişme, Adsorpsiyon ve Mekanik Özelliklerinin İncelenmesi”, Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 20, sy. 7, ss. 258–265, 2014, doi: 10.5505/pajes.2014.08370.
ISNAD Bal, Ayça vd. “Sodyum Akrilat Esaslı Hidrojel Ve Kriyojellerin Şişme, Adsorpsiyon Ve Mekanik Özelliklerinin İncelenmesi”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 20/7 (Temmuz 2014), 258-265. https://doi.org/10.5505/pajes.2014.08370.
JAMA Bal A, Özkahraman B, Gök MK, Acar İ. Sodyum Akrilat Esaslı Hidrojel ve Kriyojellerin Şişme, Adsorpsiyon ve Mekanik Özelliklerinin İncelenmesi. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2014;20:258–265.
MLA Bal, Ayça vd. “Sodyum Akrilat Esaslı Hidrojel Ve Kriyojellerin Şişme, Adsorpsiyon Ve Mekanik Özelliklerinin İncelenmesi”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 20, sy. 7, 2014, ss. 258-65, doi:10.5505/pajes.2014.08370.
Vancouver Bal A, Özkahraman B, Gök MK, Acar İ. Sodyum Akrilat Esaslı Hidrojel ve Kriyojellerin Şişme, Adsorpsiyon ve Mekanik Özelliklerinin İncelenmesi. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2014;20(7):258-65.





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