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Schiff bazı temelli yeni geliştirilmiş Cu2+-seçici elektrot kullanılarak çevresel örneklerdeki Cu2+ iyonlarının potansiyometrik tayini

Yıl 2018, Cilt: 24 Sayı: 7, 1325 - 1331, 28.12.2018

Öz

Bu çalışmada, yeni sentezlenen bir schiff bazı
kompleksi kullanılarak katyonik türler için iyon seçici elektrotların hazırlanabilmesi
durumu araştırılmıştır. Schiff bazı kompleksi, polivinilklorür, o-nitrofenil
oktileter ve potasyumtetrakis paraklorotetrafenilborat maddeleri ile farklı
kompozisyonlarda PVC-membran karışımları hazırlanmıştır. Hazırlanan membran
karışımları, katı-kontak elektrotlara kaplanmıştır ve iyon seçici elektrotlar
oluşturulmuştur. Yapılan potansiyometrik ölçümler, hazırlanan elektrotların Cu2+
iyonlarına karşı seçici davranış sergilediğini göstermiştir. Elektrotun en
uygun membran bileşiminin ise %3.9 iyonofor, %32.0 PVC, %64.0 o-nitrofenil
oktileter (plastikleştirici) ve %0.1 potasyumtetrakis paraklorotetrafenilborat
olduğu belirlenmiştir. Hazırlanan Cu2+-seçici elektrotun, çeşitli
katyonik türlerin yanında Cu2+ iyonları için 1.0×10-5-1.0×10-1
M derişim aralığında her on katlık konsantrasyon değişiminde 29.8±0.7 mV eğimle
doğrusal cevap sergiledi ve doğrusallık katsayısının ise 0.9966 (R2=0.9966)
olduğu belirlenmiştir. Elektrotun 5 sn. içerisinde denge potansiyeline ulaştığı
ve 4.1×10-6 M tayin limitine sahip olduğu gözlenmiştir. Geliştirilen
elektrotun pH=3.0-8.0 arasında deney çözeltilerinin pH değişiminden
etkilenmeden potansiyometrik davranış sergilediği test edilmiştir. İlaveten, 12
haftalık kullanım ömrü olan potansiyometrik Cu2+-seçici elektrot, Cu2+
iyonlarının EDTA ile potansiyometrik titrasyonunda ve çeşme suyu, nehir suyu ve
baraj suyu gibi farklı matriks ortamlarına sahip su numunelerinde bulunan Cu2+
iyonlarının potansiyometrik tayininde başarılı bir şekilde kullanılmıştır.

Kaynakça

  • Dalo MA, Salam AA, Nassory NS. “Ion Imprinted Polymer Based Electrochemical Sensor for Environmental Monitoring of Copper(II)”. International Journal of Electrochemical Science, 10, 6780-6793, 2015.
  • Schaefer M, Gitlin JD. “IV. Wilson’s disease and Menkes disease”. American Journal of Physiology-Gastrointestinal and Liver Physiology, 276(2), 311-314, 1999.
  • Gupta, VK, Singh LP, Singh R, Upadhyay N, Kaur SP, Sethi B. “A novel copper (II) selective sensor based on dimethyl 4, 4′(o-phenylene) bis (3-thioallophanate) in PVC matrix”. Journal of Molecular Liquids, 174, 11-16, 2012.
  • Yılmaz V, Hazer O, Kartal Ş. “Synthesis, characterization and application of a novel ion-imprinted polymer for selective solid phase extraction of copper (II) ions from high salt matrices prior to its determination by FAAS”. Talanta, 116, 322-329, 2013.
  • Townsend AT, Miller KA, McLean S, Aldous S. “The determination of copper, zinc, cadmium and lead in urine by high resolution ICP-MS”. Journal of Analytical Atomic Spectrometry, 13(11), 1213-1219,1998.
  • Poitevin E. “Determination of calcium, copper, iron, magnesium, manganese, potassium, phosphorus, sodium, and zinc in fortified food products by microwave digestion and inductively coupled plasma-optical emission spectrometry: single-laboratory validation and ring trial”. Journal of AOAC International, 95(1), 177-185, 2012.
  • Janegitz BC, Marcolino-Junior LH, Campana-Filho SP, Faria RC, Fatibello-Filho O. “Anodic stripping voltammetric determination of copper (II) using a functionalized carbon nanotubes paste electrode modified with crosslinked chitosan”. Sensors and Actuators B: Chemical, 142(1), 260-266, 2009.
  • Jain AK, Gupta VK, Singh LP, Raisoni JR. “Chelating ionophore based membrane sensors for copper (II) ions”. Talanta, 66(5), 1355-1361, 2005.
  • Topcu C. “Highly selective direct determination of chlorate ions by using a newly developed potentiometric electrode based on modified smectite”. Talanta, 161, 623-631, 2016.
  • Topcu C. “Nikel-Sakkarin temelli PVC-membran karbonat (CO32-) seçici elektrot ve potansiyometrik uygulamaları”. Karaelmas Fen ve Mühendislik Dergisi, 6(2), 283-292, 2016.
  • Altıkatoğlu M, Işıldak İ. “İyon-Seçici sensörler kullanılarak bazı sebzelerin topraksız bitki yetiştirme ortamlarındaki nitrat, potasyum ve kalsiyum tayini”. Türkiye Tarımsal Araştırmalar Dergisi, 4(1), 65-70, 2017.
  • Çoldur F, Andaç M, Önder A. “Metiltriamonyum klorür temelli potansiyometrik perklorat-seçici PVC-Membran sensör”. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 33(1), 1-9, 2017.
  • Topcu C, Coldur F, Andac M, Isildak I, Senyuz N, Bati H. “Ag+-selective poly (vinyl chloride) Membrane Electrode Based on [N, N'-ethylenebis-(3-methoxy salicylaldimine)]” Current Analytical Chemistry, 7(2), 136-145, 2011.
  • Nezamzadeh-Ejhieh A, Shahanshahi M. “Modification of clinoptilolite nano-particles with hexadecylpyridynium bromide surfactant as an active component of Cr (VI) selective electrode”. Journal of Industrial and Engineering Chemistry, 19(6), 2026-2033, 2013.
  • Lu X, Chen Z, Hall SB, Yang X. “Evaluation and characteristics of a Pb (II) ion-selective electrode based on aquatic humic substances”. Analytica chimica Acta, 418(2), 205-212, 2000.
  • Shamsipur M, Rouhani S, Ganjali MR, Sharghi H, Eshghi H. “Zinc-selective membrane potentiometric sensor based on a recently synthesized benzo-substituted macrocyclic diamide”. Sensors and Actuators B: Chemical, 59(1), 30-34, 1999.
  • Gupta VK, Singh AK, Mehtab S, Gupta B. “A cobalt (II)-selective PVC membrane based on a Schiff base complex of N, N′-bis (salicylidene)-3, 4-diaminotoluene”. Analytica chimica acta, 566(1), 5-10, 2006.
  • Pinner A. Die Imidoäther und Ihre Derivate. 1. Auflage, Berlin, Germany, Oppenheim, 1892.
  • Umezawa Y, Bühlmann P, Umezawa K, Tohda K, & Amemiya S. “Potentiometric selectivity coefficients of ion-selective electrodes. Part I. Inorganic cations (technical report)”. Pure and Applied Chemistry, 72(10), 1851-2082, 2000.
  • Gupta VK, Goyal RN, Bachheti N, Singh LP, Agarwal S. “A copper-selective electrode based on bis (acetylacetone) propylenediimine”. Talanta, 68(2), 193-197, 2005.
  • Fakhari AR, Raji TA, & Naeimi H. “Copper-selective PVC membrane electrodes based on salens as carriers”. Sensors and Actuators B: Chemical, 104(2), 317-323, 2005.
  • Gupta VK, Prasad R, Kumar A. “Preparation of ethambutol-copper (II) complex and fabrication of PVC based membrane potentiometric sensor for copper”. Talanta, 60(1), 149-160, 2003.
  • Shamsipur M, Rouhani S, Ganjali MR, Eshghi H, Sharghi H. “Copper (II)-selective membrane electrode based on a recently synthesized macrocyclic diamide”. Microchemical Journal, 63(2), 202-210, 1999.
  • Shamsipur M, Javanbakht M, Mousavi MF, Ganjali MR, Lippolis V, Garau A, Tei L. “Copper (II)-selective membrane electrodes based on some recently synthesized mixed aza-thioether crowns containing a 1, 10-phenanthroline sub-unit”. Talanta, 55(6), 1047-1054, 2001.
  • Ardakani MM, Salavati-Niasari M, Kashani M, Ghoreishi SM. “A copper ion-selective electrode with high selectivity prepared by sol-gel and coated wire techniques”. Analytical and Bioanalytical Chemistry. 378(6), 1659-1665, 2004.
  • Mahajan RK, Sood P. “Novel copper (II)-selective electrode based on 2, 2’: 5’, 2’’-terthiophene in PVC matrix”. International Journal of Electrochemical Science, 2, 832-847, 2007.
  • Jain AK, Gupta VK, Sahoo BB, Singh LP. “Copper (II)-selective electrodes based on macrocyclic compounds”. Analytical Proceedings including Analytical Communications, 32(3), 99-101, 1995.
  • Abbaspour A, Kamyabi MA. “Copper (II)-selective electrode based on dithioacetal”. Analytica Chimica Acta, 455(2), 225-231, 2002.
  • Yoshimoto S, Mukai H, Kitano T, Sohrin Y. “Copper (II)-selective membrane electrode based on hydrotris (3-isopropylpyrazolyl) methane in a poly (vinyl chloride) matrix”. Analytica Chimica Acta, 494(1), 207-213, 2003.
  • Wardak C. “Solid contact cadmium ion-selective electrode based on ionic liquid and carbon nanotubes”. Sensors and Actuators B: Chemical, 209, 131-137, 2015.

Potentiometric determination of Cu2+ ions in environmental samples using a newly developed Cu2+-selective electrode based on schiff base

Yıl 2018, Cilt: 24 Sayı: 7, 1325 - 1331, 28.12.2018

Öz

In this study, we investigated the possibility of
preparing ion-selective electrodes for cationic species by using a newly
synthesized Schiff base. PVC-membrane compositions in different ratios were
prepared by using schiff base complex, polyvinylchloride, o-nitrophenyl
octylether and potassiumtetrakis parachlorotetraphenylborate. The prepared
membrane compositions were coated on the surfaces of solid state contact
electrodes and ion selective electrodes were fabricated. Potentiometric
measurements showed that; prepared electrodes exhibited selective behavior
towards Cu2+ ions. The most suitable membrane composition of
electrode was determined as 3.9% ionophore, 32.0% polyvinylchloride, 64.0%
o-nitrophenyl octylether (plasticizer) and 0.1% potassiumtetrakis
parachlorotetraphenylborate. The prepared Cu2+-selective electrode
showed potentiometric working range to Cu2+ between the
concentration of 1.0×10-5 and 1.0×10-1 M with a slope of
29.8±0.7 mV per decade (R2= 0.9966) in the presence of the common
cationic species. It was observed that the electrode reached the equilibrium
potential within 5 seconds and had a limit of 4.1×10-6 M. It was
tested that the developed electrode exhibited potentiometric behavior at pH =
3.0-8.0 without being affected by the pH change of the test solutions.
In addition, the
potentiometric Cu2+-selective electrode had 12-week lifetime. The
electrode was successfully used in the potentiometric titration of Cu2+
ions with EDTA and the potentiometric determination Cu2+ ions in
water samples with different matrix structures such as tap water, river water
and dam water.

Kaynakça

  • Dalo MA, Salam AA, Nassory NS. “Ion Imprinted Polymer Based Electrochemical Sensor for Environmental Monitoring of Copper(II)”. International Journal of Electrochemical Science, 10, 6780-6793, 2015.
  • Schaefer M, Gitlin JD. “IV. Wilson’s disease and Menkes disease”. American Journal of Physiology-Gastrointestinal and Liver Physiology, 276(2), 311-314, 1999.
  • Gupta, VK, Singh LP, Singh R, Upadhyay N, Kaur SP, Sethi B. “A novel copper (II) selective sensor based on dimethyl 4, 4′(o-phenylene) bis (3-thioallophanate) in PVC matrix”. Journal of Molecular Liquids, 174, 11-16, 2012.
  • Yılmaz V, Hazer O, Kartal Ş. “Synthesis, characterization and application of a novel ion-imprinted polymer for selective solid phase extraction of copper (II) ions from high salt matrices prior to its determination by FAAS”. Talanta, 116, 322-329, 2013.
  • Townsend AT, Miller KA, McLean S, Aldous S. “The determination of copper, zinc, cadmium and lead in urine by high resolution ICP-MS”. Journal of Analytical Atomic Spectrometry, 13(11), 1213-1219,1998.
  • Poitevin E. “Determination of calcium, copper, iron, magnesium, manganese, potassium, phosphorus, sodium, and zinc in fortified food products by microwave digestion and inductively coupled plasma-optical emission spectrometry: single-laboratory validation and ring trial”. Journal of AOAC International, 95(1), 177-185, 2012.
  • Janegitz BC, Marcolino-Junior LH, Campana-Filho SP, Faria RC, Fatibello-Filho O. “Anodic stripping voltammetric determination of copper (II) using a functionalized carbon nanotubes paste electrode modified with crosslinked chitosan”. Sensors and Actuators B: Chemical, 142(1), 260-266, 2009.
  • Jain AK, Gupta VK, Singh LP, Raisoni JR. “Chelating ionophore based membrane sensors for copper (II) ions”. Talanta, 66(5), 1355-1361, 2005.
  • Topcu C. “Highly selective direct determination of chlorate ions by using a newly developed potentiometric electrode based on modified smectite”. Talanta, 161, 623-631, 2016.
  • Topcu C. “Nikel-Sakkarin temelli PVC-membran karbonat (CO32-) seçici elektrot ve potansiyometrik uygulamaları”. Karaelmas Fen ve Mühendislik Dergisi, 6(2), 283-292, 2016.
  • Altıkatoğlu M, Işıldak İ. “İyon-Seçici sensörler kullanılarak bazı sebzelerin topraksız bitki yetiştirme ortamlarındaki nitrat, potasyum ve kalsiyum tayini”. Türkiye Tarımsal Araştırmalar Dergisi, 4(1), 65-70, 2017.
  • Çoldur F, Andaç M, Önder A. “Metiltriamonyum klorür temelli potansiyometrik perklorat-seçici PVC-Membran sensör”. Erciyes Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 33(1), 1-9, 2017.
  • Topcu C, Coldur F, Andac M, Isildak I, Senyuz N, Bati H. “Ag+-selective poly (vinyl chloride) Membrane Electrode Based on [N, N'-ethylenebis-(3-methoxy salicylaldimine)]” Current Analytical Chemistry, 7(2), 136-145, 2011.
  • Nezamzadeh-Ejhieh A, Shahanshahi M. “Modification of clinoptilolite nano-particles with hexadecylpyridynium bromide surfactant as an active component of Cr (VI) selective electrode”. Journal of Industrial and Engineering Chemistry, 19(6), 2026-2033, 2013.
  • Lu X, Chen Z, Hall SB, Yang X. “Evaluation and characteristics of a Pb (II) ion-selective electrode based on aquatic humic substances”. Analytica chimica Acta, 418(2), 205-212, 2000.
  • Shamsipur M, Rouhani S, Ganjali MR, Sharghi H, Eshghi H. “Zinc-selective membrane potentiometric sensor based on a recently synthesized benzo-substituted macrocyclic diamide”. Sensors and Actuators B: Chemical, 59(1), 30-34, 1999.
  • Gupta VK, Singh AK, Mehtab S, Gupta B. “A cobalt (II)-selective PVC membrane based on a Schiff base complex of N, N′-bis (salicylidene)-3, 4-diaminotoluene”. Analytica chimica acta, 566(1), 5-10, 2006.
  • Pinner A. Die Imidoäther und Ihre Derivate. 1. Auflage, Berlin, Germany, Oppenheim, 1892.
  • Umezawa Y, Bühlmann P, Umezawa K, Tohda K, & Amemiya S. “Potentiometric selectivity coefficients of ion-selective electrodes. Part I. Inorganic cations (technical report)”. Pure and Applied Chemistry, 72(10), 1851-2082, 2000.
  • Gupta VK, Goyal RN, Bachheti N, Singh LP, Agarwal S. “A copper-selective electrode based on bis (acetylacetone) propylenediimine”. Talanta, 68(2), 193-197, 2005.
  • Fakhari AR, Raji TA, & Naeimi H. “Copper-selective PVC membrane electrodes based on salens as carriers”. Sensors and Actuators B: Chemical, 104(2), 317-323, 2005.
  • Gupta VK, Prasad R, Kumar A. “Preparation of ethambutol-copper (II) complex and fabrication of PVC based membrane potentiometric sensor for copper”. Talanta, 60(1), 149-160, 2003.
  • Shamsipur M, Rouhani S, Ganjali MR, Eshghi H, Sharghi H. “Copper (II)-selective membrane electrode based on a recently synthesized macrocyclic diamide”. Microchemical Journal, 63(2), 202-210, 1999.
  • Shamsipur M, Javanbakht M, Mousavi MF, Ganjali MR, Lippolis V, Garau A, Tei L. “Copper (II)-selective membrane electrodes based on some recently synthesized mixed aza-thioether crowns containing a 1, 10-phenanthroline sub-unit”. Talanta, 55(6), 1047-1054, 2001.
  • Ardakani MM, Salavati-Niasari M, Kashani M, Ghoreishi SM. “A copper ion-selective electrode with high selectivity prepared by sol-gel and coated wire techniques”. Analytical and Bioanalytical Chemistry. 378(6), 1659-1665, 2004.
  • Mahajan RK, Sood P. “Novel copper (II)-selective electrode based on 2, 2’: 5’, 2’’-terthiophene in PVC matrix”. International Journal of Electrochemical Science, 2, 832-847, 2007.
  • Jain AK, Gupta VK, Sahoo BB, Singh LP. “Copper (II)-selective electrodes based on macrocyclic compounds”. Analytical Proceedings including Analytical Communications, 32(3), 99-101, 1995.
  • Abbaspour A, Kamyabi MA. “Copper (II)-selective electrode based on dithioacetal”. Analytica Chimica Acta, 455(2), 225-231, 2002.
  • Yoshimoto S, Mukai H, Kitano T, Sohrin Y. “Copper (II)-selective membrane electrode based on hydrotris (3-isopropylpyrazolyl) methane in a poly (vinyl chloride) matrix”. Analytica Chimica Acta, 494(1), 207-213, 2003.
  • Wardak C. “Solid contact cadmium ion-selective electrode based on ionic liquid and carbon nanotubes”. Sensors and Actuators B: Chemical, 209, 131-137, 2015.
Toplam 30 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Makale
Yazarlar

Faruk Kardaş 0000-0002-0900-7503

Cihan Topçu 0000-0003-0613-5873

Yayımlanma Tarihi 28 Aralık 2018
Yayımlandığı Sayı Yıl 2018 Cilt: 24 Sayı: 7

Kaynak Göster

APA Kardaş, F., & Topçu, C. (2018). Schiff bazı temelli yeni geliştirilmiş Cu2+-seçici elektrot kullanılarak çevresel örneklerdeki Cu2+ iyonlarının potansiyometrik tayini. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, 24(7), 1325-1331.
AMA Kardaş F, Topçu C. Schiff bazı temelli yeni geliştirilmiş Cu2+-seçici elektrot kullanılarak çevresel örneklerdeki Cu2+ iyonlarının potansiyometrik tayini. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. Aralık 2018;24(7):1325-1331.
Chicago Kardaş, Faruk, ve Cihan Topçu. “Schiff Bazı Temelli Yeni geliştirilmiş Cu2+-seçici Elektrot kullanılarak çevresel örneklerdeki Cu2+ iyonlarının Potansiyometrik Tayini”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 24, sy. 7 (Aralık 2018): 1325-31.
EndNote Kardaş F, Topçu C (01 Aralık 2018) Schiff bazı temelli yeni geliştirilmiş Cu2+-seçici elektrot kullanılarak çevresel örneklerdeki Cu2+ iyonlarının potansiyometrik tayini. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 24 7 1325–1331.
IEEE F. Kardaş ve C. Topçu, “Schiff bazı temelli yeni geliştirilmiş Cu2+-seçici elektrot kullanılarak çevresel örneklerdeki Cu2+ iyonlarının potansiyometrik tayini”, Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 24, sy. 7, ss. 1325–1331, 2018.
ISNAD Kardaş, Faruk - Topçu, Cihan. “Schiff Bazı Temelli Yeni geliştirilmiş Cu2+-seçici Elektrot kullanılarak çevresel örneklerdeki Cu2+ iyonlarının Potansiyometrik Tayini”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi 24/7 (Aralık 2018), 1325-1331.
JAMA Kardaş F, Topçu C. Schiff bazı temelli yeni geliştirilmiş Cu2+-seçici elektrot kullanılarak çevresel örneklerdeki Cu2+ iyonlarının potansiyometrik tayini. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2018;24:1325–1331.
MLA Kardaş, Faruk ve Cihan Topçu. “Schiff Bazı Temelli Yeni geliştirilmiş Cu2+-seçici Elektrot kullanılarak çevresel örneklerdeki Cu2+ iyonlarının Potansiyometrik Tayini”. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi, c. 24, sy. 7, 2018, ss. 1325-31.
Vancouver Kardaş F, Topçu C. Schiff bazı temelli yeni geliştirilmiş Cu2+-seçici elektrot kullanılarak çevresel örneklerdeki Cu2+ iyonlarının potansiyometrik tayini. Pamukkale Üniversitesi Mühendislik Bilimleri Dergisi. 2018;24(7):1325-31.





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