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Polypyrrole Modified Graphite Electrode for Supercapacitor Application: The Effect of Cycling Electrolytes

Yıl 2019, Cilt: 23 Sayı: 3, 462 - 471, 01.06.2019
https://doi.org/10.16984/saufenbilder.493079

Öz

Graphite
electrode was modified by polypyrrole (PPy) thin film. PPy was electrodeposited
potentiostatically by applying -1.5 V from acidic aqueous solution having
pyrrole monomers. The waiting time of deposition solution effect the surface
coverage of resulted films. PPy modified electrodes fabricated by old solution
have lower surface coverage than PPy obtained from freshly prepared solution.
PPy films were transferred to aqueous (acidic, neutral, alkaline) and a non-aqueous
(Deep Eutectic Solvent) solutions for cycling. Capacitance performance of PPy
film in a choline chloride based ionic liquid (Ethaline) was compared with that
of PPy films in aqueous solutions. As PPy film in salt solution (LiClO4
and NaCl) was evolved because deposition electrolyte was different (H2SO4)
than deposition electrolyte and salt ions are exchanged at the beginning of
cycling. Film obtained in acidic media was transferred into alkaline solution
or ionic liquid is electroinactive. PPy film is strongly electroactive in an
acidic media for hundreds of cycles as acidic media can cause the highest
charge which is directly related to capacitive performance. Upon increasing pH
value of cycling electrolyte, current and charge value decreases. PPy film in a
salt solution (NaCl or LiClO4 in water) and acidic solution (H2SO4)
is electroactive and can be used for supercapacitor application. As PPy film in
ionic liquids and alkaline solution cannot be electroactive, they cannot be
used for supercapacitor applications. Capacity retention of PPy in KOH and
Ethaline is low (around 5%). However, PPy thin film in H2SO4
has 77% of capacitance retention after 500 scans.

Kaynakça

  • Referans1 I. Dincer, "Renewable energy and sustainable development: a crucial review," Renewable & Sustainable Energy Reviews. vol. 4, pp. 157–175, 2000.
  • Referans2 M.-S. Balogun, W. Qiu, W. Wang, P. Fang, X. Lu, Y. Tong, "Recent advances in metal nitrides as high-performance electrode materials for energy storage devices," Journal of Materials Chemistry A. vol. 3, pp. 1364–1387, 2015.
  • Referans3 A. Borenstein, O. Hanna, R. Attias, S. Luski, T. Brousse, D. Aurbach, "Carbon-based composite materials for supercapacitor electrodes: a review," Journal of Materials Chemistry A. vol. 5, pp.12653–12672, 2017.
  • Referans4 L. Kouchachvili, W. Yaïci, E. Entchev, "Hybrid battery/supercapacitor energy storage system for the electric vehicles," Journal of Power Sources. vol. 374, pp. 237–248, 2018.
  • Referans5 S. Faraji and F.N. Ani, "The development supercapacitor from activated carbon by electroless plating—A review," Renewable & Sustainable Energy Reviews. vol. 42, pp. 823–834, 2015.
  • Referans6 V. Augustyn, P. Simon, B. Dunn, "Pseudocapacitive oxide materials for high-rate electrochemical energy storage," Energy Environ. Sci. vol. 7 (2014) 1597–1614.
  • Referans7 I. Shown, A. Ganguly, L. Chen, K. Chen, "Conducting polymer‐based flexible supercapacitor," Energy Science and Engineering. vol. 3, pp. 2–26, 2015.
  • Referans8 R. Balint, N.J. Cassidy, S.H. Cartmell, "Conductive polymers: towards a smart biomaterial for tissue engineering," Acta Biomaterilia. vol. 10, pp. 2341–2353, 2014.
  • Referans9 C.O. Baker, X. Huang, W. Nelson, R.B. Kaner, "Polyaniline nanofibers: broadening applications for conducting polymers," Chemical Society Reviews. vol. 46, pp. 1510–1525, 2017.
  • Referans10 Y. Huang, H. Li, Z. Wang, M. Zhu, Z. Pei, Q. Xue, Y. Huang, C. Zhi, "Nanostructured polypyrrole as a flexible electrode material of supercapacitor," Nano Energy. vol. 22, pp. 422–438, 2016.
  • Referans11 T.V. Vernitskaya, O.N. Efimov, "Polypyrrole: a conducting polymer; its synthesis, properties and applications," Russian Chemical Reviews. vol. 66, pp. 443–457, 1997.
  • Referans12 H. Bagheri, Z. Ayazi, M. Naderi, "Conductive polymer-based microextraction methods: a review," Analytica Chimica Acta. vol. 767, pp. 1–13, 2013.
  • Referans13 A. Kausaite-Minkstimiene, V. Mazeiko, A. Ramanaviciene, A. Ramanavicius, "Evaluation of chemical synthesis of polypyrrole particles," Colloids and Surfaces A: Physicochemical and Engineering Aspects. vol. 483, pp. 224–231, 2015.
  • Referans14 B. Jin, F. Gao, Y.-F. Zhu, X.-Y. Lang, G.-F. Han, W. Gao, Z. Wen, M. Zhao, J.-C. Li, Q. Jiang, "Facile synthesis of non-graphitizable polypyrrole-derived carbon/carbon nanotubes for lithium-ion batteries," Scientific Reports. vol. 6, pp. 19317, 2016.
  • Referans15 D. Plausinaitis, L. Sinkevicius, L. Mikoliunaite, V. Plausinaitiene, A. Ramanaviciene, A. Ramanavicius, "Electrochemical polypyrrole formation from pyrrole ‘adlayer," Physical Chemistry Chemical Physics. vol. 19, pp. 1029–1038, 2017.
  • Referans16 N. Aravindan, M. V Sangaranarayanan, Influence of solvent composition on the anti-corrosion performance of copper–polypyrrole (Cu–PPy) coated 304 stainless steel, Prog. Org. Coatings. vol. 95, pp. 38–45, 2016.
  • Referans17 M. Culebras, B. Uriol, C.M. Gómez, A. Cantarero, "Controlling the thermoelectric properties of polymers: application to PEDOT and polypyrrole," Physical Chemistry Chemical Physics. vol. 17, pp. 15140–15145, 2015.
  • Referans18 J. Wang, S.-P. Chen, M.S. Lin, "Use of different electropolymerization conditions for controlling the size-exclusion selectivity at polyaniline, polypyrrole and polyphenol films," Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. vol. 273, pp. 231–242, 1989.
  • Referans19 M. Fujii, Y. Saeki, K. Arii, K. Yoshino, "Fractal structure of electrochemically polymerized polypyrrole and growth process as function of monomer concentration, electrolyte concentration and applied voltage," Japanese Journal of Applied Physics. vol. 29, pp. 2501, 1990.
  • Referans20 M. Mallouki, F. Tran-Van, C. Sarrazin, C. Chevrot, J.F. Fauvarque, "Electrochemical storage of polypyrrole–Fe2O3 nanocomposites in ionic liquids," Electrochimica Acta. vol. 54, pp. 2992–2997, 2009.
  • Referans21 J. Wu, J. Pawliszyn, "Solid-phase microextraction based on polypyrrole films with different counter ions," Analytica Chimica Acta. vol. 520, pp. 257–264, 2004.
Yıl 2019, Cilt: 23 Sayı: 3, 462 - 471, 01.06.2019
https://doi.org/10.16984/saufenbilder.493079

Öz

Kaynakça

  • Referans1 I. Dincer, "Renewable energy and sustainable development: a crucial review," Renewable & Sustainable Energy Reviews. vol. 4, pp. 157–175, 2000.
  • Referans2 M.-S. Balogun, W. Qiu, W. Wang, P. Fang, X. Lu, Y. Tong, "Recent advances in metal nitrides as high-performance electrode materials for energy storage devices," Journal of Materials Chemistry A. vol. 3, pp. 1364–1387, 2015.
  • Referans3 A. Borenstein, O. Hanna, R. Attias, S. Luski, T. Brousse, D. Aurbach, "Carbon-based composite materials for supercapacitor electrodes: a review," Journal of Materials Chemistry A. vol. 5, pp.12653–12672, 2017.
  • Referans4 L. Kouchachvili, W. Yaïci, E. Entchev, "Hybrid battery/supercapacitor energy storage system for the electric vehicles," Journal of Power Sources. vol. 374, pp. 237–248, 2018.
  • Referans5 S. Faraji and F.N. Ani, "The development supercapacitor from activated carbon by electroless plating—A review," Renewable & Sustainable Energy Reviews. vol. 42, pp. 823–834, 2015.
  • Referans6 V. Augustyn, P. Simon, B. Dunn, "Pseudocapacitive oxide materials for high-rate electrochemical energy storage," Energy Environ. Sci. vol. 7 (2014) 1597–1614.
  • Referans7 I. Shown, A. Ganguly, L. Chen, K. Chen, "Conducting polymer‐based flexible supercapacitor," Energy Science and Engineering. vol. 3, pp. 2–26, 2015.
  • Referans8 R. Balint, N.J. Cassidy, S.H. Cartmell, "Conductive polymers: towards a smart biomaterial for tissue engineering," Acta Biomaterilia. vol. 10, pp. 2341–2353, 2014.
  • Referans9 C.O. Baker, X. Huang, W. Nelson, R.B. Kaner, "Polyaniline nanofibers: broadening applications for conducting polymers," Chemical Society Reviews. vol. 46, pp. 1510–1525, 2017.
  • Referans10 Y. Huang, H. Li, Z. Wang, M. Zhu, Z. Pei, Q. Xue, Y. Huang, C. Zhi, "Nanostructured polypyrrole as a flexible electrode material of supercapacitor," Nano Energy. vol. 22, pp. 422–438, 2016.
  • Referans11 T.V. Vernitskaya, O.N. Efimov, "Polypyrrole: a conducting polymer; its synthesis, properties and applications," Russian Chemical Reviews. vol. 66, pp. 443–457, 1997.
  • Referans12 H. Bagheri, Z. Ayazi, M. Naderi, "Conductive polymer-based microextraction methods: a review," Analytica Chimica Acta. vol. 767, pp. 1–13, 2013.
  • Referans13 A. Kausaite-Minkstimiene, V. Mazeiko, A. Ramanaviciene, A. Ramanavicius, "Evaluation of chemical synthesis of polypyrrole particles," Colloids and Surfaces A: Physicochemical and Engineering Aspects. vol. 483, pp. 224–231, 2015.
  • Referans14 B. Jin, F. Gao, Y.-F. Zhu, X.-Y. Lang, G.-F. Han, W. Gao, Z. Wen, M. Zhao, J.-C. Li, Q. Jiang, "Facile synthesis of non-graphitizable polypyrrole-derived carbon/carbon nanotubes for lithium-ion batteries," Scientific Reports. vol. 6, pp. 19317, 2016.
  • Referans15 D. Plausinaitis, L. Sinkevicius, L. Mikoliunaite, V. Plausinaitiene, A. Ramanaviciene, A. Ramanavicius, "Electrochemical polypyrrole formation from pyrrole ‘adlayer," Physical Chemistry Chemical Physics. vol. 19, pp. 1029–1038, 2017.
  • Referans16 N. Aravindan, M. V Sangaranarayanan, Influence of solvent composition on the anti-corrosion performance of copper–polypyrrole (Cu–PPy) coated 304 stainless steel, Prog. Org. Coatings. vol. 95, pp. 38–45, 2016.
  • Referans17 M. Culebras, B. Uriol, C.M. Gómez, A. Cantarero, "Controlling the thermoelectric properties of polymers: application to PEDOT and polypyrrole," Physical Chemistry Chemical Physics. vol. 17, pp. 15140–15145, 2015.
  • Referans18 J. Wang, S.-P. Chen, M.S. Lin, "Use of different electropolymerization conditions for controlling the size-exclusion selectivity at polyaniline, polypyrrole and polyphenol films," Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. vol. 273, pp. 231–242, 1989.
  • Referans19 M. Fujii, Y. Saeki, K. Arii, K. Yoshino, "Fractal structure of electrochemically polymerized polypyrrole and growth process as function of monomer concentration, electrolyte concentration and applied voltage," Japanese Journal of Applied Physics. vol. 29, pp. 2501, 1990.
  • Referans20 M. Mallouki, F. Tran-Van, C. Sarrazin, C. Chevrot, J.F. Fauvarque, "Electrochemical storage of polypyrrole–Fe2O3 nanocomposites in ionic liquids," Electrochimica Acta. vol. 54, pp. 2992–2997, 2009.
  • Referans21 J. Wu, J. Pawliszyn, "Solid-phase microextraction based on polypyrrole films with different counter ions," Analytica Chimica Acta. vol. 520, pp. 257–264, 2004.
Toplam 21 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Malzeme Üretim Teknolojileri
Bölüm Araştırma Makalesi
Yazarlar

Abdulcabbar Yavuz Bu kişi benim 0000-0002-7216-0586

Sıtkı Aktaş 0000-0002-9143-6752

Salih Durdu 0000-0002-6288-0926

Yayımlanma Tarihi 1 Haziran 2019
Gönderilme Tarihi 6 Aralık 2018
Kabul Tarihi 23 Ocak 2019
Yayımlandığı Sayı Yıl 2019 Cilt: 23 Sayı: 3

Kaynak Göster

APA Yavuz, A., Aktaş, S., & Durdu, S. (2019). Polypyrrole Modified Graphite Electrode for Supercapacitor Application: The Effect of Cycling Electrolytes. Sakarya University Journal of Science, 23(3), 462-471. https://doi.org/10.16984/saufenbilder.493079
AMA Yavuz A, Aktaş S, Durdu S. Polypyrrole Modified Graphite Electrode for Supercapacitor Application: The Effect of Cycling Electrolytes. SAUJS. Haziran 2019;23(3):462-471. doi:10.16984/saufenbilder.493079
Chicago Yavuz, Abdulcabbar, Sıtkı Aktaş, ve Salih Durdu. “Polypyrrole Modified Graphite Electrode for Supercapacitor Application: The Effect of Cycling Electrolytes”. Sakarya University Journal of Science 23, sy. 3 (Haziran 2019): 462-71. https://doi.org/10.16984/saufenbilder.493079.
EndNote Yavuz A, Aktaş S, Durdu S (01 Haziran 2019) Polypyrrole Modified Graphite Electrode for Supercapacitor Application: The Effect of Cycling Electrolytes. Sakarya University Journal of Science 23 3 462–471.
IEEE A. Yavuz, S. Aktaş, ve S. Durdu, “Polypyrrole Modified Graphite Electrode for Supercapacitor Application: The Effect of Cycling Electrolytes”, SAUJS, c. 23, sy. 3, ss. 462–471, 2019, doi: 10.16984/saufenbilder.493079.
ISNAD Yavuz, Abdulcabbar vd. “Polypyrrole Modified Graphite Electrode for Supercapacitor Application: The Effect of Cycling Electrolytes”. Sakarya University Journal of Science 23/3 (Haziran 2019), 462-471. https://doi.org/10.16984/saufenbilder.493079.
JAMA Yavuz A, Aktaş S, Durdu S. Polypyrrole Modified Graphite Electrode for Supercapacitor Application: The Effect of Cycling Electrolytes. SAUJS. 2019;23:462–471.
MLA Yavuz, Abdulcabbar vd. “Polypyrrole Modified Graphite Electrode for Supercapacitor Application: The Effect of Cycling Electrolytes”. Sakarya University Journal of Science, c. 23, sy. 3, 2019, ss. 462-71, doi:10.16984/saufenbilder.493079.
Vancouver Yavuz A, Aktaş S, Durdu S. Polypyrrole Modified Graphite Electrode for Supercapacitor Application: The Effect of Cycling Electrolytes. SAUJS. 2019;23(3):462-71.

Sakarya University Journal of Science (SAUJS)