Polipirol/dekstran kompozit filminin platin elektrot yüzeyine elektrokimyasal sentezi ve karakterizasyonu

Yıl 2023, Cilt: 6 Sayı: 2, 27 - 40, 31.12.2023

Süleyman Yalçınkaya Şirin Duran

https://doi.org/10.55198/artibilimfen.1405861

Öz

Bu çalışmada polipirol monomeri dekstran biyopolimeri ile 0,3 M okzalik asit çözeltisi içerisinde platin elektrot yüzeyinde ince film halinde kompozit olarak sentezlenmiştir. Sentez işlemi için elektrokimyasal yöntem kullanılarak dönüşümlü voltametri tekniği ile gerçekleştirilmiştir. Sentezlenen ince filmin karakterizasyonu için FT-IR, H-NMR, SEM, UV-VİS, TG-DTA analizleri ve elektrokimyasal açıdan davranışlarının incelenmesi için dönüşümlü voltametri teknikleri kullanılmıştır. Karakterizasyon işlemleri sonucunda sentezlenen kompozit için muhtemel bir kimyasal yapı önerilmiştir. Çözünürlük testleri sonucunda genel olarak çözünmediği ancak DMSO çözücüsünde az miktarda çözündüğü tespit edilmiştir. Elektrokimyasal analizler sonucunda elektroaktif olduğu ve iyi bir redox davranışı gösterdiği belirlenmiştir.

Anahtar Kelimeler

Dekstran, Elektrokimyasal Sentez, Kompozit, Polipirol.

Destekleyen Kurum

Hatay Mustafa Kemal Üniversitesi Bilimsel Araştırma Projeleri (HMKÜ-BAP) birimi

Proje Numarası

21.D.023

Teşekkür

Bu çalışmanın gerçekleştirilmesi için sağladığı maddi destekten dolayı Hatay Mustafa Kemal Üniversitesi Bilimsel Araştırma Projeleri (HMKÜ-BAP) birimine (Proje No: 21.D.023) teşekkür ederiz.

Electrochemical synthesis and characterization of polypyrrolle/dextran composite film on platinum electrode surface

Öz

In this study, a thin film composite of polypyrrole monomer with dextran biopolymer was synthesized on the surface of platinum electrode in 0,3 M oxalic acid solution. For the synthesis process, it was carried out by the technique of cyclic voltammetry using the electrochemical method. FT-IR, H-NMR, SEM, UV-VIS, TG-DTA analyses were used for the characterization of the synthesized thin film and cyclic voltammetry techniques were used to examine its electrochemical behavior. A possible chemical structure was proposed for the composite synthesized as a result of the characterization processes. As a result of the solubility tests, it was found that it was generally insoluble, but slightly dissolved in the DMSO solvent. As a result of electrochemical analysis, it was determined that it was electroactive and showed good redox behavior.

Anahtar Kelimeler

Dextran, Electrochemical Synthesis, Composit, Polypyrolle.

Proje Numarası

21.D.023

Kaynakça

• Folorunso, O., Olukanmi, P., Thokozani, S. (2023) . Conductive polymers’electronic structure modification for multifunctional applications. Materialstody, 35,106308.
• Yalçınkaya, S., Tüken, T., Yazıcı, B., Erbil, M. (2010). Electrochemical synthesis and corrosion behaviour of poly (pyrrole-co-o-anisidine-co-o-toluidine). Current Applied Physics, 10(3), 783-789.
• Ghoreishi, S. M., Shabani-Nooshabadi, M., Behpour, M., Jafari, Y. (2012) Electrochemical synthesis of poly(poli(o-anisidine) and its corrosion studies as a coating on aluminum alloy 3105. Progress in Organic Coatings, 74(3), 502-510.
• Filazi, İ., Özyılmaz A.T. (2022). PANi/PPy and PANi Films on ZnNi alloy coated carbon steel; Electrochemical syntheses and corrosion performances. Eurasian Journal of Biological and Chemical Sciences, 5(1):15-21.
• Yalçınkaya, S., Duran, Ş. (2023). Poli (pirol-ko-o-amino fenol)/kitosan kompozit filmlerinin farklı monomer oranlarındaki çözeltilerde elektrokimyasal sentezi ve karakterizasyonu. Osmaniye Korkut Ata Üniversitesi Fen Bilimleri Enstitü Dergisi, 6(1), 619 – 634.
• Kumar, A. M., Suresh, B., Das, S., Obot, I. B., Adesina, A. Y., Ramakrishna, S. (2017). Promising 3 bio-composites of polypyrrole and chitosan : Surface protective and in vitro biocompatibility performance on 316L SS implants. Carbohydrate Polymers, 173,121-130.
• Yalçınkaya, S., Çakmak, D. (2021). Immobilization of CoII-(N,N’-bis(salicydene)-2aminobenzylamine) on poly(pyrrole-co-o-anisidine)/chitosan compositefilms: application to electrocatalytic oxidation of catechol. Electroanaliysis, 33(3), 755-765.
• Yalçınkaya, S., Duran, Ş. (2022). Chemical synthesis and characterization of poly (pyrrole-co-o aminophenol) /chitosan composite. Polymer Bulletin, 79, 10037–10052.
• Chen, F., Huang, G., Huang H. (2020). Preparation and application of dextran and its derivatives as carriers. International Journal of Biological Macromolecules, 145 (2020) 827–834.
• Zhang, Q. H., Hou, B. S., Li, Y. Y., Zhu, Z. Y.,Lei, Y., Wang, X., Liu, H. F., Zhang, G. A. (2021). Dextran derivatives as highly efficient green corrosion inhibitors for carbon steel in CO2-saturated oil field produced water: Experimental and theoretical approaches. Chemical Engineering Journal, 424:130-519.
• Li, X., Shi, H., Cui, Y., Pan, K., Wei, W., Liu, X. (2020). Dextran-caffeic asid/tetraaniline composite coatingsfor simultaneous improvement of cytocompatibility and corrosion resistance of magnesium alloy. Progress in Organic Coatings, 149-105928.
• Bucak Demirbilek, C., Özdemir Dinç, C. (2021). Alizarin red boyar maddesinin dietilaminodekstran/epiklorohidrin (DEAE-D/ECH) kriyojeli ile sulu çözeltiden gideriminin araştırılması. International Journal of Pure and Applied Sciences, 7(3) 383-390.
• Guı Li, X., Xia Wang, L., Rong Huang, M., Quing Lu Y., Fang Zhu, M., Manner A., Springer, J. (2001). Synthesis and Characterization of Pyrrole and Anisidine Copolymer. Polymer, 42(14) 6095-6103.
• Yalçınkaya, S., Demetgül, C., Timur, M. (2010). Electrochemical synthesis and characterization of polypyrrole/chitosan composite on platinum electrode: Its electrochemical and thermal behaviors. Carbohydrate Polymers, 79, 908-913.
• Tüken, T., Arslan, G., Yazıcı, B., Erbil, M. (2004). The corrosion protection of mild steel by polypyrole/polyphenol. multilayer coating. Corrosion Science, 46(11), 2743-2754.
• Yalçınkaya, S., Tüken, T., Yazici, B., Erbil M. (2008). Electrochemical synthesis and corrosion performance of poly(pyrrole-co-panse). Progress in Organic Coatings, 62 (2), 236-244.
• Iconaru, S. L., Predoi, M.V., Motelica-Heino, M., Predoi, D., Buton, N., Megier, C., George Stan, E.G. (2020). Dextran-Thyme magnesium-doped hydroxyapatite composite antimicrobial coatings. Coatings, 10(57), 1001-0057.
• Yalçınkaya, S., Demirbilek, C., Ozdemir Dinç, C., (2015). Preparation and characterization of polypyrrole/dextran sulphate composite:its electrochemical and thermal behaviors. Polymer Bulletin, 72:2843-2855.
• Ozyılmaz, A. T., Filazi, I., Surmelioglu, C., Ozyılmaz, G. (2022). Optimization of anticorrosive PANi and PPy synthesis conditions on ZnNiMo coated copper electrode surface with box behnken design. Investigation methods for physicochemical systems, 58 (4), 883–897.
• Meera Moydeen A., Syed Ali Padusha M., Thamer, B.M., Anis Ahamed, N., Al-Enizi1, A.M., El-Hamshary, H., El-Newehyl, M.H. (2019). Single-nozzle Core-shell electrospun nanofibers of PVP/dextran as drug delivery system. Fibers and Polymers, 20(10), 2078-2089.
• Siddiquia, N. N., Amana, A., Silipo Ul, A., Qadera, S. A., Molinarob, A. (2014). Structural analysis and characterization of dextran produced by wild and mutant strains of Leuconostoc mesenteroides. Carbohydrate Polymers, 99,331-338,
• Ozkazanç, E. (2012). Polypyrrole/copper(II) acetlyacetonate composites prepared by in situ chemical oxidative polymerization. Synthtetic Metals, 162, 1016-1023.
• Yalçınkaya, S., Çakmak, D. (2017). Electrochemical synthesis of poly(pyrrole-co-oanisidine)/chitosan composite films. Journal of Molecular Structure, 1135, 32-43.