Araştırma Makalesi
BibTex RIS Kaynak Göster

A cleaner application on hydrogen sulfide

Yıl 2021, Cilt: 9 Sayı: 2, 153 - 159, 06.12.2021
https://doi.org/10.51354/mjen.953547

Öz

With the increasing industrial production, there was a significant number of toxic and harmful hydrogen sulfide (H2S) gas generated. Due to the industrial activities, converting H2S gas from the waste of industrial process is environmentally attractive. This paper focuses on the conversion of H2S to elemental sulfur (S°) and other sulfur species (i.e., sulfite ion (SO32-); sulfate ion (SO42-) using Fenton reagent. The effects of some reaction parameters such as Fe2+ ion concentration, amount of hydrogen peroxide (H2O2), reaction time, initial H2S concentration and, liquid-gas ratio on H2S conversion percentage were explored thoroughly. The results revealed that the increase of the Fe2+ ion concentration and H2O2 quantity could promote the conversion of H2S. Besides, the comparable results were recorded for each reaction parameter. An apparent positive effect was observed with increasing the amount of H2O2 on H2S conversion. However, the conversion percentage was decreased while increased in the initial concentration of the H2S in the Fenton reactor. It was well accepted that the main conversion pathway of H2S was hydroxyl radical (•OH). Additionally, the oxidative reaction of H2O2 on H2S is thought another removal pathway. The expected products are sulphuric acid and S°.

Destekleyen Kurum

Tubitak

Proje Numarası

217M284

Kaynakça

  • Liu Y, Shi S, Wang Y. "Removal of Pollutants from Gas Streams Using Fenton (-like)-based Oxidation Systems: A Review", J Hazard Mater, (2021), 125927.
  • Kailasa S.K, Koduru J.R, Vikrant K, Tsang Y.F, Singhal R.K, Hussain C.M, Kim K-H. "Recent progress on solution and materials chemistry for the removal of hydrogen sulfide from various gas plants", J Mol Liq, 297, (2020), 111886.
  • Rubright S.L.M, Pearce L.L, Peterson J. "Environmental toxicology of hydrogen sulfide. Nitric oxide: biology and chemistry", 71,(2017),1-5.
  • Lin H, Wang Y-N, Wei W, Yu Y-J. "Treatment of H 2 S in mine water using Fenton reagent", J China Coal Soc, 37, (2012),1760-1764.
  • Liu D, Wang Q, Wu J, Liu Y. "A review of sorbents for high-temperature hydrogen sulfide removal from hot coal gas", Environmental Chemistry Letters 17,(2019),259-276.
  • Lin F, Wang Z, Zhang Z, He Y, Zhu Y, Shao J, Yuan D, Chen G, Cen K. "Flue gas treatment with ozone oxidation: An overview on NOx, organic pollutants, and mercury", Chem Eng J 382,(2020),123030.
  • Wang Y, Wang Z, Liu Y. "Oxidation absorption of gaseous H2S using Fenton-like advanced oxidation systems", Energy & Fuels 32,(2018),11289-11295.
  • Liu Y, Wang Y. "Gaseous elemental mercury removal using VUV and heat coactivation of Oxone/H2O/O2 in a VUV-spraying reactor", Fuel 243,(2019),352-361.
  • Wang H, Yuan B, Hao R, Zhao Y, Wang X. "A critical review on the method of simultaneous removal of multi-air-pollutant in flue gas", Chem Eng J 378,(2019),122155.
  • Pagella C, De Faveri D. "H2S gas treatment by iron bioprocess", Chem Eng Sci 55,(2000),2185-2194.
  • Oyarzún P, Arancibia F, Canales C, Aroca GE. "Biofiltration of high concentration of hydrogen sulphide using Thiobacillus thioparus", Process Biochem 39,(2003),165-170.
  • Deshpande A.S, Khomane R.B, Vaidya B.K, Joshi R.M, Harle A.S, Kulkarni B.D. "Sulfur nanoparticles synthesis and characterization from H2S gas, using novel biodegradable iron chelates in W/O microemulsion", Nanoscale Research Letters 3,(2008),221-229.
  • Dumont E. "H2S removal from biogas using bioreactors: a review", International Journal of Energy and Environnement 6,(2015),479-498.
  • Safarzadeh-Amiri A, Bolton JR, Cater SR. "The use of iron in advanced oxidation processes" Journal of Advanced Oxidation Technologies 1,(1996),18-26.
  • Cetinkaya SG, Morcali M.H, Akarsu S, Ziba C.A, Dolaz M. "Comparison of classic Fenton with ultrasound Fenton processes on industrial textile wastewater", Sustainable Environment Research 28,(2018),165-170.
  • Guo R-t, Pan W-g, Zhang X-b, Ren J-x, Jin Q, Xu H-j, Wu J. "Removal of NO by using Fenton reagent solution in a lab-scale bubbling reactor", Fuel 90,(2011),3295-3298.
  • Liu Y, Zhang J, Sheng C, Zhang Y, Zhao L. "Simultaneous removal of NO and SO2 from coal-fired flue gas by UV/H2O2 advanced oxidation process", Chem Eng J 162,(2010),1006-1011.
  • Ma Y, Jin X, Hu Y, Huang Q, Wang Z. "Recovery of Hydrogen and Sulfur by Electrolysis of Ionized H2S in an Amine-Containing Organic Electrolyte with Highly Temperature-Dependent Sulfur Solubility", Energy & Fuels 34,(2020),7756-7762.
  • De Crisci AG, Moniri A, Xu Y. "Hydrogen from hydrogen sulfide: towards a more sustainable hydrogen economy", Int J Hydrogen Energy 44, (2019),1299-1327.
  • Liu Y, Wang Y. "Removal of gaseous hydrogen sulfide by a photo-Fenton wet oxidation scrubbing system", Energy & Fuels 33,(2019),10812-10819.
  • Wang Y, Wang Z, Pan J, Liu Y. "Removal of gaseous hydrogen sulfide using Fenton reagent in a spraying reactor", Fuel 239,(2019),70-75.
Yıl 2021, Cilt: 9 Sayı: 2, 153 - 159, 06.12.2021
https://doi.org/10.51354/mjen.953547

Öz

Proje Numarası

217M284

Kaynakça

  • Liu Y, Shi S, Wang Y. "Removal of Pollutants from Gas Streams Using Fenton (-like)-based Oxidation Systems: A Review", J Hazard Mater, (2021), 125927.
  • Kailasa S.K, Koduru J.R, Vikrant K, Tsang Y.F, Singhal R.K, Hussain C.M, Kim K-H. "Recent progress on solution and materials chemistry for the removal of hydrogen sulfide from various gas plants", J Mol Liq, 297, (2020), 111886.
  • Rubright S.L.M, Pearce L.L, Peterson J. "Environmental toxicology of hydrogen sulfide. Nitric oxide: biology and chemistry", 71,(2017),1-5.
  • Lin H, Wang Y-N, Wei W, Yu Y-J. "Treatment of H 2 S in mine water using Fenton reagent", J China Coal Soc, 37, (2012),1760-1764.
  • Liu D, Wang Q, Wu J, Liu Y. "A review of sorbents for high-temperature hydrogen sulfide removal from hot coal gas", Environmental Chemistry Letters 17,(2019),259-276.
  • Lin F, Wang Z, Zhang Z, He Y, Zhu Y, Shao J, Yuan D, Chen G, Cen K. "Flue gas treatment with ozone oxidation: An overview on NOx, organic pollutants, and mercury", Chem Eng J 382,(2020),123030.
  • Wang Y, Wang Z, Liu Y. "Oxidation absorption of gaseous H2S using Fenton-like advanced oxidation systems", Energy & Fuels 32,(2018),11289-11295.
  • Liu Y, Wang Y. "Gaseous elemental mercury removal using VUV and heat coactivation of Oxone/H2O/O2 in a VUV-spraying reactor", Fuel 243,(2019),352-361.
  • Wang H, Yuan B, Hao R, Zhao Y, Wang X. "A critical review on the method of simultaneous removal of multi-air-pollutant in flue gas", Chem Eng J 378,(2019),122155.
  • Pagella C, De Faveri D. "H2S gas treatment by iron bioprocess", Chem Eng Sci 55,(2000),2185-2194.
  • Oyarzún P, Arancibia F, Canales C, Aroca GE. "Biofiltration of high concentration of hydrogen sulphide using Thiobacillus thioparus", Process Biochem 39,(2003),165-170.
  • Deshpande A.S, Khomane R.B, Vaidya B.K, Joshi R.M, Harle A.S, Kulkarni B.D. "Sulfur nanoparticles synthesis and characterization from H2S gas, using novel biodegradable iron chelates in W/O microemulsion", Nanoscale Research Letters 3,(2008),221-229.
  • Dumont E. "H2S removal from biogas using bioreactors: a review", International Journal of Energy and Environnement 6,(2015),479-498.
  • Safarzadeh-Amiri A, Bolton JR, Cater SR. "The use of iron in advanced oxidation processes" Journal of Advanced Oxidation Technologies 1,(1996),18-26.
  • Cetinkaya SG, Morcali M.H, Akarsu S, Ziba C.A, Dolaz M. "Comparison of classic Fenton with ultrasound Fenton processes on industrial textile wastewater", Sustainable Environment Research 28,(2018),165-170.
  • Guo R-t, Pan W-g, Zhang X-b, Ren J-x, Jin Q, Xu H-j, Wu J. "Removal of NO by using Fenton reagent solution in a lab-scale bubbling reactor", Fuel 90,(2011),3295-3298.
  • Liu Y, Zhang J, Sheng C, Zhang Y, Zhao L. "Simultaneous removal of NO and SO2 from coal-fired flue gas by UV/H2O2 advanced oxidation process", Chem Eng J 162,(2010),1006-1011.
  • Ma Y, Jin X, Hu Y, Huang Q, Wang Z. "Recovery of Hydrogen and Sulfur by Electrolysis of Ionized H2S in an Amine-Containing Organic Electrolyte with Highly Temperature-Dependent Sulfur Solubility", Energy & Fuels 34,(2020),7756-7762.
  • De Crisci AG, Moniri A, Xu Y. "Hydrogen from hydrogen sulfide: towards a more sustainable hydrogen economy", Int J Hydrogen Energy 44, (2019),1299-1327.
  • Liu Y, Wang Y. "Removal of gaseous hydrogen sulfide by a photo-Fenton wet oxidation scrubbing system", Energy & Fuels 33,(2019),10812-10819.
  • Wang Y, Wang Z, Pan J, Liu Y. "Removal of gaseous hydrogen sulfide using Fenton reagent in a spraying reactor", Fuel 239,(2019),70-75.
Toplam 21 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Araştırma Makalesi
Yazarlar

Merve Aksu

M.hakan Morcali 0000-0002-5021-4459

Proje Numarası 217M284
Yayımlanma Tarihi 6 Aralık 2021
Yayımlandığı Sayı Yıl 2021 Cilt: 9 Sayı: 2

Kaynak Göster

APA Aksu, M., & Morcali, M. (2021). A cleaner application on hydrogen sulfide. MANAS Journal of Engineering, 9(2), 153-159. https://doi.org/10.51354/mjen.953547
AMA Aksu M, Morcali M. A cleaner application on hydrogen sulfide. MJEN. Aralık 2021;9(2):153-159. doi:10.51354/mjen.953547
Chicago Aksu, Merve, ve M.hakan Morcali. “A Cleaner Application on Hydrogen Sulfide”. MANAS Journal of Engineering 9, sy. 2 (Aralık 2021): 153-59. https://doi.org/10.51354/mjen.953547.
EndNote Aksu M, Morcali M (01 Aralık 2021) A cleaner application on hydrogen sulfide. MANAS Journal of Engineering 9 2 153–159.
IEEE M. Aksu ve M. Morcali, “A cleaner application on hydrogen sulfide”, MJEN, c. 9, sy. 2, ss. 153–159, 2021, doi: 10.51354/mjen.953547.
ISNAD Aksu, Merve - Morcali, M.hakan. “A Cleaner Application on Hydrogen Sulfide”. MANAS Journal of Engineering 9/2 (Aralık 2021), 153-159. https://doi.org/10.51354/mjen.953547.
JAMA Aksu M, Morcali M. A cleaner application on hydrogen sulfide. MJEN. 2021;9:153–159.
MLA Aksu, Merve ve M.hakan Morcali. “A Cleaner Application on Hydrogen Sulfide”. MANAS Journal of Engineering, c. 9, sy. 2, 2021, ss. 153-9, doi:10.51354/mjen.953547.
Vancouver Aksu M, Morcali M. A cleaner application on hydrogen sulfide. MJEN. 2021;9(2):153-9.

Manas Journal of Engineering 

16155