Year 2019, Volume 15, Issue 1, Pages 23 - 28 2019-03-22

Synthesis and Characterizations of TiO2/Ag Photoanodes for used Indigo Carmine Sensitizer Based Solar Cells

Soner Çakar [1] , Keziban Atacan [2] , Nuray Güy [3]

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In this work we have prepared Ag doped TiO2 composite semiconductor by microwave hydrothermal methods. The prepared TiO2/Ag photoanode was characterized via XRD, FE-SEM and DRS spectroscopy techniques. Then this composite was used as a photoanode material for dye sensitized solar cells. The TiO2/Ag photoanode was prepared by spin coating technique. The sensitizer of this solar cell is indigo carmine and it was prepared in different pH solution in ACN. The higher solar cell efficiency values were achieved up to 1.91% with TiO2/Ag photoanode and in pH 5.3 indigo carmine dye solution. As a result, in this study, it was observed that the addition of Ag nanoparticles was increased the efficiency of solar cell by 20-45%.

Dye sensitized solar cells, indigo carmine, Ag/TiO2
  • Oskam, G. 2010. Dye-sensitized solar cells with natural dyes extracted from achiote seeds, Solar Energy Materials & Solar Cells; 94: 40–44.
  • 2. Vekariya, RL, Sonigara, KK, Fadadu, KB, Vaghasiya, JB, Soni, SS. 2016. Humic Acid as a Sensitizer in Highly Stable Dye Solar Cells: Energy from an Abundant Natural Polymer Soil Component, ACS Omega; 1: 14–18.
  • 3. Gong, J, Sumathy, K, Qiao, Q, Zhou, Z. 2017. Review on dye-sensitized solar cells (DSSCs): Advanced techniques and research trends, Renewable and Sustainable Energy Reviews; 68: 234–246.
  • 4. Narayan, MR. 2012. Review : Dye sensitized solar cells based on natural photosensitizers, Renewable and Sustainable Energy Reviews; 16: 208–215.
  • 5. Dou, Y, Wu, F, Fang, L, Liu, G, Mao, C, Wan, K, Zhou, M. 2016. Enhanced performance of dye-sensitized solar cell using Bi2Te3 nano-tube/ZnO nanoparticle composite photoanode by the synergistic effect of photovoltaic and thermoelectric conversion, Journal of Power Sources; 307: 181–189.
  • 6. Gokilamani, N, Muthukumarasamy, N, Thambidurai, M, Ranjitha, A, Velauthapillai, D, Senthil, TS, Balasundaraprabhu, R. 2013. Dye-sensitized solar cells with natural dyes extracted from rose petals, Journal of Materials Science and Materials in Electronics; 24: 3394–3402.
  • 7. Kumar, KA, Subalakshmi, K, Senthilselvan, J. 2016. Effect of mixed valence state of titanium on reduced recombination for natural dye-sensitized solar cell applications, Journal of Solid State Electrochemis-try; 12: 1–12.
  • 8. Venkatachalam, P, Joby, NG, Krishnakumar, N. 2013. Enhanced photovoltaic characterization and charge transport of TiO2 nanoparti-cles/nanotubes composite photoanode based on indigo carmine dye-sensitized solar cells, Journal of Sol-Gel Science and Technology; 67: 618–628.
  • 9. Bouzidi, A, Yahia, IS, Jilani, W, El-Bashir, SM, AlFaify, S, Algarni, H, Guermazi, H. 2018. Electronic conduction mechanism and optical spectroscopy of Indigo carmine as novel organic semiconductors, Op-tical Quantum Electronics; 50: 1–15.
  • 10. Sarma, BK, Pal, AR, Bailung, H, Chutia, J. 2013. Growth of nano-crystalline TiO2 thin films and crystal anisotropy of anatase phase de-posited by direct current reactive magnetron sputtering, Materials Chemistry and Physics; 139: 979–987.
  • 11. Djerdj, I, Tonejc, AM. 2006. Structural investigations of nanocrystal-line TiO2 samples, Journal of Alloys and Compounds; 413: 159–174. 12. Tobaldi, DM, Pullar, Gualtieri, AF, Seabra, MP, Labrincha, JA. 2013. Phase composition, crystal structure and microstructure of silver and tungsten doped TiO2 nanopowders with tuneable photochromic behav-iour, Acta Materiala; 61: 5571–5585.
  • 13. Krawczyk, S, Zdyb, A. 2011. Electronic Excited States of Carotenoid Dyes Adsorbed on TiO2, Journal of Physical Chemistry C; 115: 22328–22335.
  • 14. S.S. Kanmani, K. Ramachandran, Synthesis and characterization of TiO2/ZnO core/shell nanomaterials for solar cell applications, Renew-able Energy, 2012, 43: 149–156.
  • 15. Çakar, S, Özacar, M. 2017. The effect of iron complexes of quercetin on dye-sensitized solar cell efficiency, Jornal of Photochemistry and Photobiology A Chemistry; 346: 512–522.
  • 16. Çakar, S, Özacar, M. 2016. Fe–tannic acid complex dye as photo sensitizer for different morphological ZnO based DSSCs, Spectro-chimica Acta Part A Moleculer and Biomoleculer Spectroscopy; 163: 79–88.
Primary Language en
Subjects Engineering
Published Date 22-03-2019
Journal Section Articles
Authors

Orcid: 0000-0002-3745-954X
Author: Soner Çakar (Primary Author)
Institution: BÜLENT ECEVİT ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ
Country: Turkey


Author: Keziban Atacan
Institution: SAKARYA ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA BÖLÜMÜ
Country: Turkey


Author: Nuray Güy
Institution: SAKARYA ÜNİVERSİTESİ, FEN-EDEBİYAT FAKÜLTESİ, KİMYA BÖLÜMÜ
Country: Turkey


Bibtex @research article { cbayarfbe430644, journal = {Celal Bayar University Journal of Science}, issn = {1305-130X}, eissn = {1305-1385}, address = {Celal Bayar University}, year = {2019}, volume = {15}, pages = {23 - 28}, doi = {10.18466/cbayarfbe.430644}, title = {Synthesis and Characterizations of TiO2/Ag Photoanodes for used Indigo Carmine Sensitizer Based Solar Cells}, key = {cite}, author = {Çakar, Soner and Atacan, Keziban and Güy, Nuray} }
APA Çakar, S , Atacan, K , Güy, N . (2019). Synthesis and Characterizations of TiO2/Ag Photoanodes for used Indigo Carmine Sensitizer Based Solar Cells. Celal Bayar University Journal of Science, 15 (1), 23-28. DOI: 10.18466/cbayarfbe.430644
MLA Çakar, S , Atacan, K , Güy, N . "Synthesis and Characterizations of TiO2/Ag Photoanodes for used Indigo Carmine Sensitizer Based Solar Cells". Celal Bayar University Journal of Science 15 (2019): 23-28 <http://dergipark.org.tr/cbayarfbe/issue/44005/430644>
Chicago Çakar, S , Atacan, K , Güy, N . "Synthesis and Characterizations of TiO2/Ag Photoanodes for used Indigo Carmine Sensitizer Based Solar Cells". Celal Bayar University Journal of Science 15 (2019): 23-28
RIS TY - JOUR T1 - Synthesis and Characterizations of TiO2/Ag Photoanodes for used Indigo Carmine Sensitizer Based Solar Cells AU - Soner Çakar , Keziban Atacan , Nuray Güy Y1 - 2019 PY - 2019 N1 - doi: 10.18466/cbayarfbe.430644 DO - 10.18466/cbayarfbe.430644 T2 - Celal Bayar University Journal of Science JF - Journal JO - JOR SP - 23 EP - 28 VL - 15 IS - 1 SN - 1305-130X-1305-1385 M3 - doi: 10.18466/cbayarfbe.430644 UR - https://doi.org/10.18466/cbayarfbe.430644 Y2 - 2019 ER -
EndNote %0 Celal Bayar University Journal of Science Synthesis and Characterizations of TiO2/Ag Photoanodes for used Indigo Carmine Sensitizer Based Solar Cells %A Soner Çakar , Keziban Atacan , Nuray Güy %T Synthesis and Characterizations of TiO2/Ag Photoanodes for used Indigo Carmine Sensitizer Based Solar Cells %D 2019 %J Celal Bayar University Journal of Science %P 1305-130X-1305-1385 %V 15 %N 1 %R doi: 10.18466/cbayarfbe.430644 %U 10.18466/cbayarfbe.430644
ISNAD Çakar, Soner , Atacan, Keziban , Güy, Nuray . "Synthesis and Characterizations of TiO2/Ag Photoanodes for used Indigo Carmine Sensitizer Based Solar Cells". Celal Bayar University Journal of Science 15 / 1 (March 2019): 23-28. https://doi.org/10.18466/cbayarfbe.430644