Year 2019, Volume 15, Issue 1, Pages 131 - 138 2019-03-22

Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs

Merve Zeyrek Ongun [1]

54 145

An oxygen sensitive optical chemical sensor has been developed based on fluorescence quenching of the meso-tetraphenylporphyrin (H2TPP) immobilized in a silicone derivative along with silver nanoparticles (AgNPs) and different ionic liquids (ILs). Emission spectra of the H2TTP doped thin film exhibited an increment due to the formation of an associated complex between H2TPP and AgNPs. The offered thin films responded to the oxygen in the direction of quenching with extreme sensitivity. Emission and decay-time measurements of the H2TPP in thin solid matrices were studied in the concentration range of 0-100% p(O2). Utilization of the porphyrin dye along with AgNPs and ionic liquid as an additive exhibited higher oxygen sensitivity with respect to the additive-free forms and resulted in many advances such as linear response, improvement in sensor dynamics and extreme sensitivity. Together with additives, the meso-tetraphenylporphyrin-based composites yielded higher Stern-Volmer constant (Ksv), faster response time, and larger linear response range when compared with the additive-free form. The response time of the sensor has been recorded as 90 s

meso-tetraphenylporphyrin (H2TPP), silver nanoparticles, ionic liquids, O2, sensing
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Primary Language en
Subjects Engineering
Published Date 22-03-2019
Journal Section Articles
Authors

Author: Merve Zeyrek Ongun (Primary Author)
Country: Turkey


Dates

Publication Date: March 22, 2019

Bibtex @research article { cbayarfbe507626, journal = {Celal Bayar University Journal of Science}, issn = {1305-130X}, eissn = {1305-1385}, address = {Celal Bayar University}, year = {2019}, volume = {15}, pages = {131 - 138}, doi = {10.18466/cbayarfbe.507626}, title = {Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs}, key = {cite}, author = {Zeyrek Ongun, Merve} }
APA Zeyrek Ongun, M . (2019). Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs. Celal Bayar University Journal of Science, 15 (1), 131-138. DOI: 10.18466/cbayarfbe.507626
MLA Zeyrek Ongun, M . "Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs". Celal Bayar University Journal of Science 15 (2019): 131-138 <http://dergipark.org.tr/cbayarfbe/issue/44005/507626>
Chicago Zeyrek Ongun, M . "Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs". Celal Bayar University Journal of Science 15 (2019): 131-138
RIS TY - JOUR T1 - Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs AU - Merve Zeyrek Ongun Y1 - 2019 PY - 2019 N1 - doi: 10.18466/cbayarfbe.507626 DO - 10.18466/cbayarfbe.507626 T2 - Celal Bayar University Journal of Science JF - Journal JO - JOR SP - 131 EP - 138 VL - 15 IS - 1 SN - 1305-130X-1305-1385 M3 - doi: 10.18466/cbayarfbe.507626 UR - https://doi.org/10.18466/cbayarfbe.507626 Y2 - 2019 ER -
EndNote %0 Celal Bayar University Journal of Science Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs %A Merve Zeyrek Ongun %T Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs %D 2019 %J Celal Bayar University Journal of Science %P 1305-130X-1305-1385 %V 15 %N 1 %R doi: 10.18466/cbayarfbe.507626 %U 10.18466/cbayarfbe.507626
ISNAD Zeyrek Ongun, Merve . "Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs". Celal Bayar University Journal of Science 15 / 1 (March 2019): 131-138. https://doi.org/10.18466/cbayarfbe.507626
AMA Zeyrek Ongun M . Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs. Celal Bayar Univ J Sci. 2019; 15(1): 131-138.
Vancouver Zeyrek Ongun M . Development of Highly Sensitive Metal-Free Tetraphenylporphyrin-Based Optical Oxygen Sensing Materials along with ILs and AgNPs. Celal Bayar University Journal of Science. 2019; 15(1): 138-131.