Year 2017, Volume 38, Issue 3, Pages 492 - 501 2017-09-30

Influences of Cerium Addition on the Structural and Superconducting Properties with Pb and Pb-free Bi2Sr2Ca2Cu3Oδ System
Kurşunlu ve Kurşunsuz Bi2Sr2Ca2Cu3Oδ Sistemine Seryum Katkısının Yapısal ve Süperiletkenlik Özelliklere Etkileri

Hasan AĞIL [1]

151 227

In this study, the thermal, structural and superconducting properties with lead and lead-free cerium added Bi2Sr2Ca2Cu3Oδ superconducting system have been investigated. Cerium-added superconductors with the general stoichiometry of Bi2-xPbxSr2Ca2Cu3CeyOδ (x = 0 and 0.4 and y = 0, 0.1, 0.2 and 0.4) were prepared by the conventional solid state synthesis technique. The materials are characterized by DTA/TGA, XRD, SEM, EDX and R-T measurements. Although the desired phase is the Bi-2223 phase in the manufactured materials, it is observed that Bi-2212 phase predominates in some materials. Especially while being the Bi-2212 phase in Pb-free samples, the main phase is relatively Bi-2223 phase in Pb containing samples. Consequently, critical temperature values have also decreased and transition behavior has been observed in two steps.  

Bu çalışmada kurşunsuz ve kurşunlu seryum ilave edilmiş Bi2Sr2Ca2Cu3Oδ süperiletken sisteminin termal, yapısal ve süperiletkenlik özellikleri araştırılmıştır. Bi2-xPbxSr2Ca2Cu3CeyOδ (x = 0 ve 0.4 ve y = 0, 0.1, 0.2 ve 0.4) genel stokiyometrisine sahip seryum katkılı süperiletkenler geleneksel katı hal sentezleme tekniği ile hazırlanmıştır. Malzemeler DTK/TGA, XRD, SEM, EDX ve R-T ölçümleri ile karakterize edilmiştir. Üretilen malzemelerde elde edilmek istenen faz Bi-2223 fazı olmasına rağmen bazı malzemelerde Bi-2212 fazının baskın olduğu görülmüştür. Özellikle kurşunsuz malzemelerde ana faz Bi-2212 fazı iken kurşunlu malzemelerde ise nispeten ana faz Bi-2223 fazıdır. Buna bağlı olarak kritik sıcaklık değerleri düşmüş ve iki adımda geçiş davranışı gözlemlenmiştir.  

  • [1]. Runde, M.: IEEE Trans. Appl. Supercond. 5, 813 (1995).
  • [2]. Godeke, A., Cheng, D., Dietderich, D.R., English, C.D., Felice, H., Hannaford, C.R., Prestemon, S.O., Sabbi, G., Scanlan, R.M., Hikichi, Y., Nishioka, J., Hasegawa, T.: IEEE Trans. Appl. Supercond. 18, 516 (2008).
  • [3]. Miao, H., Meinesz, M., Czabai, B., Parrell, J., Hong, S.: AIP Conf. Proc. 986, 423 (2008).
  • [4]. Maeda, H., Tanaka, Y., Fukutomi, M., Asano, T.: Jpn. J. Appl. Phys. 27, L209 (1988).
  • [5]. Mousavi Ghahfarokhi, S.E., Zargar Shoushtari, M.: Physica B 405, 4643 (2010).
  • [6]. P. Majewski, J. Mater. Res. 15 (2000) 854.
  • [7]. Biju, P.M. Sarun, R.P. Aloysius, U. Syamaprasad, J. Alloy Compd. 433 (2007) 68–72.
  • [8]. X.Y. Lu, K. Watanabe, D. Yi, H. Chen, A. Nagata, C. Physica, Supercond. Appl. 471 (2011) 1090.
  • [9]. C. Terzioglu, H. Aydin, O. Ozturk, E. Bekiroglu, I. Belenli, Phys. B: Cond. Mater. 403 (2008) 3354–3359.
  • [10]. T.S. Chin, T.W. Huang, W.T. Lin, N.C. Wa, Y.H. Chou, T.C. Wu, P.T. Wu, H.H. Yen, Symp. Proc. Mater. Res. Soc., 1988, p. 261.
  • [11]. L. Ciontea, V. Boffa, T. Petrisor, R. Bruzzese, E. Perte, C. Alvani, Phys. C: Supercond. Appl. 257 (1996) 304.
  • [12]. Y.W. Hsueh, S.C. Chang, R.S. Liu, L. Woodall, M. Gerards, Mater. Res. Bull. 36 (2001) 1653.
  • [13]. P.E. Kazin, Yu D. Tretvakov, Russian Chem. Rev. 72 (2003) 849.
  • [14]. Sedky, J. Phys. Chem. Sol. 70 (2009) 9.
  • [15]. W. Zhu, C.K. Kuo, P.S. Nicholson, J. Am. Ceram. Soc. 80 (8) (1997) 1975.
  • [16]. J.C. Grivel, F. Kubel, R. Flukiger, J. Therm. Anal. 48 (1997) 665–674.
  • [17]. B.A. Marinkovic, P.M. Jardim, F. Rizzo, L. Mancic, O. Milosevic, Materials Chemistry and Physics 94 (2005) 233–240.
  • [18]. H.K. Liu, S.X. Dou, M. Ionescu, Z.B. Shao, K.R. Liu, L.Q. Liu, J. Mater. Res. 10 (11) (1995) 2933–2937.
  • [19]. Chong, M. Hiroi, J. Izumi, Y. Shimoyama, Y. Nakayama, K. Kishio, T. Terashima, Y. Bando, M. Takano, Science 276 (1997) 770–773.
  • [20]. T. Motohashi, Y. Nakayama, T. Fujita, K. Kitazawa, J. Shimoyama, K. Kishio, Phys. Rev. B 59 (1999) 14080–14086.
  • [21]. W.D.Wu, A. Keren, L.P. Le, B.J. Sternlieb, G.M. Luke, Y.J. Uemura, Phys. Rev. B 47 (1993) 8172–8186.
  • [22]. Crossley, A.D. Caplin, A.V. Berenov, J.L. MacManus, Supercond. Sci. Technol. 13 (2000) 551–557.
  • [23]. C.W. Chiu, R.L. Meng, L. Gao, Z.J. Huang, F. Chen, Y.Y. Xue, Nature 365, 323 (1993).
  • [24]. S.A. Halim, S.A. Khawaldeh, S.B. Mohammed, H. Azhan, Mater. Chem. Phys. 61, 251 (1999).
Subjects Basic Sciences
Journal Section Articles
Authors

Author: Hasan AĞIL
Country: Turkey


Bibtex @research article { csj340877, journal = {Cumhuriyet Science Journal}, issn = {2587-2680}, eissn = {2587-246X}, address = {Cumhuriyet University}, year = {2017}, volume = {38}, pages = {492 - 501}, doi = {10.17776/csj.340877}, title = {Influences of Cerium Addition on the Structural and Superconducting Properties with Pb and Pb-free Bi2Sr2Ca2Cu3Oδ System}, key = {cite}, author = {AĞIL, Hasan} }
APA AĞIL, H . (2017). Influences of Cerium Addition on the Structural and Superconducting Properties with Pb and Pb-free Bi2Sr2Ca2Cu3Oδ System. Cumhuriyet Science Journal, 38 (3), 492-501. DOI: 10.17776/csj.340877
MLA AĞIL, H . "Influences of Cerium Addition on the Structural and Superconducting Properties with Pb and Pb-free Bi2Sr2Ca2Cu3Oδ System". Cumhuriyet Science Journal 38 (2017): 492-501 <http://dergipark.org.tr/csj/issue/31252/340877>
Chicago AĞIL, H . "Influences of Cerium Addition on the Structural and Superconducting Properties with Pb and Pb-free Bi2Sr2Ca2Cu3Oδ System". Cumhuriyet Science Journal 38 (2017): 492-501
RIS TY - JOUR T1 - Influences of Cerium Addition on the Structural and Superconducting Properties with Pb and Pb-free Bi2Sr2Ca2Cu3Oδ System AU - Hasan AĞIL Y1 - 2017 PY - 2017 N1 - doi: 10.17776/csj.340877 DO - 10.17776/csj.340877 T2 - Cumhuriyet Science Journal JF - Journal JO - JOR SP - 492 EP - 501 VL - 38 IS - 3 SN - 2587-2680-2587-246X M3 - doi: 10.17776/csj.340877 UR - https://doi.org/10.17776/csj.340877 Y2 - 2017 ER -
EndNote %0 Cumhuriyet Science Journal Influences of Cerium Addition on the Structural and Superconducting Properties with Pb and Pb-free Bi2Sr2Ca2Cu3Oδ System %A Hasan AĞIL %T Influences of Cerium Addition on the Structural and Superconducting Properties with Pb and Pb-free Bi2Sr2Ca2Cu3Oδ System %D 2017 %J Cumhuriyet Science Journal %P 2587-2680-2587-246X %V 38 %N 3 %R doi: 10.17776/csj.340877 %U 10.17776/csj.340877
ISNAD AĞIL, Hasan . "Influences of Cerium Addition on the Structural and Superconducting Properties with Pb and Pb-free Bi2Sr2Ca2Cu3Oδ System". Cumhuriyet Science Journal 38 / 3 (September 2017): 492-501. https://doi.org/10.17776/csj.340877