Year 2017, Volume 38, Issue 4, Pages 121 - 129 2017-12-08

Investigation of Semiconductor Quantum Dots for Quantum Sensitized Solar Cells (QDSSCs)
Kuantum Nokta Tabanlı Güneş Pilleri (QDSSCs) için Yarıiletken Kuantum Noktalarının İncelenmesi

Sabit HOROZ [1]

204 654

Semiconductor quantum dots (QDs) have recently attracted great interest as a material for solar energy conversion due to its versatile optical and electrical properties. QD-based solar cells (QDSSCs) are one of the evolving semiconductor QD solar cells that show promising developments for the new generation of solar cells. This work focuses on 1) quantum confinement effect in QDSSC, 2) multiple excitation production (MEG) of QDs, 3) production methods of QDs and 4) nanocrystalline photoelectrodes for solar cells. In addition, proposals are made for research on future QDSSCs. Although the QDSSC's effectiveness is still low, I believe there will be significant breakthroughs in the development of QDSSCs in the future.

Yarı iletken kuantum noktaları (QD'ler) son zamanlarda çok yönlü optik ve elektriksel özelliklerinden dolayı güneş enerjisi dönüşümü için bir malzeme olarak büyük ilgi görmektedir. QD tabanlı güneş pilleri (QDSSCs), yeni nesil güneş pilleri için umut verici gelişmeler gösteren gelişen yarıiletken QD güneş pillerinden biridir. Bu çalışmada, 1) QDSSC'lerde kuantum sınırlandırma etkisi, 2) QD'lerin çoklu eksitasyon üretimi (MEG), 3) QD'lerin üretim yöntemleri ve 4) güneş pilleri için nanokristalli fotoelektrodlar gibi konular üzerinde durulmuştur. Ayrıca, gelecekteki QDSSC’ler üzerine yapılacak araştırmalar için önerilerde bulunulmaktadır. QDSSC'lerin etkinliği halen düşük olmakla birlikte, ileride QDSSC'lerin geliştirilmesinde önemli atılımlar olacağı kanaatindeyim.

  • [1]. Tada H., Fujishima M., Kobayashi H. Photodeposition of metal sulfide quantum dots on titanium(IV) dioxide and the applications to solar energy conversion. Chem. Soc. Rev. 2011; 40 (7): 4232-4243.
  • [2]. Santra P.K., Kamat P.V. Mn-Doped Quantum Dot Sensitized Solar Cells: A Strategy to Boost Efficiency over 5%. J. Am. Chem. Soc.2002; 134(5): 2508-2511.
  • [3]. Ryu J., Lee S.H., Nam D.H., Park C.B. Rational design and engineering of quantum-dot-sensitized TiO₂ nanotube arrays for artificial photosynthesis. Adv. Mater. 2011; 23(16): 1883-1888.
  • [4]. Kamat P.V. Quantum Dot Solar Cells.- The Next Big Thing in Photovoltaics. J. Phys. Chem. Lett. 2013; 4 (6): 908-918.
  • [5]. Oregan B., Gratzel M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature. 1991; 353: 737-740.
  • [6]. Bomben P.G., Robson K.C.D., Sedach P.A., Berlinguette C.P. On the Viability of Cyclometalated Ru(II) Complexes for Light-Harvesting Applications. Inorg. Chem.2009; 48 (20): 9631-9643.
  • [7]. Zhao H.C., Harney J.P., Huang Y.T., Yum J.H., Nazeeruddin M.K., Gratzel M., et al., Evaluation of a ruthenium oxyquinolate architecture for dye-sensitized solar cells. Inorg. Chem. 2012; 51(1): 1-3.
  • [8]. Panigrahi S, Basak D. J Colloid Interface Sci. 2011;364: 10-17.
  • [9]. Shen Q., Kobayashi J., Diguna L.J., Toyoda T., Effect of ZnS coating on the photovoltaic properties of CdSe quantum dot-sensitized solar cells. J. Appl. Phys. 2008; 103: 084304.
  • [10]. Plass R., Pelet,S., Krueger J., Gratzel M., Bach U. Quantum Dot Sensitization of Organic-Inorganic Hybrid Solar Cells. J. Phys. Chem. B. 2002; 106 (31): 7578-7580.
  • [11]. Yu P., Zhu K., Norman A.G., Ferrere S., Frank A.J., Nozik A.J. Nanocrystalline TiO2 Solar Cells Sensitized with InAs Quantum Dots. J. Phys. Chem. B. 2006; 110 (50): 25451-25454.
  • [12]. Gonzalez-Pedro V., Xu X., Mora-Sero I., Bisquert J. Modeling high-efficiency quantum dot sensitized solar cells. Acs Nano.2010; 4(10): 5783-5790.
  • [13]. Yu X.Y., Liao J.Y., Qiu K.Q., Kuang D.B., Su C.Y. Dynamic study of highly efficient CdS/CdSe quantum dot-sensitized solar cells fabricated by electrodeposition. Acs Nano. 2011; 5 (12): 9494-9500.
  • [14]. Cheng C.W., Karuturi S.K., Liu L.J., Liu J.P., Li H.X., Su L.T., et al., Quantum-Dot-Sensitized TiO2 Inverse Opals for Photoelectrochemical Hydrogen Generation. Small. 2012; 8 (1): 37-42.
  • [15]. Zhu G., Pan L., Xu T., Sun Z.. CdS/CdSe-cosensitized TiO2 photoanode for quantum-dot-sensitized solar cells by a microwave-assisted chemical bath deposition method. Acs Appl. Mater. Inter. 2011; 3(8): 3146-3151.
  • [16]. Lee Y.L., Lo Y.S.. Highly Efficient Quantum-Dot-Sensitized Solar Cell Based on Co-Sensitization of CdS/CdSe. Adv. Funct. Mater.2009; 19 (4): 604-609.
  • [17]. Tian J.J., Gao R., Zhang Q.F., Zhang S.G., Li Y.W., Lan J.L., et al.,. Enhanced Performance of CdS/CdSe Quantum Dot Cosensitized Solar Cells via Homogeneous Distribution of Quantum Dots in TiO2 Film. J. Phys. Chem. C. 2012; 116 (35): 18655-18662.
  • [18]. Kamat P.V. Quantum Dot Solar Cells. Semiconductor Nanocrystals as Light Harvesters. J. Phys. Chem. C. 2008; 112 (48): 18737-18753.
  • [19]. Chakrapani V., Baker D., Kamat P.V., Understanding the Role of the Sulfide Redox Couple (S2–/Sn2–) in Quantum Dot-Sensitized Solar Cells. J. Am. Chem. Soc. 2001; 133(24): 9607-9615.
  • [20]. Zhang Q., Uchaker E., Candelaria S.L., Cao G. Nanomaterials for energy conversion and storage. Chem. Soc. Rev. 2013; 42 (7): 3127-3171.
  • [21]. Segets D., Lucas J.M., Taylor R.N.K., Scheele M., Zheng H., Alivisatos A.P., et al., Determination of the quantum dot band gap dependence on particle size from optical absorbance and transmission electron microscopy measurements. Acs Nano. 2012; 6(10): 9021-9032.
  • [22]. Wood V., Bulović V. Colloidal quantum dot light-emitting devices. Nano Rev. 2010; 1: 5202.
  • [23]. Shibu E., Sonoda A., Tao Z., Feng Q., Furube A., Masuo S., et al. Energy materials: supramolecular nanoparticles for solar energy harvesting. Nano Rev.2013; 4: 2107.
  • [24]. Lee J.R.I., Meulenberg R.W., Hanif K.M., Mattoussi H., Klepeis J.E., Terminello L.J., et al., Experimental Observation of Quantum Confinement in the Conduction Band of CdSe Quantum Dots. Phys. Rev. Lett. 2007; 98: 146803.
  • [25]. Moreels I., Lambert K., Smeets D., De Muynck D., Nollet T., Martins J.C., et al., Size-dependent optical properties of colloidal PbS quantum dots. Acs Nano. 2009; 3, 3023-3030.
  • [26]. Kongkanand A., Tvrdy K., Takechi K., Kuno M., Kamat P.V. Quantum Dot Solar Cells. Tuning Photoresponse through Size and Shape Control of CdSe−TiO2 Architecture. J. Am. Chem Soc.2008; 130: 4007-4015.
  • [27]. Xu Y., Schoonen M.A.A. The absolute energy positions of conduction and valence bands of selected semiconducting minerals. Am. Mineral. 2000; 85: 543-556.
  • [28]. Kim .SH., Markovich G., Rezvani S., Choi S.H., Wang K.L., Heath J.R. Tunnel diodes fabricated from CdSe nanocrystal monolayers. Appl. Phys. Lett. 1999; 74: 317-319.
  • [29]. Nozik, A.J. Nanoscience and nanostructures for photovoltaics and solar fuels. Nano Lett. 2010; 10 (8): 2735-2741.
  • [30]. Semonin O.E., Luther J.M., Choi S., Chen H.Y., Gao J., Nozik A.J., et al. Peak external photocurrent quantum efficiency exceeding 100% via MEG in a quantum dot solar cell. Science 2011; 334 (6062): 1530-1533.
  • [31]. Beard M.C. Multiple Exciton Generation in Semiconductor Quantum Dots. J. Phys. Chem. Lett. 2011; 2 (11): 1282-1288.
  • [32]. Emin S., Singh S.P., Han L., Satoh N., Islam A. Colloidal quantum dot solar cells. Sol. Energy 2011; 85 (6): 1264-1282.
  • [33]. Halim M.A. Harnessing Sun’s Energy with Quantum Dots Based Next Generation Solar Cell. Nanomaterials 2013; 3 (1): 22-47.
  • [34]. Choi Y., Seol M., Kim W., Yong K., Chemical Bath Deposition of Stoichiometric CdSe Quantum Dots for Efficient Quantum-Dot-Sensitized Solar Cell Application. J. Phys. Chem. C 2014; 118 (11): 5664-5670.
  • [35]. Hu Y., Wang B., Zhang J., Wang T., Liu R., Zhang J., et al. Synthesis and photoelectrochemical response of CdS quantum dot-sensitized TiO2 nanorod array photoelectrodes. Nanoscale Res. Lett.2013; 8 (1): 222.
  • [36]. Senthamilselvi V., Saravanakumar K., Begum N.J., Anandhi R., Ravichandran A.T., Sakthivel B., et al. Photovoltaic properties of nanocrystalline CdS films deposited by SILAR and CBD techniques-a comparative study. J. Mater. Sci: Mater. Electron 2012; 23(1): 302-308.
  • [37]. Gimenez S., Mora-Sero I., Macor L., Guijarro N., Lana-Villarreal T., Go´mez R., et al. Improving the performance of colloidal quantum-dot-sensitized solar cells. Nanotechnol. 2009; 20: 295204.
  • [38]. Guijarro N., Lana-Villarreal T., Mora-Sero I., Bisquert J., Go´mez R. CdSe Quantum Dot-Sensitized TiO2 Electrodes: Effect of Quantum Dot Coverage and Mode of Attachmen. J. Phys. Chem. C 2009; 113 (10): 4208-4214.
  • [39]. Hossain M.A., James R.J., Shen C., Jia P.H., Koh Z.Y., Mathews N., et al., 2012. CdSe-sensitized mesoscopic TiO2 solar cells exhibiting >5% efficiency: redundancy of CdS buffer layer. J. Mater. Chem. 2012; 22 (32): 16235-16242.
  • [40]. Lee J.W., Son D.Y., Ahn T.K., Shin H.W., Kim I.Y., Hwang S.J., et al. Quantum-Dot-Sensitized Solar Cell with Unprecedentedly High Photocurrent. Sci. Rep. 2013; 3: 1050.
  • [41]. Zhang Q.F., Cao G.Z. Hierarchically structured photoelectrodes for dye-sensitized solar cells. J. Mater. Chem.2011; 21 (19): 6769-6774.
  • [42]. Zhang Q.F., Chou T.R., Russo B., Jenekhe S.A., Cao G.Z. Aggregation of ZnO nanocrystallites for high conversion efficiency in dye-sensitized solar cells. Angew Chem. Int. Ed. Engl. 2008; 47(13): 2402-2406.
  • [43]. Zhang Q.F., Dandeneau C.S., Zhou X.Y., Cao G.Z. ZnO nanostructures for dye-sensitized solar cells. Adv. Mater. 2009; 21: 4087-108.
  • [44]. Zhang Q.F., Yodyingyong S., Xi J.T., Myers D., Cao G.Z. Oxide nanowires for solar cell applications. Nanoscale 2012; 4 (5): 1436-1445.
  • [45]. Seol M., Ramasamy E., Lee J., Yong K. Highly Efficient and Durable Quantum Dot Sensitized ZnO Nanowire Solar Cell Using Noble-Metal-Free Counter Electrode. J. Phys. Chem. C. 2011; 115: (44), 22018-22024.
  • [46]. Yao C.Z., Wei B.H., Meng L.X., Li H., Gong Q.J, Sun H., et al. Controllable electrochemical synthesis and photovoltaic performance of ZnO/CdS core–shell nanorod arrays on fluorine-doped tin oxide. J. Power Sources 2012; 207: 222-228.
  • [47]. Bora T., Kyaw H.H., Dutta J. Zinc oxide-zinc stannate core–shell nanorod arrays for CdS quantum dot sensitized solar cells. Electrochim. Acta 2012; 68: 141-145.
  • [48]. Tian J.J., Zhang Q.F., Zhang L.L., Gao R., Shen L.F., Zhang S.G., et al. ZnO/TiO2 nanocable structured photoelectrodes for CdS/CdSe quantum dot co-sensitized solar cells. Nanoscale 2013; 5 (3): 936-943.
  • [49]. Tian J.J., Zhang Q.F., Zhang L.L., Gao R., Shen L.F., Zhang S.G., et al.. Energy materials: core/shell structural photoelectrodes assembled with quantum dots for solar cells. Nano Rev. 2013; 4: 21080.
  • [50]. Irannejad A., Janghorban K., Tan O.K., Huang H., Lim C.K., Tan P.Y., et al. Effect of the TiO2 shell thickness on the dye-sensitized solar cells with ZnO–TiO2 core-shell nanorod electrodes. Electrochim. Acta 2011; 58: 19-24.
Subjects Basic Sciences
Journal Section Natural Sciences
Authors

Author: Sabit HOROZ (Primary Author)

Bibtex @research article { csj363334, journal = {Cumhuriyet Science Journal}, issn = {2587-2680}, eissn = {2587-246X}, address = {Cumhuriyet University}, year = {2017}, volume = {38}, pages = {121 - 129}, doi = {10.17776/csj.363334}, title = {Investigation of Semiconductor Quantum Dots for Quantum Sensitized Solar Cells (QDSSCs)}, key = {cite}, author = {HOROZ, Sabit} }
APA HOROZ, S . (2017). Investigation of Semiconductor Quantum Dots for Quantum Sensitized Solar Cells (QDSSCs). Cumhuriyet Science Journal, 38 (4), 121-129. DOI: 10.17776/csj.363334
MLA HOROZ, S . "Investigation of Semiconductor Quantum Dots for Quantum Sensitized Solar Cells (QDSSCs)". Cumhuriyet Science Journal 38 (2017): 121-129 <http://dergipark.org.tr/csj/issue/32371/363334>
Chicago HOROZ, S . "Investigation of Semiconductor Quantum Dots for Quantum Sensitized Solar Cells (QDSSCs)". Cumhuriyet Science Journal 38 (2017): 121-129
RIS TY - JOUR T1 - Investigation of Semiconductor Quantum Dots for Quantum Sensitized Solar Cells (QDSSCs) AU - Sabit HOROZ Y1 - 2017 PY - 2017 N1 - doi: 10.17776/csj.363334 DO - 10.17776/csj.363334 T2 - Cumhuriyet Science Journal JF - Journal JO - JOR SP - 121 EP - 129 VL - 38 IS - 4 SN - 2587-2680-2587-246X M3 - doi: 10.17776/csj.363334 UR - https://doi.org/10.17776/csj.363334 Y2 - 2017 ER -
EndNote %0 Cumhuriyet Science Journal Investigation of Semiconductor Quantum Dots for Quantum Sensitized Solar Cells (QDSSCs) %A Sabit HOROZ %T Investigation of Semiconductor Quantum Dots for Quantum Sensitized Solar Cells (QDSSCs) %D 2017 %J Cumhuriyet Science Journal %P 2587-2680-2587-246X %V 38 %N 4 %R doi: 10.17776/csj.363334 %U 10.17776/csj.363334
ISNAD HOROZ, Sabit . "Investigation of Semiconductor Quantum Dots for Quantum Sensitized Solar Cells (QDSSCs)". Cumhuriyet Science Journal 38 / 4 (December 2017): 121-129. https://doi.org/10.17776/csj.363334