Year 2018, Volume 39, Issue 1, Pages 192 - 195 2018-03-16

Lattice Energies for Groups 1 and 2 Halides from Absolute Hardness
Kimyasal Sertlikten Grup 1 ve 2 Halojenürlerin Örgü Enerjileri

Robson Fernandes DE FARIAS [1] , Savaş KAYA [2]

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In this work, we presented new empirical equations to calculate the lattice energy values of groups 1 and 2 halides based on absolute hardness values of cations and anions forming the ionic compound.

In the given equations, r+ and r+2 = cation radius (pm); η+ and η+2 = cation absolute hardness (eV) and η- = anion absolute hardness (eV). Here, it should be noted that calculated lattice energy values for mentioned ionic compounds are in good agreement with the reference values obtained from the literature. 

Bu çalışmada grup 1 ve 2 halojenürlerin örgü enerjilerini hesaplamak için iyonik bileşiği oluşturan katyon ve anyonların mutlak sertlik değerlerine dayalı yeni denklemler türetilmiştir.

Verilen denklemlerde, r+ ve r+2 = katyon yarıçapı (pm); η+ ve η+2 = katyon mutlak sertliği (eV). η- = anyon mutlak sertliği (eV). Belirtilmelidir ki, çalışmada dikkate alınan iyonik bileşikler için elde edilen denklemler aracılığıyla hesaplanan örgü enerjisi değerleri, literatürden elde edilen referans değerler ile uyum içerisindedir.

  • [1] R.F. de Farias, Inorg. Chem., 55 (23) (2016) 12126. [2] L. Glasser, H.D.B. Jenkins, J. Am. Chem. Soc., 122 (2000) 632. [3] S. Kaya, C. Kaya, Inorg. Chem., 54 (2015) 8207. [4] R.F. de Farias, Chem. Res. J., 2(4) (2017) 188. [5] M.V. Putz, Absolute and chemical electronegativity and hardness, Nova Science Publishers, New York, 2009. [6] http://www.rsc.org/periodic-table. [7] L. Mu, C. Feng, H. He, Commun. Math. Comput. Chem., 56 (2000) 97. [8] CRC Handbook of Chemistry and Physics 96th ed., Taylor and Francis, Boca Raton, 2016. [9] http://abulafia.mt.ic.ac.uk/shannon/. [10] A.F. Kapustinskii, Q. Rev. Chem. Soc., 10 (1956) 283. [11] R.F. de Farias, unpublished results.
Primary Language en
Subjects Basic Sciences
Journal Section Natural Sciences
Authors

Author: Robson Fernandes DE FARIAS
Country: Brazil


Author: Savaş KAYA
Country: Turkey


Bibtex @research article { csj345660, journal = {Cumhuriyet Science Journal}, issn = {2587-2680}, eissn = {2587-246X}, address = {Cumhuriyet University}, year = {2018}, volume = {39}, pages = {192 - 195}, doi = {10.17776/csj.345660}, title = {Lattice Energies for Groups 1 and 2 Halides from Absolute Hardness}, key = {cite}, author = {DE FARIAS, Robson Fernandes and KAYA, Savaş} }
APA DE FARIAS, R , KAYA, S . (2018). Lattice Energies for Groups 1 and 2 Halides from Absolute Hardness. Cumhuriyet Science Journal, 39 (1), 192-195. DOI: 10.17776/csj.345660
MLA DE FARIAS, R , KAYA, S . "Lattice Energies for Groups 1 and 2 Halides from Absolute Hardness". Cumhuriyet Science Journal 39 (2018): 192-195 <http://dergipark.org.tr/csj/issue/36110/345660>
Chicago DE FARIAS, R , KAYA, S . "Lattice Energies for Groups 1 and 2 Halides from Absolute Hardness". Cumhuriyet Science Journal 39 (2018): 192-195
RIS TY - JOUR T1 - Lattice Energies for Groups 1 and 2 Halides from Absolute Hardness AU - Robson Fernandes DE FARIAS , Savaş KAYA Y1 - 2018 PY - 2018 N1 - doi: 10.17776/csj.345660 DO - 10.17776/csj.345660 T2 - Cumhuriyet Science Journal JF - Journal JO - JOR SP - 192 EP - 195 VL - 39 IS - 1 SN - 2587-2680-2587-246X M3 - doi: 10.17776/csj.345660 UR - https://doi.org/10.17776/csj.345660 Y2 - 2018 ER -
EndNote %0 Cumhuriyet Science Journal Lattice Energies for Groups 1 and 2 Halides from Absolute Hardness %A Robson Fernandes DE FARIAS , Savaş KAYA %T Lattice Energies for Groups 1 and 2 Halides from Absolute Hardness %D 2018 %J Cumhuriyet Science Journal %P 2587-2680-2587-246X %V 39 %N 1 %R doi: 10.17776/csj.345660 %U 10.17776/csj.345660
ISNAD DE FARIAS, Robson Fernandes , KAYA, Savaş . "Lattice Energies for Groups 1 and 2 Halides from Absolute Hardness". Cumhuriyet Science Journal 39 / 1 (March 2018): 192-195. https://doi.org/10.17776/csj.345660