Year 2018, Volume 39, Issue 1, Pages 181 - 191 2018-03-16

Removal of Cationic Dye in Aquatic Medium by Using a New Composite Material
Yeni Bir Kompozit Malzeme Kullanılarak Sulu Ortamdaki Katyonik Boya Giderimi

Zeynep Mine HASDEMİR [1] , Selçuk ŞİMŞEK [2]

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In this study, a new composite material containing polyacrylamide (PAA) and diatomite (D) was developed and characterized for effective removal of Methylene Blue (MB) dye in aquatic medium. The obtained new composite material, polyacrylamide-diatomite (PAA-D) was characterized by point zero charge (PZC), FTIR analysis. The adsorption properties of new composite material were investigated comprehensively and experimental variables were optimized such as concentration, pH, temperature, time and ionic strength. Experimental data were evaluated by using theoretical adsorption models. The maximum adsorption capacity of material was calculated as 0.019 mol kg−1 by considering Langmuir equation. The constants calculated from Freundlich and DR model were found as 0.075 and 0.034, respectively. Adsorption kinetic was also explained with pseudo second order and intra particular diffusion models. Experimental studies were showed that adsorption was endothermic and occurred spontaneously. New developed material can be used as potential adsorbent in order to removal of methylene blue from various medium such as wastewater.

Bu çalışmada, Poliakrilamid (PAA) ve diatomit (D) içeren yeni bir kompozit materyal sentezlendi ve bir katyonik boya olan metilen mavisinin (MB) sulu ortamdaki gideriminde kullanıldı. Elde edilen yeni kompozit, pliakrilamid-diatomit (PAA-D) sıfır yük noktası (SYN), FTIR analizleriyle karakterize edildi. Yeni kompozit materyalin adsorpsiyon özellikleri kapsamlı olarak ve deneysel değişkenler derişim, pH, sıcaklık, zaman ve iyonik şiddet gibi optimize edilerek araştırılmıştır. Deneysel veriler teorik adsorpsiyon modelleri kullanılarak hesaplandı. Kompozit materyalin adsorpsiyon kapasitesi Langmiur eşitliğinden 0.019 mol kg−1 olarak hesaplandı. Freundlich ve DR modellerinden hesaplanan sabitler 0.075 ve 0.034 olarak bulundu. Adsorpsiyon kinetiği yalanci ikinci derece kinetik ve parçacık içi difüzyon modelleriyle de açıklandı. Deneysel çalışmalar adsorpsiyonun endotermik olduğunu ve kendiliğinden meydana geldiğini gösterdi. Yeni geliştirilen materyal çeşitli ortamlardan atık sular gibi, metilen mavisi katyonik boyasını gidermek için potansiyel bir adsorban olarak kullanılabilir.

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Primary Language en
Subjects Basic Sciences
Journal Section Natural Sciences
Authors

Author: Zeynep Mine HASDEMİR (Primary Author)
Institution: CUMHURİYET ÜNİVERSİTESİ
Country: Turkey


Author: Selçuk ŞİMŞEK
Institution: CUMHURİYET ÜNİVERSİTESİ
Country: Turkey


Bibtex @research article { csj356915, journal = {Cumhuriyet Science Journal}, issn = {2587-2680}, eissn = {2587-246X}, address = {Cumhuriyet University}, year = {2018}, volume = {39}, pages = {181 - 191}, doi = {10.17776/csj.356915}, title = {Removal of Cationic Dye in Aquatic Medium by Using a New Composite Material}, key = {cite}, author = {HASDEMİR, Zeynep Mine and ŞİMŞEK, Selçuk} }
APA HASDEMİR, Z , ŞİMŞEK, S . (2018). Removal of Cationic Dye in Aquatic Medium by Using a New Composite Material. Cumhuriyet Science Journal, 39 (1), 181-191. DOI: 10.17776/csj.356915
MLA HASDEMİR, Z , ŞİMŞEK, S . "Removal of Cationic Dye in Aquatic Medium by Using a New Composite Material". Cumhuriyet Science Journal 39 (2018): 181-191 <http://dergipark.org.tr/csj/issue/36110/356915>
Chicago HASDEMİR, Z , ŞİMŞEK, S . "Removal of Cationic Dye in Aquatic Medium by Using a New Composite Material". Cumhuriyet Science Journal 39 (2018): 181-191
RIS TY - JOUR T1 - Removal of Cationic Dye in Aquatic Medium by Using a New Composite Material AU - Zeynep Mine HASDEMİR , Selçuk ŞİMŞEK Y1 - 2018 PY - 2018 N1 - doi: 10.17776/csj.356915 DO - 10.17776/csj.356915 T2 - Cumhuriyet Science Journal JF - Journal JO - JOR SP - 181 EP - 191 VL - 39 IS - 1 SN - 2587-2680-2587-246X M3 - doi: 10.17776/csj.356915 UR - https://doi.org/10.17776/csj.356915 Y2 - 2018 ER -
EndNote %0 Cumhuriyet Science Journal Removal of Cationic Dye in Aquatic Medium by Using a New Composite Material %A Zeynep Mine HASDEMİR , Selçuk ŞİMŞEK %T Removal of Cationic Dye in Aquatic Medium by Using a New Composite Material %D 2018 %J Cumhuriyet Science Journal %P 2587-2680-2587-246X %V 39 %N 1 %R doi: 10.17776/csj.356915 %U 10.17776/csj.356915
ISNAD HASDEMİR, Zeynep Mine , ŞİMŞEK, Selçuk . "Removal of Cationic Dye in Aquatic Medium by Using a New Composite Material". Cumhuriyet Science Journal 39 / 1 (March 2018): 181-191. https://doi.org/10.17776/csj.356915