TY  - JOUR
T1  - Synthesis and crystal structure of new [Pyridine-4-boronic acid methyl ester and Nickel(II) dithiooxalate] compound
TT  - Yeni [Piridin-4-boronik asit metil ester ve Nikel(II) ditiooksalat] bileşiğinin sentezi ve kristal yapısı
AU  - Kara Subasat, Hülya
AU  - Güngör, Elif
PY  - 2022
DA  - July
DO  - 10.25092/baunfbed.1070259
JF  - Balıkesir Üniversitesi Fen Bilimleri Enstitüsü Dergisi
JO  - BAUN Fen. Bil. Enst. Dergisi
PB  - Balıkesir University
WT  - DergiPark
SN  - 1301-7985
SP  - 750
EP  - 756
VL  - 24
IS  - 2
LA  - en
AB  - In this study, a new compound [HNC5H4B(OH)(OCH3)-4]2[Ni(S2C2O2)2], [Pyridine-4-boronic acid methyl ester and Nickel(II) dithiooxalate] was synthesized and its crystal structure was determined by the single-crystal X-ray diffraction method.  The compound crystallized in the monoclinic crystal system in the P21/n space group.  The NiII ion is four-coordinated and has a slightly distorted square-plane geometry.  There is NH⋯O, OH⋯O and CH⋯O hydrogen bond interactions in the crystal structure. These interactions form a 3-dimension network stacked along the c axis in the ab plane.
KW  - Crystal structure
KW  - 4-pyridine boronic acid
KW  - hydrogen bond interactions
N2  - Bu çalışmada yeni bir bileşik [HNC5H4B(OH)(OCH3)-4]2[Ni(S2C2O2)2], [Piridin-4-boronik asit metil ester ve Nikel(II) ditiooksalat] sentezlendi ve onun kristal yapısı tek kristal X-ışını difraktometresi metodu ile belirlendi.  Bileşik P21/n uzay grubunda monoklinik kristal sisteminde kristallendi.  NiII iyonu dört koordinasyonlu ve hafifçe bozulmuş kare düzlem geometriye sahiptir.  Kristal yapıda, NH⋯O, OH⋯O ve CH⋯O hidrojen bağ etkileşimleri vardır.  Bu etkileşimler ab düzleminde c ekseni boyunca paketlenir ve 3 boyutlu bir ağ oluşturur.
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UR  - https://doi.org/10.25092/baunfbed.1070259
L1  - https://dergipark.org.tr/en/download/article-file/2240959
ER  -