TY  - JOUR
T1  - H3PMo12O40@MOF as a New Catalytic System for Cycloxexanone Oxidation to Adipic Acid
AU  - Mazarı, Tassadit
AU  - Amıtouche, Dahbia
AU  - Mouannı, Sihem
AU  - Dermeche, Leila
AU  - Roch-marchal, Catherine
AU  - Rabıa, Cherifa
PY  - 2022
DA  - December
DO  - 10.55549/epstem.1222678
JF  - The Eurasia Proceedings of Science Technology Engineering and Mathematics
JO  - EPSTEM
PB  - ISRES Publishing
WT  - DergiPark
SN  - 2602-3199
SP  - 112
EP  - 119
VL  - 20
LA  - en
AB  - Keggin-type phosphomolibdic acid (H3PMo12O40, PMo12) encapsulated in the mesocages of chromium-based terephthalate metal–organic framework (MIL-101), was established to be an active and new green catalyst for the adipic acid (AA) synthesis via cyclohexanone (-One) oxidation in free solvent conditions and hydrogen peroxide as green oxidant. In this paper, we wish to report the synthesis of MIL-101 with different high loadings of the PMo12 nanocrystals incorporated within the large pores of MIL-101. Two and five POMs per large cavity can be incorporated into the matrix of MIL-101 respectively, xH3PMo12@ MIL101 with x=0, 2 and 5, they were characterized by several physic-chemical technics, then investigated in the reaction oxidation with 30 mmol –One at 90 ° C for 20h. A sequenced addition of 0.5ml of H2O2 (30%) was made every 30 min. The catalysts have shown good activity and the purity of AA was invistigeted by 1H and 13C NMR.
KW  - Heteropolysalts
KW  - Metal–organic framework
KW  - Catalytic oxidation
KW  - Hydrogen peroxide
KW  - Adipic acid
CR  - Tassadit, M., Mouanni, S., Rabia, C., Amitouche, D., Dermeche,L., & Roch Marchal, C.(2022). H3PMo12O40@MOF as a new catalytic system for cycloxexanone oxidation to adipic acid. The Eurasia Proceedings of Science, Technology, Engineering & Mathematics, 20, 112-119.
UR  - https://doi.org/10.55549/epstem.1222678
L1  - https://dergipark.org.tr/en/download/article-file/2846402
ER  -