TY  - JOUR
T1  - Photoproduction of High Molecular Weight Poly (N-methylpyrrole) under Green Conditions
AU  - Kaya, Kerem
PY  - 2023
DA  - May
Y2  - 2023
DO  - 10.18596/jotcsa.1232989
JF  - Journal of the Turkish Chemical Society Section A: Chemistry
JO  - JOTCSA
PB  - Turkish Chemical Society
WT  - DergiPark
SN  - 2149-0120
SP  - 443
EP  - 452
VL  - 10
IS  - 2
LA  - en
AB  - A novel and green photochemical polymerization method of N-methylpyrole is reported. Spectral and chromatographic characterizations revealed the formation of high molecular weight polymer (1436 kg/mol) having light absorption in the near-infrared region (~750 nm), high fluorescence emission in the visible region, high conductivity (0.062 S/cm) and good thermal stability. Powder X-ray diffractogram identified a totally amorphous polymer. According to cyclic voltammetry studies the polymer formed (PMPy) possess a relatively low electronic band gap (1.39 eV) which is very important for the (opto)electronic device applications of such materials.
KW  - conductive polymers
KW  - polypyrrole derivatives
KW  - sustainable/green chemistry
KW  - photochemical polymerization
KW  - step-growth polymerization.
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UR  - https://doi.org/10.18596/jotcsa.1232989
L1  - https://dergipark.org.tr/en/download/article-file/2886389
ER  -