TY  - JOUR
T1  - Enhancing paint performance through the incorporation of thermoplastic acrylates with varying proportions of a sustainable, bio-based gum rosin acrylic monomer (GRA)
TT  - Sürdürülebilir, biyo-esaslı sakız reçinesi akrilik monomerinin (GRA) değişen oranlarda termoplastik akrilatlarla birleştirilmesi yoluyla boya performansının arttırılması
AU  - Dızman, Cemil
AU  - Cerrahoğlu Kaçakgil, Elif
AU  - Turanlı, Aleyna
PY  - 2025
DA  - April
Y2  - 2025
DO  - 10.7212/karaelmasfen.1613080
JF  - Karaelmas Fen ve Mühendislik Dergisi
PB  - Zonguldak Bulent Ecevit University
WT  - DergiPark
SN  - 2146-7277
SP  - 211
EP  - 217
VL  - 15
IS  - 1
LA  - en
AB  - In this study, a bio-based acrylic monomer (GRA) was synthesized through the acrylation of bio-based gum rosin. This monomer was subsequently employed in the synthesis of thermoplastic 1K (one component) acrylate polymers. These polymers are applicable in varnish and paint formulations, offering superior coating features, including increased gloss, enhanced adhesion, improved visual appeal, and robust impact resistance. The synthesized GRA served as a bio-based monomer in thermoplastic acrylate compositions at ratios of 2.5%, 5.0%, and 10.0%. The synthesized monomer and its resultant polymers were studied using gel permeation chromatography (GPC) and Attenuated Total Reflection-Fourier Transform Infrared Spectroscopy (ATR-FTIR). The thermal characteristics of the polymers were analyzed using a differential scanning calorimeter (DSC). The coating properties, including adhesion, gloss, hardness, drying times, and impact resistance, were evaluated and studied. The results indicate that increasing the quantity of gum rosin monomers in the polymers reduced the glass transition temperatures from 30.18 °C to 24.12 °C, which enhanced impact resistance and improved adhesion to metal surfaces. The adhesion is nearly doubled on metallic surfaces. Paints formulated with increased amounts of bio-based gum rosin exhibit exceptionally high gloss values, rapid drying times, and superior aesthetics compared to standard formulations. In comparison to the binders employed in currently available paints, the polymer containing gum rosin acrylate monomers can be utilized to manufacture paints and varnishes with enhanced coating capabilities. By the way, the paint formulations can be prepared without any addition of plasticizer.
KW  - 1K acrylic
KW  - gum rosin
KW  - paints
KW  - thermoplastic acrylates.
N2  - Bu çalışmada, biyo esaslı sakız reçinesinin akrilasyonu yoluyla biyo esaslı bir akrilik monomer (GRA) sentezlendi. Bu monomer daha sonra termoplastik 1K (tek bileşenli) akrilat polimerlerinin sentezinde kullanıldı. Bu polimerler vernik ve boya formülasyonlarında uygulanabilir; daha fazla parlaklık, daha iyi yapışma, daha iyi görsel çekicilik ve sağlam darbe direnci gibi üstün kaplama özellikleri sunar. Sentezlenen GRA, termoplastik akrilat bileşimlerinde %2.5, %5.0 ve %10.0 oranlarında biyo esaslı monomer olarak eklendi. Sentezlenen monomer ve bunun sonucunda elde edilen polimerler, jel geçirgenlik kromatografisi (GPC) ve Yansıma-Fourier Dönüşüm Kızılötesi (ATR-FTIR) spektroskopisi kullanılarak incelenmiştir. Polimerlerin termal özellikleri, diferansiyel taramalı kalorimetre (DSC) kullanılarak analiz edildi. Yapışma, parlaklık, sertlik, kuruma süreleri ve darbe direnci dahil olmak üzere kaplama özellikleri değerlendirildi ve incelendi. Sonuçlar, polimerlerdeki sakız reçinesi monomerlerinin miktarının arttırılmasının, cam geçiş sıcaklıklarını 30.18 °C’den 24.12 °C’ye düşürdüğünü, bunun da darbe direncini artırdığını ve metal yüzeylere yapışmayı iyileştirdiğini göstermektedir. Metal yüzeylerde yapışma neredeyse iki katına çıkar. Artan miktarlarda biyo esaslı sakız reçinesi ile formüle edilen boyalar, standart formülasyonlarla karşılaştırıldığında olağanüstü yüksek parlaklık değerleri, hızlı kuruma süreleri ve üstün estetik sergiledi. Halihazırda mevcut boyalarda kullanılan bağlayıcılarla karşılaştırıldığında, sakız reçinesi akrilat monomerleri içeren polimer, geliştirilmiş kaplama kapasitesine sahip boyalar ve vernikler üretmek için kullanılabilir. Bu arada boya formülasyonları herhangi bir plastikleştirici ilave edilmeden hazırlanabilmektedir.
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UR  - https://doi.org/10.7212/karaelmasfen.1613080
L1  - https://dergipark.org.tr/en/download/article-file/4491633
ER  -