TY  - JOUR
T1  - Improvement of Mechanical and Tribological Properties of PC/ABS Composite Parts Manufactured with 3D FDM Technology by Cryogenic Treatment
TT  - 3D FDM teknolojisi ile üretilen PC/ABS kompozit parçaların kriyojenik işlemle mekanik ve tribolojik özelliklerinin iyileştirilmesi
AU  - Arslan, Yusuf
AU  - Altınsoy, Alirıza
PY  - 2025
DA  - October
Y2  - 2025
DO  - 10.29130/dubited.1733839
JF  - Duzce University Journal of Science and Technology
JO  - DÜBİTED
PB  - Duzce University
WT  - DergiPark
SN  - 2148-2446
SP  - 1783
EP  - 1798
VL  - 13
IS  - 4
LA  - en
AB  - In this article, the effects of cryogenic treatment on mechanical and tribological properties of products made of PC/ABS composite material used in 3D FDM printing technology were investigated. Three different load test samples were produced for hardness, tensile strength, impact strength and friction coefficient in accordance with the relevant st andards. The production parameters of all the experimental samples produced at room temperature were kept constant and the subsequent cryogenic treatment was focused on. These samples were subjected to cryogenic treatment with liquid nitrogen at different holding times and -180℃. In order to see the effects of cryogenic treatment, mechanical property tests were carried out and also images were taken from the surfaces that were broken in the tensile test with Scanning Electron Microscope (SEM) and the microstructure was examined. Within the limits of this study, the hardness values of all products produced from cryogenically treated PC/ABS composite materials increased compared to those that were not treated. The highest hardness increase was in the 24 CT coded PC/ABS samples with an increase of 22.37%. An increase was observed in the tensile strength values of all samples compared to the untreated samples. However, the highest increase in tensile strength values was in the 18 CT coded samples with an increase of 8.35%. A decrease in impact strength was observed in all samples. However, samples with code 18 CT showed the highest decrease with a rate of 33.38%. In the wear tests performed under three different loads (5 N, 10 N and 20 N), an improvement was observed in the friction coefficients of all samples compared to untreated samples. When the microstructure (SEM) images of the material were compared, it was seen that there were differences in the matrix structure. The increase in the hardness values as a result of the process was explained as the molecular chain arrangement in the microstructure of the samples becoming more regular and turning into a stable structure. It was evaluated that these structural changes had a positive effect on the mechanical properties of PC/ABS composite materials. This research constitutes a pioneering study reporting the tribological and mechanical performance of parts manufactured from PC/ABS composites, a preferred material in 3D FDM printing technology, under cryogenic conditions.
KW  - 3D FDM
KW  - PC/ABS
KW  - Mechanical Properties
KW  - Friction Coefficient
KW  - Cryogenic Treatment
N2  - Bu makalede, 3D FDM baskı teknolojisinde kullanılan PC/ABS kompozit malzemeden üretilen ürünlerin mekanik ve tribolojik özellikleri üzerinde kriyojenik işlemin etkileri araştırılmıştır. İlgili standartlara uygun olarak sertlik, çekme dayanımı, darbe dayanımı ve sürtünme katsayısı için üç farklı yük test numunesi üretilmiştir. Oda sıcaklığında üretilen deney numunelerinin hepsinin üretim parametreleri sabit tutularak daha sonra yapılan kriyojenik işleme odaklanılmıştır. Bu numunelere farklı bekletme zamanlarında ve -180℃’de sıvı azot ile kriyojenik işlem uygulanmıştır. Kriyojenik işlemin etkilerini görmek için mekanik özellik deneyleri yapılmış ayrıca Tarama Elektron Mikroskobu (SEM) ile çekme deneyinde kopan yüzeylerden görüntüler alınıp mikroyapı incelenmiştir. Bu çalışmanın sınırları dahilinde kriyojenik işlem PC/ABS kompozit malzemelerden üretilen ürünlerin hepsinin işlem görmemiş olanlara göre sertlik değerleri artmıştır. En yüksek sertlik artışı % 22,37 artarak 24 CT kodlu PC/ABS numunelerde olmuştur. Tüm numunelerin çekme dayanımı değerlerinde işlem görmemiş numunelere göre artış görülmüştür. Ancak çekme dayanımı değerlerinde en yüksek artış %8,35 ile 18 CT kodlu numunelerde olmuştur. Tüm numunelerde darbe dayanımında azalma görülmüştür. Ancak 18 CT kodlu numuneler %33,38 oranıyla en yüksek düşüşü göstermiştir. Üç farklı yük altında (5 N, 10 N ve 20 N) yapılan aşınma testlerinde tüm numunelerin sürtünme katsayılarında işlem görmemiş numunelere göre iyileşme görülmüştür. Malzemenin mikro yapı (SEM) görüntüleri karşılaştırıldığında matris yapısında farklılıklar olduğu görülmüştür. İşlem sonucu sertlik değerlerinde meydana gelen artış, numunelerin mikro yapısındaki moleküler zincir dizilimin daha düzenli hale gelerek kararlı bir yapıya dönüşmesi olarak açıklanmıştır. Bu yapısal değişimlerin PC/ABS kompozit malzemelerin mekanik özellikleri üzerinde olumlu etki yarattığı değerlendirilmiştir.
CR  - Altinsoy, A., & Arslan, Y. (2024). Investigation of the effects of deep cryogenic treatment on the structural and mechanic properties of polyoxymethylene copolymer (POM-C) materials. Proceedings of the Institution of Mechanical Engineers, Part E: Journal of Process Mechanical Engineering, 238(6), 2623-2632. https://doi.org/10.1177/09544089221139647
CR  - Amza, C. G., Zapciu, A., Baciu, F., & Radu, C. (2023). Effect of UV-C radiation on 3D printed ABS-PC polymers. Polymers, 15(8), Article 1966. https://doi.org/10.3390/polym15081966
CR  - Arslan, Y. (2020a). The effects of cryogenic process on the AISI M2 punch materials and on the hole edge geometry of the DIN EN 10111‐98 sheet metal control arm parts. Advances in Materials Science and Engineering, 2020(1), Article 9236783. https://doi.org/10.1155/2020/9236783
CR  - Arslan, Y. (2020b). The effect of cryogenic treatment on the punch wear and the hole edge geometry. Transactions of FAMENA, 44(2), 45-57. https://doi.org/10.21278/TOF.44205
CR  - Arslan, Y., Seker, U., Ozcatalbas, Y., & Ozdemir, A. (2016). An investigation of the hole diameter and circularity on the stainless steel sheet perforated via by deep cryogenically treated cold work tool steel punches. Journal of Engineering Research and Applied Science, 5(1), 378-390.
CR  - Bakar, A. A. B. A., Zainuddin, M. Z. B., Adam, A. N. B., Noor, I. S. B. M., Tamchek, N. B., Alauddin, M. S. B., & Ghazali, M. I. B. M. (2022). The study of mechanical properties of poly (lactic) acid PLA-based 3D printed filament under temperature and environmental conditions. Materials Today: Proceedings, 67, 652-658. https://doi.org/10.1016/j.matpr.2022.06.198
CR  - Bartolomé, E., Bozzo, B., Sevilla, P., Martínez-Pasarell, O., Puig, T., & Granados, X. (2017). ABS 3D printed solutions for cryogenic applications. Cryogenics, 82, 30-37. https://doi.org/10.1016/j.cryogenics.2017.01.005
CR  - Bermudo Gamboa, C., Martín-Béjar, S., Bañón García, F., & Sevilla Hurtado, L. (2024). Enhancing Fatigue Resistance of Polylactic Acid through Natural Reinforcement in Material Extrusion. Polymers, 16(17), Article 2422. https://doi.org/10.3390/polym16172422
CR  - Bourell, D., Kruth, J. P., Leu, M., Levy, G., Rosen, D., Beese, A. M., & Clare, A. (2017). Materials for additive manufacturing. CIRP Annals, 66(2), 659-681. https://doi.org/10.1016/j.cirp.2017.05.009
CR  - Chopra, S., Deshmukh, K. A., Somvanshi, M. V., Patil, N. V., Rakhe, S. R., Sontakke, R. V., ... & Carlone, P. (2021). Structural elucidation and mechanical behavior of cryogenically treated ultra-high molecular weight poly-ethylene (UHMWPE). Transactions of the Indian Institute of Metals, 74(2), 255-265. https://doi.org/10.1007/s12666-020-02140-2
CR  - Cruz, P., Shoemake, E. D., Adam, P., & Leachman, J. (2015, November). Tensile strengths of polyamide based 3D printed polymers in liquid nitrogen. In IOP Conference Series: Materials Science and Engineering (Vol. 102, No. 1, p. 012020). IOP Publishing. doi:10.1088/1757-899X/102/1/012020
CR  - Çiçek, A., Kıvak, T., Uygur, I., Ekici, E., & Turgut, Y. (2012). Performance of cryogenically treated M35 HSS drills in drilling of austenitic stainless steels. The International Journal of Advanced Manufacturing Technology, 60(1), 65-73. https://doi.org/10.1007/s00170-011-3616-8
CR  - Das, D., Dutta, A. K., & Ray, K. K. (2009). Influence of varied cryotreatment on the wear behavior of AISI D2 steel. Wear, 266(1-2), 297-309. https://doi.org/10.1016/j.wear.2008.07.001
CR  - Dey, A., & Yodo, N. (2019). A systematic survey of FDM process parameter optimization and their influence on part characteristics. Journal of Manufacturing and Materials Processing, 3(3), Article 64. https://doi.org/10.3390/jmmp3030064
CR  - Dizon, J. R. C., Espera Jr, A. H., Chen, Q., & Advincula, R. C. (2018). Mechanical characterization of 3D-printed polymers. Additive manufacturing, 20, 44-67. https://doi.org/10.1016/j.addma.2017.12.002
CR  - Engler, L. G., Crespo, J. S., Gately, N. M., Major, I., & Devine, D. M. (2022). Process optimization for the 3D printing of PLA and HNT composites with Arburg plastic freeforming. Journal of Composites Science, 6(10), Article 309. https://doi.org/10.3390/jcs6100309
CR  - Evlen, H., Özdemir, M. A., & Çalışkan, A. (2019). Doluluk oranlarının PLA ve PET malzemelerin mekanik özellikleri üzerine etkileri. Politeknik Dergisi, 22(4), 1031-1037. [in Turkish]. https://doi.org/10.2339/politeknik.426413
CR  - Garzon-Hernandez, S., Garcia-Gonzalez, D., Jérusalem, A., & Arias, A. (2020). Design of FDM 3D printed polymers: An experimental-modelling methodology for the prediction of mechanical properties. Materials & Design, 188, Article 108414. https://doi.org/10.1016/j.matdes.2019.108414
CR  - Gaweł, A., Kuciel, S., Liber-Kneć, A., & Mierzwiński, D. (2023). Examination of low-cyclic fatigue tests and poisson’s ratio depending on the different infill density of polylactide (PLA) produced by the fused deposition modeling method. Polymers, 15(7), Article 1651. https://doi.org/10.3390/polym15071651
CR  - Gebel, M. E., & Ermurat, M. (2021). Investigation of polymer matrix continuous fiber reinforced composite part manufacturability for composite additive manufacturing. Journal of the Faculty of Engineering and Architecture of Gazi University, 36(1), 57-67. [in Turkish]. https://doi.org/10.17341/gazimmfd.606618
CR  - Gupta, A., Kumar, N., Sachdeva, A., Sharma, G. K., Kumar, M., & Verma, R. (2025). Effect of cryogenic treatment on the mechanical properties of 3D-printed polylactic acid part. Cryogenics, 145, Article 104000. https://doi.org/10.1016/j.cryogenics.2024.104000
CR  - Horasan, M., & Sarac, I. (2024). The fatigue responses of 3D‐printed polylactic acid (PLA) parts with varying raster angles and printing speeds. Fatigue & Fracture of Engineering Materials & Structures, 47(10), 3693-3706. https://doi.org/10.1111/ffe.14406
CR  - Jayswal, A., & Adanur, S. (2022). Effect of heat treatment on crystallinity and mechanical properties of flexible structures 3D printed with fused deposition modeling. Journal of Industrial Textiles, 51(2S), 2616S-2641S. https://doi.org/10.1177/15280837211064937
CR  - Kannan, S., & Ramamoorthy, M. (2020). Mechanical characterization and experimental modal analysis of 3D printed ABS, PC and PC-ABS materials. Materials Research Express, 7(1), Article 015341. https://doi.org/10.1088/2053-1591/ab6a48
CR  - Karabıyık, Ö., & Apak, K. (2021). Eklemeli imalat yöntemiyle PLA malzemesinden üretilen ürünlerin mekanik özelliklerinin incelenmesi. Uluslararası Teknolojik Bilimler Dergisi, 13(2), 62-68. [in Turkish].
CR  - Karakoc, B., & Uzun, G. (2023). Ergiyik yığma modelleme yöntemi ile üretilen numunelerde örme yönteminin ve baskı yönünün mukavemete olan etkisi. Politeknik Dergisi, 27(4), 1233-1242. [in Turkish]. https://doi.org/10.2339/politeknik.1262855
CR  - Koçar, O., Anaç, N., Baysal, E., Parmaksız, F., & Akgül, İ. (2024). Investigation of mechanical properties and color changes of 3D-printed parts with different infill ratios and colors after aging. Materials, 17(23), Article 5908. https://doi.org/10.3390/ma17235908
CR  - Konta, A. A., García-Piña, M., & Serrano, D. R. (2017). Personalised 3D printed medicines: which techniques and polymers are more successful? Bioengineering, 4(4), Article 79. https://doi.org/10.3390/bioengineering4040079
CR  - Liu, Y., Dong, J., Tiersch, T. R., Wu, Q., & Monroe, W. T. (2022). An open hardware 3-D printed device for measuring tensile properties of thermoplastic filament polymers at cryogenic temperatures. Cryogenics, 121, Article 103409. https://doi.org/10.1016/j.cryogenics.2021.103409
CR  - Moghanizadeh, A., & Ashrafizadeh, F. (2021). Studying sacrificial ice structure, as soluble support layers, in 3D printing of polymers (FDM). Progress in Additive Manufacturing, 6(4), 757-763. https://doi.org/10.1007/s40964-021-00195-1
CR  - Ni, H., Zhuo, L., Gu, H., Lv, S., Zhu, Y., Shi, C., & Wang, X. (2018). Effect of cryogenic treatment on micro-structure and properties of different polymer materials. In MATEC Web of Conferences (Vol. 166, p. 01002). EDP Sciences. https://doi.org/10.1051/matecconf/201816601002
CR  - Pande, K. N., Peshwe, D. R., & Kumar, A. (2012). Effect of the cryogenic treatment on polyamide and optimization of its parameters for the enhancement of wear performance. Transactions of the Indian Institute of Metals, 65(3), 313-319. https://doi.org/10.1007/s12666-012-0135-8
CR  - Pandelidi, C., Bateman, S., Piegert, S., Hoehner, R., Kelbassa, I., & Brandt, M. (2021). The technology of continuous fibre-reinforced polymers: a review on extrusion additive manufacturing methods. The International Journal of Advanced Manufacturing Technology, 113(11), 3057-3077. https://doi.org/10.1007/s00170-021-06837-6
CR  - Podgornik, B., Leskovšek, V., & Vižintin, J. (2009). Influence of deep-cryogenic treatment on tribological properties of P/M high-speed steel. Materials and Manufacturing Processes, 24(7-8), 734-738. https://doi.org/10.1080/10426910902809339
CR  - Rouf, S., Raina, A., Haq, M. I. U., Naveed, N., Jeganmohan, S., & Kichloo, A. F. (2022). 3D printed parts and mechanical properties: Influencing parameters, sustainability aspects, global market scenario, challenges and applications. Advanced Industrial and Engineering Polymer Research, 5(3), 143-158. https://doi.org/10.1016/j.aiepr.2022.02.001
CR  - Salifu, S., Ogunbiyi, O., & Olubambi, P. A. (2022). Potentials and challenges of additive manufacturing techniques in the fabrication of polymer composites. The International Journal of Advanced Manufacturing Technology, 122(2), 577-600. https://doi.org/10.1007/s00170-022-09976-6
CR  - Saroia, J., Wang, Y., Wei, Q., Lei, M., Li, X., Guo, Y., & Zhang, K. (2020). A review on 3D printed matrix polymer composites: its potential and future challenges. The international journal of advanced manufacturing technology, 106(5), 1695-1721. https://doi.org/10.1007/s00170-019-04534-z
CR  - Shahrubudin, N., Lee, T. C., & Ramlan, R. J. P. M. (2019). An overview on 3D printing technology: Technological, materials, and applications. Procedia manufacturing, 35, 1286-1296. https://doi.org/10.1016/j.promfg.2019.06.089
CR  - Sözen, A., & Neşer, G. (2022). Eklemeli imalat yöntemiyle tekne inşaatında dolgu yoğunluğu ve örüntüsünün mukavemet üzerindeki bileşik etkisi. Gemi ve Deniz Teknolojisi, 221, 163-177. [in Turkish]. https://doi.org/10.54926/gdt.1117813
CR  - Stan, F., Stanciu, N. V., Sandu, I. L., Fetecau, C., & Serban, A. (2019). Effect of low and extreme-low temperature on mechanical properties of 3D printed polyethylene terephthalate glycol copolymer. The Romanian Journal of Technical Sciences. Applied Mechanics, 64(1), 21-41.
CR  - Valino, A. D., Dizon, J. R. C., Espera Jr, A. H., Chen, Q., Messman, J., & Advincula, R. C. (2019). Advances in 3D printing of thermoplastic polymer composites and nanocomposites. Progress in Polymer Science, 98, Article 101162. https://doi.org/10.1016/j.progpolymsci.2019.101162
CR  - Veer, P., Vettivel, S. C., Madan, J., & Pabla, B. S. (2023). Mechanical and tribological characterization of 3D printed-cryogenically treated thermoplastic polyurethane. Materials Today: Proceedings. https://doi.org/10.1016/j.matpr.2023.09.050
CR  - Wang, Q., Zheng, F., & Wang, T. (2016). Tribological properties of polymers PI, PTFE and PEEK at cryogenic temperature in vacuum. Cryogenics, 75, 19-25. https://doi.org/10.1016/j.cryogenics.2016.01.001
CR  - Weiss, K. P., Bagrets, N., Lange, C., Goldacker, W., & Wohlgemuth, J. (2015, November). Thermal and mechanical properties of selected 3D printed thermoplastics in the cryogenic temperature regime. In IOP Conference Series: Materials Science and Engineering (Vol. 102, No. 1, p. 012022). IOP Publishing. doi:10.1088/1757-899X/102/1/012022
CR  - Yap, P. V., Chan, M. Y., & Koay, S. C. (2021). Preliminary study on mechanical properties of 3D printed multi-materials ABS/PC parts: Effect of printing parameters. Journal of Physical Science, 32(2), 87-104. https://doi.org/10.21315/jps2021.32.2.7
CR  - Yap, Y. L., Toh, W., Koneru, R., Lin, K., Yeoh, K. M., Lim, C. M., Lee, J. S., Plemping, N. A., Lin, R., Ng, T. Y., Chan, K. I., Guang, H., Chan, W. Y. B., Teong, S. S., & Zheng, G. (2019). A non-destructive experimental-cum-numerical methodology for the characterization of 3D-printed materials—polycarbonate-acrylonitrile butadiene styrene (PC-ABS). Mechanics of Materials, 132, 121-133. https://doi.org/10.1016/j.mechmat.2019.03.005
CR  - Yılmaz, M., Yılmaz, N. F., Kılıç, A., & Mazı, H. (2024). Investigation of manufacturability of in-situ crosslinked polylactic acid (PLA) and peroxide composite in additive manufacturing. Journal of the Faculty of Engineering and Architecture of Gazi University, 39(2), 859-867. [in Turkish]. https://doi.org/10.17341/gazimmfd.1213974
CR  - Zerankeshi, M. M., Bakhshi, R., & Alizadeh, R. (2022). Polymer/metal composite 3D porous bone tissue engineering scaffolds fabricated by additive manufacturing techniques: A review. Bioprinting, 25, Article e00191. https://doi.org/10.1016/j.bprint.2022.e00191
UR  - https://doi.org/10.29130/dubited.1733839
L1  - https://dergipark.org.tr/en/download/article-file/5018871
ER  -