TY  - JOUR
TT  - Synthesis, spectroscopic and thermal characterization of isonicotinamide complexes of metal(II) p-dimethylaminobenzoates.
AU  - Aybirdi, Özgür
AU  - Necefoğlu, Hacali
PY  - 2016
DA  - August
Y2  - 2016
DO  - 10.16984/saufenbilder.26682
JF  - Sakarya University Journal of Science
JO  - SAUJS
PB  - Sakarya University
WT  - DergiPark
SN  - 2147-835X
SP  - 167
EP  - 175
VL  - 20
IS  - 2
KW  - termal parçalanma
KW  - p-dimetilaminobenzoat
KW  - izonikotinamid
KW  - geçiş metal bileşikleri
N2  - In this study, the 6 new mixed complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with p-dimethylaminobenzoic acid (DMABA), and isonicotinamide (INA) have been synthesized: [Mn(DMAB)2(İNA)(H2O)2] 1, [Co(DMAB)2(İNA)(H2O)2] 2, [Ni(DMAB)2(İNA)(H2O)2] 3, Cu2(DMAB)4(İNA)2] 4, [Zn(DMAB)2(İNA)(H2O)2] 5, [Cd(DMAB)2(İNA)(H2O)2] 6. The complexes were characterized by elemental analysis, direct injection probe mass, IR, 1H-NMR, 13C-NMR, UV-vis, ESR spectroscopy, thermogravimetry measurements. Concequently, it has been determined that Complex 4 have square-pyramidal and the others complexes have octahedral geometries. The decomposition of each complex starts with dehydration and follows by decomposition organic part, respectively.The thermal dehydration of complexes takes place in steps from one to two. The decomposition mechanism and termal stability of the investigated complexes are interpreted in terms of their structures.The final decomposition products are found to be the respective metal oxides.
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UR  - https://doi.org/10.16984/saufenbilder.26682
L1  - https://dergipark.org.tr/en/download/article-file/227614
ER  -