TY  - JOUR
T1  - Synthesis and Characterization Studies of MIL-101
TT  - Yeni Nesil MIL-101 Malzemesi Sentez ve Karakterizasyon Çalışmaları
AU  - Kaya Ekinci, Emine
PY  - 2017
DA  - December
DO  - 10.29109/http-gujsc-gazi-edu-tr.306699
JF  - Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji
JO  - GUJS Part C
PB  - Gazi University
WT  - DergiPark
SN  - 2147-9526
SP  - 178
EP  - 185
VL  - 5
IS  - 4
LA  - en
AB  - MIL-101is a kind of Metal Organic Frameworks (MOFs), which have attracted muchattention in the past decade due to its promising application in chemicalindustries. MIL-101 is also known as “Porous Chromium Terephthalate”. It hasvery high surface area and pore volume. MIL-101 exhibits exceptional stabilityagainst moisture and other chemicals and is composed of coordinatelyunsaturated Cr- sites with high concentration available for catalysis andadsorption. MIL-101 was synthesized by hydrothermal method and characterized byXRD, nitrogen adsorption and desorption analyses and SEM. XRD patterns show thepresence of MIL-101’s crystal structure with high surface area (~2400 m2/g).Nitrogen adsorption-desorption analyzes showed that the material exhibitedmesoporous material behavior.
KW  - MIL-101
KW  - Metal organic frameworks
KW  - Porous materials
N2  - MetalOrganik Yapılar (MOFs) sınıfına giren MIL-101, son yıllarda yapılançalışmalarda, gelecek vaat eden uygulamalarıyla oldukça dikkat çekmektedir. Nemve diğer kimyasallara karşı olağanüstü bir kararlılık sergileyen MIL-101, eşsizkristal yapı kombini ile doyamamış krom sitelerinden oluşması gibi üstünözellikleri ile ayırma süreçleri ve kataliz uygulamalarında kullanımı önemkazanmıştır. Yapılan çalışmada MIL-101 hidrotermal yöntemle sentezlenmiş vekarakterizasyonu XRD, azot adsorpsiyon-desorpsiyon analizleri ve SEM ileyapılmıştır. XRD desenleri MIL-101 karakteristik piklerini taşıdığı göstermişve yüksek yüzey alanlı (~2400 m2/g) malzeme elde edilmiştir. Azotadsorpsiyon-desorpsiyon analizleri sonucunda malzemenin mezogözenekli malzemedavranışı gösterdiği görülmüştür.
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UR  - https://doi.org/10.29109/http-gujsc-gazi-edu-tr.306699
L1  - https://dergipark.org.tr/en/download/article-file/376717
ER  -