@article{article_316870, title={Investigation of Single Crystal and Polycrystalline Forms of Copper(II) and Vanadium(II) Doped Beta Potassium Sulfate Complex by Electron Spin Resonance Technique}, journal={International Journal of Pure and Applied Sciences}, volume={3}, pages={33–39}, year={2017}, DOI={10.29132/ijpas.316870}, url={https://izlik.org/JA49WT47RK}, author={Kurt, Murat and Çelik, Fahri}, keywords={ESR analysis,single crystal,Cu2+ and V2+ doping,single crystal}, abstract={<p class="MsoNormal" style="margin-bottom:.0001pt;text-align:justify;text-indent:21.3pt;line-height:normal;"> <span style="font-size:10pt;font-family:’Times New Roman’, serif;">In this study, single crystal and powder of Cu <sup>2+ </sup> and V <sup>2+ </sup>
transition metal ions doped potassium sulphate complex were evaluated by electron
spin resonance (ESR) technique. For </span> <span lang="en-us" style="font-size:10pt;font-family:’Times New Roman’, serif;" xml:lang="en-us">Cu <sup>2+ </sup> </span> <span style="font-size:10pt;font-family:’Times New Roman’, serif;">doped complex were determined four paramagnetic centers and g and A values
were found for each of the paramagnetic centers. g and A values obtained for
the single crystal were found to be in agreement with the g and A values
obtained for the powder form of this complex. The angles between the
experimental axis set and the actual axes were determined. Molecular binding
coefficients for each paramagnetic centers and powder form calculated. The
values obtained from the spectras, in the regions where the </span> <span lang="en-us" style="font-size:10pt;font-family:’Times New Roman’, serif;" xml:lang="en-us">Cu <sup>2+ </sup> </span> <span style="font-size:10pt;font-family:’Times New Roman’, serif;">ions are located, it is concluded that the neighbors of
the paramagnetic centers are the rhombic symmetry (low symmetry). Similar
measurements were made for the powder form of the V <sup>2+ </sup> transition
metal ion doped potassium sulphate complex. According to the datas obtained
from the powder spectrum,itis concluded that the neighbors in the region where
the ion is placed are compatible with the axial symmetry. Also g and A values were
obtained for this structure. </span> </p> <p> </p> <p> </p>}, number={2}