@article{article_341530, title={The catalytic activity of Palladium(II) complexes containing PN ligands in the Heck and Suzuki C-C coupling reactions}, journal={Journal of the Turkish Chemical Society Section A: Chemistry}, volume={5}, pages={133–148}, year={2017}, DOI={10.18596/jotcsa.341530}, author={Yılmaz, Mustafa Kemal and Keleş, Mustafa}, keywords={iminophosphine,palladium complexes,Heck coupling,suzuki coupling}, abstract={<span lang="en-us" style="font-size:10pt;font-family:Verdana, sans-serif;" xml:lang="en-us">A range of iminophosphine (PN) ligands ((C <sub>6 </sub>H <sub>5 </sub>) <sub>2 </sub>P-C <sub>6 </sub>H <sub>4 </sub>-CH=NR
(R=-C <sub>6 </sub>H <sub>3 </sub>(2-CH <sub>3 </sub>)(4-OH) ( <b>1a </b>), -CH <sub>2 </sub>CH <sub>2 </sub>C <sub>6 </sub>H <sub>4 </sub>(4-OH)
( <b>1b </b>) and -C <sub>5 </sub>H <sub>3 </sub>N(2-CH <sub>3 </sub>)
( <b>1c </b>))  have been synthesized starting from 4-amino-3-methylphenol,
4-(2-aminoethyl)phenol and 2-amino-3-methylpyridine with 2-(diphenylphosphino)benzaldehyde.
The PN ligands were reacted with Pd(cod)Cl <sub>2 </sub> to give corresponding new
PdLCl <sub>2 </sub>metal complexes, ( <b>2a </b>, <b>2b </b>and <b> 2c </b>). </span> <span lang="en-us" style="font-size:10pt;font-family:Verdana, sans-serif;" xml:lang="en-us">The Heck and Suzuki C-C coupling reactions were examined with
catalysts <b>2a </b>- <b>2c </b> and showed high conversions under the determined conditions with
para substituted arylhalides </span>}, number={1}, publisher={Turkish Chemical Society}