TY  - JOUR
TT  - The Investigation of - Irradiated Single Crystal of  4-Methyl Benzylamine Glyoxime by EPR and  Simulation Technique
AU  - Akpınar, Ülkü
AU  - Yüksel, Hüseyin
AU  - Yıldırım, Bilge
AU  - Birey, Mehmet
PY  - 2005
DA  - December
JF  - Politeknik Dergisi
PB  - Gazi University
WT  - DergiPark
SN  - 2147-9429
SP  - 397
EP  - 401
VL  - 8
IS  - 4
KW  - EPR
KW  - Spektroskopik Yarılma Faktörü
KW  - g
KW  - Aşırı İnce Yapı Etkileşme Sabiti
KW  - 
KW  - Spin Yoğunluğu
KW  - .
N2  - The electron paramagnetic resonance of   irradiated single crystal of 4-Methyl Benzylamine Glyoxime(4-MBG) has been observed and analysed for different orientations of the crystals in a magnetic field. 4-MBG single crystal has been investigated at the temperatures between 100 and 400 K. The spectra were found to be temperature independent. Principal values of the g and the hyperfine splitting tensors and their direction cosines are given in the Table 1. The average values of g-factor and the hyperfine splittings were found to be g = 1,999, aN = 14G , aH (NH ) = 13,5G and aCH 7,5G 2 = respectively. The measurements indicate that N(NH) = 0,5 and H(NH) = 0,5 of the unpaired electron are localized on nitrogen and hydrogen respectively. The g-values and the hyperfine coupling constants of the unpaired electron with the protons and nitrogen were determined by EPR and simulation technique.
UR  - https://dergipark.org.tr/en/pub/politeknik/article/367051
L1  - https://dergipark.org.tr/en/download/article-file/384497
ER  -