TY  - JOUR
T1  - Photoinduced Synthesis of Block Copolymers by Combination of Atom Transfer Radical Polymerization and Photoinduced Radical Oxidation/Addition/Deactivation
AU  - Ciftci, Mustafa
PY  - 2018
DA  - January
Y2  - 2018
DO  - 10.18596/jotcsa.396618
JF  - Journal of the Turkish Chemical Society Section A: Chemistry
JO  - JOTCSA
PB  - Turkish Chemical Society
WT  - DergiPark
SN  - 2149-0120
SP  - 469
EP  - 478
VL  - 5
IS  - 2
LA  - en
AB  - A new polymerization mechanistic transformationstrategy, combining two different controlled polymerization techniques ofdifferent modes, atom transfer radical polymerization (ATRP) and photoinducedradical oxidation/addition/deactivation (PROAD), is successfully applied forthe synthesis of block copolymers. Thus, mono- or bi- bromide functionalpolystyrenes (PS-Br or Br-PS-Br) synthesized by light induced ATRP were used asmacroinitiator for the living cationic polymerization of isobutyl vinyl ethervia PROAD process to give the corresponding block copolymers. In this way,depending on the structure of the macroinitiator, AB or ABA type blockcopolymers (PS-b-PIBVE or PIBVE-b-PS-b-PIBVE)were formed. The final polymers and precursor polymers were characterized byspectral and chromatographic analyses.
KW  - Mechanistic transformation
KW  - block copolymer
KW  - ATRP
KW  - PROAD
CR  - Assoc. Prof. Muhammet U. Kahveci, Istanbul Technical University, kahvecimuk@gmail.com
CR  - Assist. Prof. Omer Suat Taskın, Istanbul University, omert@istanbul.edu.tr
UR  - https://doi.org/10.18596/jotcsa.396618
L1  - https://dergipark.org.tr/en/download/article-file/438004
ER  -