TY  - JOUR
T1  - Novel Aminopyrene Substituted Monospiro/Dispiro Cyclotriphosphazenes:  Synthesis, Characterization and Chemosensor Properties
AU  - Şenkuytu, Elif
PY  - 2018
DA  - June
DO  - 10.18466/cbayarfbe.399162
JF  - Celal Bayar University Journal of Science
JO  - CBUJOS
PB  - Manisa Celal Bayar University
WT  - DergiPark
SN  - 1305-130X
SP  - 209
EP  - 216
VL  - 14
IS  - 2
LA  - en
AB  - In the present work, the novel aminopyrenesubstituted monospiro/dispirocyclotriphosphazenes (6 and 7) have been synthesized. Thiscompounds were characterized general spectroscopic techniques such as mass, 1Hand 31P NMR spectrometry. The photophysical and chemosensorproperties toward various metals (Fe3+, Cr3+, Co2+,Al3+, Hg+, Mn2+, Ni2+, Cu2+,Cd2+, Zn2+, Mg2+, Ca2+, Ba2+,Li+, Na+, K+, Cs+) in THF solutionsof aminopyrene substituted compounds were investigated by fluorescencespectroscopy. The metal sensing results showed that compounds 6 and 7 can be candidate fluorescent chemosensors for Cu2+ andFe3+ ions due to their displaying high selectivity and low limit ofdetection.
KW  - Cyclotriphosphazene
KW  - Monospiro
KW  - Dispiro
KW  - 1-Aminopyrene
KW  - Photophysical Properties
CR  - 1.	Allcock, H.R, Recent advances in phosphazene (phosphonitrilic) chemistry, Chemical Reviews, 1972, 72, 315-356.
CR  - 2.	Chandrasekhar, V, Krishnan, V, Advances in the chemistry of chloro-cyclophosphazenes, Advances in Inorganic Chemistry, 2002, 53, 159-211.
CR  - 3.	Yıldırım, T, Bilgin, K, Yenilmez Çiftçi, G, Tanrıverdi Eçik, E, Şenkuytu, E, Uludağ, Y, Tomak, L, Kılıç, A, Synthesis, cytotoxicity and apoptosis of cyclotriphosphazene compounds as anti-cancer agents, European Journal of Medicinal Chemistry, 2012, 52, 213-220.
CR  - 4.	Bolink, H.J, Barea, E, Costa, R.D., Coronado, E, Sudhakar, S, Zhen, C, Sellinger, A Efficient blue emitting organic light emitting diodes based on fluorescent solution processable cyclic phosphazenes, Organ-ic Electronics, 2008, 9, 155–163.
CR  - 5.	Moriya, K, Masuda, T, Suzuki, T, Yano, S, Kajiwara, M, Liquid Crystalline Phase Transition in Hexakis (4-(N-(41-alkoxyphenyl) iminomethyl) phenoxy) cyclotriphosphazene. Molecular Crystals and Liquid Crystals Science and Technology Section A. Molecular Crys-tals and Liquid Crystals, 1998, 318(1), 267-278.
CR  - 6.	Davarcı, D, Zorlu, Y, Group 12 metal coordination polymers built on a flexible hexakis(3-pyridyloxy)cyclotriphosphazene ligand: Effect of the central metal ions on the construction of coordination polymers, Polyhedron, 2017, 127, 1–8.
CR  - 7.	Şenkuytu, E, Tanrıverdi Eçik, E, Durmuş, M, Yenilmez Çiftçi, G,  Monofunctional amines substituted fluorenylidene bridged cyclotri-phosphazenes: ‘Turn-off’ fluorescence chemosensors for Cu2+ and Fe3+ ions, Polyhedron, 2015, 101, 223–229.
CR  - 8.	Yenilmez Çiftçi, G, Şenkuytu, E, Bulut, M, Durmuş, M, Novel Coumarin Substituted Water Soluble Cyclophosphazenes as “Turn-Off” Type Fluorescence Chemosensors for Detection of Fe3+ ions in Aqueous Media, Journal of Fluorescence, 2015, 25, 1819–1830.
CR  - 9.	Kundu, A, Hariharan, P.S, Prabakaran, K, Anthony, S.P, Synthesis of new colori/ A fluorimetric chemosensor for selective sensing of bi-ologically important Fe3+, Cu2+ and Zn2+ metal ions, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2015, 151, 426–431.
CR  - 10.	Li, C.Y, Zou, C.X, Li, Y.F, Tang, J.L, Weng, C, A new rhodamine-based fluorescent chemosensor for Fe3+ and its application in living cell imaging, Dyes and Pigments, 2014, 104, 110-115.
CR  - 11.	Wanga, D, Zheng, J.Q, Zhenga, X.J, Fanga, D.C, Yuanc, D.Q, Jin, L.P, A fluorescent chemosensor for the sequential detection of cop-per(II) and histidine and its biological applications, Sensors and Actu-ators B, 2016, 228, 387–394.
CR  - 12.	Evstatiev, R, Gasche, C, Iron sensing and signalling, Gut, 2012, 61, 933–952.
CR  - 13.	Que, E.L, Domaille, D.W, Chang, C.J, Metals in Neurobiology: Probing Their Chemistry and Biology with Molecular Imaging, Chemical Reviews, 2008, 108, 1517–1549.
CR  - 14.	Andrews, N, Disorders of Iron Metabolism, The New England Jour-nal of Medicine, 1999, 341, 1986–1995.
CR  - 15.	Squittia, R,  Ghidoni, R, Simonelli, I, Ivanova, I.D, Colabufo, N.A, Zuin, M, Benussi, L, Binetti, G, Cassetta, E, Rongioletti, M, Siotto, M, Copper dyshomeostasis in Wilson disease and Alzheimer's disease as shown by serum and urine copper indicators, Journal of Trace El-ements in Medicine and Biology, 2018, 45, 181–188.
CR  - 16.	Wang, C, Liu, Y, Cheng, J , Song, J, Zhao, Y, Ye, Y, Efficient FRET-based fuorescen tratiometric chemosensors for Fe3+ and it sap-plication in living cells, Journal of Luminescence, 2015, 157, 143–148.
CR  - 17.	Park, G.J, You, G.R, Choi, Y.W, Kim, C, A naked-eye chemosensor for simultaneous detection of iron and copper ions and its copper complex for colorimetric/fluorescentsensing of cyanide, Sensors and Actuators B, 2016, 229, 257–271.
CR  - 18.	Cheng, P.F, Xu, K.X, Yao, W, Xie, E, Liu, J, Novel fluorescent chemosensors based on carbazole for Cu2+ and Fe3+ in aqueous media, Journal of Luminescence, 2013, 143, 583–586.
CR  - 19.	Carriedo, G.A, Catuxo, L.F, Alonso, F.J.G, Elipe, P.G,  Gonzalez, P.A, Preparation of a New Type of Phosphazene High Polymers Con-taining 2,2’-Dioxybiphenyl Groups, Macromolecules, 1996, 29, 5320-5325.
CR  - 20.	Parker, C.A, Rees, W, Correction of Fluorescence Spectra and Meas-urement of Fluorescence Quantum Efficiency, Analyst, 1960, 85(1013), 587-600.
UR  - https://doi.org/10.18466/cbayarfbe.399162
L1  - https://dergipark.org.tr/en/download/article-file/497163
ER  -