@article{article_407781, title={Catalytic Oxidation of 2-Mercaptoethanol by Cobalt(II)phthalocyanines Bearing Chalcone with Furan and Thiophene}, journal={Sakarya University Journal of Science}, volume={22}, pages={1699–1703}, year={2018}, DOI={10.16984/saufenbilder.407781}, author={Karaca, Hüseyin}, keywords={Catalysis,2-mercaptoethanol,oxidation,phthalocyanine}, abstract={<p class="MsoNormal">Cobalt
(II) <span lang="en-us" xml:lang="en-us">phthalocyanines carrying </span>on the four of the peripheral positions
furan and thiophene as chalcones were sythesized. <span lang="en-us" xml:lang="en-us">THF is used to investigate the catalytic
oxidation of 2-mercaptoethanol. The
synthesized phthalocyanines show catalytic activity on the oxidation of
2-mercaptoethanol. Cobalt (II) phthalocyanine derived by chalcone with furan
has given catalytic specifications such as turnover number TON as 16.6, initial
reaction rate as 0.293 μmol/sec
and the oxygen consumption as </span>10.06 <span lang="en-us" xml:lang="en-us">μmol/min.
The other cobalt (II) phthalocyanine derived by chalcone with thiophene has
given catalytic specifications such as turnover number TON as 15.9, initial
reaction rate as 0.213 μmol/sec and
the oxygen consumption as 9.88 μmol/min. So chalcone derived phthalocyanines can be used as catalyst is oxidation
of mercaptan by air. </span> </p> <p> </p>}, number={6}, publisher={Sakarya University}