TY  - JOUR
T1  - Siyah Çay (Camellia sinensis) Sulu Ekstraktı Kullanılarak Nanotanecikli ZnO İnce Filminin Üretilmesi ve Karakterize Edilmesi
TT  - Production and Characterization of Nanoparticle ZnO Thin Film by Using Black Tea (Camellia sinensis) Aqueous Extract
AU  - Çolak, HAKAN
PY  - 2018
DA  - December
Y2  - 2018
DO  - 10.21597/jist.409028
JF  - Journal of the Institute of Science and Technology
JO  - J. Inst. Sci. and Tech.
PB  - Igdir University
WT  - DergiPark
SN  - 2536-4618
SP  - 163
EP  - 170
VL  - 8
IS  - 4
LA  - tr
AB  - Nanoteknoloji, malzeme biliminin önemli bir araştırma alanıdır. Özellikle, çevre dostu yöntemlerkullanılarak nanoyapılı malzemelerin üretilmesi nanoteknoloji için daha da önemli hale gelmiştir. Çinko oksit(ZnO) nanoteknoloji için öne çıkan malzemeden bir tanesidir. Bu çalışmada, siyah çayın (Camellia sinensis) suluekstraktı kullanılarak ZnO nanotanecikleri üretildi ve döndürerek kaplama sistemi ile bir cam altlık üzerine incefilm olarak kaplandı. Üretilen ZnO örneğinin tanımlanması ve kristal özelliklerinin belirlenmesi x-ışını difraksiyonu(XRD) ile gerçekleştirildi. XRD verilerinden ZnO örneğinin ortalama kristal boyutu 44 nm olarak hesaplandı. ZnOörneğinin morfolojik özellikleri alan emisyonlu-taramalı elektron mikroskobu (FE-SEM) ile incelendi ve ortalamatanecik boyutu yaklaşık 100 nm olarak ölçüldü. Üretilen ZnO örneğinin optik özellikleri mor ötesi-görünür bölge(UV-VIS) spektrofotometresi ile incelendi ve 350-1000 nm dalgaboyu aralığında % 90 üzerinde optik geçirgenlikgözlendi. Üretilen ZnO örneğinin elektriksel iletkenlik değerleri dört nokta dc sistemi ile ölçüldü ve sırasıyla 35 ve550 °C ölçüm sıcaklıklarında 1.65*10-8 ve 1.26*10-6 Ω-1.cm-1 olarak belirlendi.
KW  - Nanomalzemeler
KW  - ZnO
KW  - siyah çay (Camellia sinensis)
KW  - yeşil sentez yöntemi
KW  - yeşil sentez yöntemi
N2  - Nanotechnology is an important field of research in materials science. In particular, the productionof nanostructured materials via environmentally friendly methods has become even more important fornanotechnology. Zinc oxide (ZnO) is one of the few materials that stand out for nanotechnology. In this study, ZnOnanoparticles were produced using black tea (Camellia sinensis) aqueous extract and coated on a glass substrateby a spin coating system. X-ray diffraction (XRD) system was used to characterize the produced ZnO sample anddetermine its crystal properties. The average crystal size of ZnO sample was calculated to be 44 nm from XRDresults. Morphological properties of produced ZnO sample was examined by field emission-scanning electronmicroscopy (FE-SEM) and the average particle size was measured as about 100 nm. The optical properties of theproduced ZnO sample were investigated by ultraviolet-visible region (UV-VIS) spectrophotometer and opticaltransparency was over 90 % in the range of 300 to 1000 nm. The electrical conductivity values of the producedZnO sample were measured by four probe dc system, and determined to be 1.65*10-8 and 1.26*10-6 Ω-1.cm-1 at themeasurement temperatures of 35 and 550 °C, respectively.
CR  - Adnan M, Ahmad A, Ahmed A, Khalid N, Hayat I, Ahmed I, 2013. Chemical Composition and Sensory Evaluation of Tea (Camellia sinensis) Commercialized in Pakistan, Pakistan Journal of Botany, 45 (3): 901-907.
CR  - Bagnall D, Chen Y, Zhu Z, Yao T, Koyama S, Shen M, Goto T, 1997. Optically Pumped Lasing of ZnO at Room Temperature Applied Physics Letters, 70 (17): 2230-2232.
CR  - Çolak H, Karaköse E, 2017a. Green Synthesis and Characterization of Nanostructured ZnO Thin Films Using Citrus aurantifolia (Lemon) Peel Extract by Spin Coating Method, Journal of Alloys and Compounds, 690: 658-662.
CR  - Çolak H, Karaköse E, 2017b. Structural, Electrical and Optical Properties of Green Synthesized ZnO Nanoparticles Using Aqueous Extract of Thyme (Thymus vulgaris). Journal of Materials Science: Materials in Electronics, 28 (16): 12184-12190.
CR  - Çolak H, Karaköse E, Duman F, 2017. High Optoelectronic and Antimicrobial Performances of Green Synthesized ZnO Nanoparticles by Using Aesculus hippocastanum. Environmental Chemistry Letters, 15 (3): 547-552.
CR  - Esparza-Gonzalez SC, Sanchez-Valdes S, Ramirez-Barron SN, Loera-Arias MJ, Bernal J, Ivan Melendez-Ortiz H, Betancourt-Galindo R, 2016. Effects of Different Surface Modifying Agents on the Cytotoxic and Antimicrobial Properties of ZnO Nanoparticles. Toxicology in Vitro, 37: 134-141.
CR  - Hong CS, Park HH, Park HH, Chang HJ, 2008. Optical and Electrical Properties of ZnO Thin Film Containing Nano-sized Ag Particles. Journal of Electroceramics, 22(4): 353-356.
CR  - Khan MI, Bhatti KA, Qindeel R, Bousiakou LG, Alonizan N, e-Aleem F, 2016. Investigations of the Structural, Morphological and Electrical Properties of Multilayer ZnO/TiO2 Thin Films, Deposited by Sol-gel Technique. Results in Physics, 6: 156-160.
CR  - Kumar B, Smita K, Cumbal L, Debut A, 2014. Green Approach for Fabrication and Applications of Zinc Oxide Nanoparticles. Bioinorganic Chemistry and Applications,  2014: 523869-523875.
CR  - Lee JB, Le HJ, Seo SH, Park JS, 2001. Characterization of Undoped and Cu-doped ZnO Films for Surface Acoustic Wave Applications. Thin Solid Films, 398-399: 641-646.
CR  - Lee W, Kang J, Chang K, 2006. Electronic Structure of Phosphorus in ZnO. Physica B: Condensed Matter, 376-377: 699-702.
CR  - Narin İ, Çolak H, Türkoğlu O, Soylak M, Doğan M, 2004. Heavy Metals in Black Tea Samples Produced in Turkey. Bulletin of Environmental Contamination and Toxicology, 72 (4): 844-849.
CR  - Sangeetha G, Rajeshwari S, Venckatesh R, 2011. Green Synthesis of Zinc Oxide Nanoparticles by Aloe Barbadensis Miller Leaf Extract: Structure and Optical properties. Materials Research Bulletin, 46 (12): 2560-2566.
CR  - Sawalha A, Abu-Abdeen M, Sedky A, 2009. Electrical Conductivity Study in Pure and Doped ZnO Ceramic System. Physica B: Condensed Matter 404: 1316-1320.
CR  - Shende S, Gade A, Rai M, 2017. Large-Scale Synthesis and Antibacterial Activity of Fungal-Derived Silver Nanoparticles. Environmental Chemistry Letters, 15 (3): 427-434.
CR  - Sirelkhatim A, Mahmud S, Seeni A, Kaus NHM, Ann LC, Bakhori SKM, Hasan H, Mohamad D, 2015. Review on Zinc Oxide Nanoparticles: Antibacterial Activity and Toxicity Mechanism. Nano-Micro Letters, 7(3): 219–242.
CR  - Tang Z, Wong G, Yu P, Kawasaki M, Ohtomo A, Koinmura H, Segawa Y, 1998. Room-Temperature Ultraviolet Laser Emission from Self-Assembled ZnO Microcrystallite Thin Films. Applied Physics Letters, 72 (25): 3270-3272.
CR  - Tariq AL, Reyaz AL, 2012. Phytochemical Analysis of Camellia sinensis Leaves. International Journal of Drug Development and Research, 4 (4): 311-316.
CR  - Yilmaz S, Turkoglu O, Belenli I, 2008. Measurement and Properties of the Ionic Conductivity of β-Phase in the Binary System of (Bi2O3)1-X(Sm2O3)X. Materials Chemistry and Physics, 112: 472-477.
UR  - https://doi.org/10.21597/jist.409028
L1  - https://dergipark.org.tr/en/download/article-file/594234
ER  -