@article{article_42192, title={SYNTHESIS AND CHARACTERIZATION OF SOME (3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL) (METHYL) SULFANE SUBSTITUTED TITANIUM PHTHALOCYANINE DERIVATIVES}, journal={Anadolu University Journal of Science and Technology A - Applied Sciences and Engineering}, volume={14}, pages={135–142}, year={2013}, author={Elmalı, Dilek and Demirel, Gürol}, keywords={Phthalocyanines; Phthalonitrile; MALDI-TOF}, abstract={Symmetrically substituted phthalocyanine derivatives have been synthesized from the reaction of anhydrous metal salts of titanium with 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio) phthalonitrile ( <strong>3) </strong>. 4-phthalonitrile ( <strong>1) </strong> and 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthiol) ( <strong>2) </strong> in dry dimethylformamide as solvent and using K <sub>2 </sub>CO <sub>3 </sub> as base via the common method of nucleophilic substitution of an activated nitro group in an aromatic ring. The compound 3,9,17,23-bis[ethane-1,1- <em>p- </em>phenol-2,2- <em>p- </em>phenokxy]phthalocyaninatocobalt (II) (FlTi <sub>2 </sub>CoPc) <sub> </sub>( <strong>4) </strong> was reacted with the compound 4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio) phthalocyaninatotinanium (IV) ( <strong>5) </strong>, which is similar to those synthesized in the past, to syhthesize a new derivative containing three phthalocyanines 3,9,17,23-bis[ethane-1,1- <em>p </em>-(4-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylthio) phthalocyaninatotinanium (IV))-2,2- <em>p- </em>phenokxy]phthalocyaninatocobalt (II) (FlTi <sub>2 </sub>CoPc) <sub> </sub> ( <strong>6) </strong>. The synthesized molecules have been characterized by <sup>19 </sup>F NMR, HETCOR, MALDI-TOFF, UV-Vis and IR spectroscopies. <br />}, number={2}, publisher={Eskisehir Technical University}