TY  - JOUR
T1  - SYNTHESIS AND OPTICAL PROPERTIES OF THE NOVEL Ho(5-SSA), (5-SSA = 5-SULFOSALICYLIC ACID) CAGE STRUCTURE
TT  - ÖZGÜN Ho(5-SSA), (5-SSA = 5-SÜLFOSALİSİLİK ASİT) KAFES YAPISININ SENTEZLENMESİ VE OPTİKSEL ÖZELLİKLERİ
AU  - Dönmez, Adem
PY  - 2018
DA  - June
DO  - 10.22531/muglajsci.423816
JF  - Mugla Journal of Science and Technology
JO  - MJST
PB  - Mugla Sitki Kocman University
WT  - DergiPark
SN  - 2149-3596
SP  - 116
EP  - 122
VL  - 4
IS  - 1
LA  - en
AB  - In recent years,intensive studies have been made on metal-organicframeworks (MOFs) which is kind of spongy structures having excellent originalarchitectures formed by ligands in organic forms and metal centers classifiedas binders. The main reason for this condensation is due to the great huge potential for such materials to beused in many technological application areas such as sensors, gas storage,photo-catalysis, organic light emitting diodes (OLEDs), solar cells (SCs) andluminescent emitting devices. The properties of the metal-organic frameworksdepend on the selected organic ligands and metal ions. Therefore, new researchand technology development (R-T-G) fields can be discovered with thesematerials that can be originally synthesized. In this work, Ho(III)-based metal-organic framework (Ho-MOF; [Ho(5-SSA)],5-SSA = 5-sulfosalicylic acid) was synthesized by hydrothermal method. Thestructural characterization has been madeby powder X-ray diffraction, a roomtemperature solid-state UV and FT-IR spectroscopy.In addition, the solid-statephotoluminescence measurements have been taken at room temperature in the UV-visible and near-infraredregion (NIR) and the energy transfer mechanism from 5-SSA ligand to the Ho+3ion is investigated in detail. Under the excitation of UV light (at 349 nm), 5-SSA ligand exhibited abroad navy-blue emission while its Ho-MOF complex exhibited severalcharacteristic emissions of the Ho+3 ion in the UV-Visible and NIRregion. The excellent luminescent performances make this compound very goodcandidate for efficient luminescence materials.
KW  - Luminescence
KW  - Metal-Organic Frameworks
KW  - Holmium
N2  - Birleştirici olarakadlandırılan organik yapıdaki ligandlar ile bağlayıcı olarak sınıflandırılanmetal merkezlerin oluşturdukları mükemmel özgün mimariye sahip olan süngerimsiyapılar diğer bir deyişle Metal organik çerçeveler (MOÇ) üzerinde son yıllardaoldukça yoğun çalışmalar yapılmaktadır. Bu yoğunlaşmanın başlıca nedeni bu türmalzemelerin sensörler, gaz depolama, foto-katalizörler, organik ışık yayandiyotlar (OLED), güneş hücreleri (SC) ve lüminesans yayabilen aygıtlar gibibirçok teknolojik uygulama alanlarında kullanılabilme potansiyelinin yüksekolmasından ötürüdür. Metal organik çerçevelerin özellikleri, seçilen organikligandlara ve metal iyonlarına bağlıdır. Dolayısıyla özgün olaraksentezlenebilen bu kristal malzemeler ile yeni araştırma ve teknolojigeliştirme (Ar-Te-Ge) alanları keşfedilebilmektedir. Bu çalışmada,Ho(III)-tabanlı metal-organik çerçevesi (Ho-MOÇ; [Ho(5-SSA)], 5-SSA =5-Sülfosalisilik asit) hidrotermal metot ile sentezlenmiştir. Toz kristalX-ışını kırınımı, oda sıcaklığında katı-hal UV ve FT-IR spektroskopisiteknikleri yardımıyla yapısal karakterizasyonu yapılmıştır. Buna ek olarak, odasıcaklığında görünür ve yakın kızıl ötesi (NIR) bölgede katı hal fotolüminesansölçümleri alınmış ve 5-SSA ligandından Ho+3 iyonuna olan enerji transfermekanizması detaylı bir şekilde incelenmiştir.UV ışınım altında(349 nm’de), 5-SSA ligandı geniş bir lacivert renginde yayılım sergilerken,Ho-MOÇ kompleksi UV-Görünür ve NIR bölgesinde Ho+3 iyonunun çeşitlikarakteristik emisyonlarını sergilemiştir. Mükemmel ışıldama performansları, bubileşiği yüksek verimli ışınım veren malzemeler için çok iyi bir aday halinegetirmektedir.
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UR  - https://doi.org/10.22531/muglajsci.423816
L1  - https://dergipark.org.tr/en/download/article-file/491487
ER  -