TY  - JOUR
T1  - Synthesis and Characterization of Metal Carbonyls [M(CO)6(M = Cr,Mo,W)] with Indole -3-carboxyaldehydemethanesulfonylhydrazone
TT  - Synthesis  and  Characterization  of  Metal Carbonyls  [M(CO)6         (M= Cr, Mo,W), Re(CO)5Br]   with    Indole -3-carboxyaldehydemethanesulfonylhydrazone
AU  - Sert, Sema
PY  - 2018
DA  - December
Y2  - 2018
DO  - 10.38061/idunas.444281
JF  - Natural and Applied Sciences Journal
JO  - IDU Natural and Applied Sciences Journal (IDUNAS)
PB  - Izmir University of Democracy
WT  - DergiPark
SN  - 2645-9000
SP  - 31
EP  - 34
VL  - 1
IS  - 2
LA  - en
AB  - Four new complexes, [M(CO)5(msh4)](Cr(1),Mo(2),W(3)),and Re(CO)4Br(inmsh)(4),were synthesized by the photochemical reaction of metal carbonyls with indole-3 carboxyaldehydemethanesulfonyl hydrazone(inmsh) and characterized by using elemental analysis, 1H NMR, EI-MS and IR spectra. The spectroscopic studies show thatinmsh behaves as a monodantate ligand coordinating via imine N donor atom in [M(CO)5(inmsh)](M = Cr,Mo,W) and Re(CO)4Br(inmsh).The sulfonamides (−SO2NH−) are used widely as antibacterial agents because of their lower cost, lower activity and mostactivity against bacterial diseases[1]. Sulfo drugs are used as chemotherapeutic agents with large spectrum of activity andthey are used today for various bacterial, protozoal and fungal infections[2a,b]. Methane sulfonamide derivatives possessDNA-binding ability and show cytostatic effects which have usage in cancer chemotherapy. Sulfonylhydrazones derived fromsulfonamides have pharmacological properties as antibacterial, antitumor, divretic, antiviral, antinociceptive activity and enzyminhibition especially to carbonic anhydrase species[3,4]. Many of the physiologically active hydrazones have applications in thetreatment of illness like tuberculosis, leprosy and mental damage
KW  - Metal Carbonyls
KW  - Sulfonylhydrazones
KW  - Photochemical Reactions
N2  - AbstractFour newcomplexes, M(CO)5(inmsh) (M=Cr(1), Mo(2),W(3)) and Re(CO)4Br(inmsh)(4), were synthesized by the photochemical reaction of metal carbonyls withindole-3-carboxyaldehydemethanesulfonyl hydrazone(inmsh) and characterized byusing elemental analysis, 1H NMR, LC-MS and IR spectra. Thespectroscopic studies show that inmsh behaves as a monodantate ligandcoordinating via imine N donor atom in [M(CO)5(inmsh)] (M=Cr, Mo, W)and Re(CO)4Br(inmsh).
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UR  - https://doi.org/10.38061/idunas.444281
L1  - https://dergipark.org.tr/en/download/article-file/1054468
ER  -