TY - JOUR T1 - Extraction of Heavy Metals using Dithizone Method on Seawater AU - Kok Seng, Leong PY - 2018 DA - August JF - The Eurasia Proceedings of Science Technology Engineering and Mathematics JO - EPSTEM PB - ISRES Publishing WT - DergiPark SN - 2602-3199 SP - 429 EP - 434 IS - 2 LA - en AB - Researchconducted is related to the preparation and characterization of dithizonemethod based on extraction of cadmium, lead and zinc trace metals from seawatersamples. Inorganic metals or ions can act back with dithizone to producecolourful coordination. The dithizone reagent is highly sensitive to thepresence of heavy metals such as plumbum (Pb), cadmium (Cd) and zinc (Zn) asdesignated in this study. Inorganic metals or ionic can react with dithizone toproduce colored coordination compounds. The resulting dithizoneate may beextracted with an organic solvent such as carbon tetrachloride (CCl4).This study also involves steps such as adjusting the pH value in order toproduce the dithizoneate metal product we need. In this study, metal powderswere dissolved in seawater samples and extracted with dithizone to enhance thedetection and extraction facilities. We analyze trace metals carried out byplasma atomic emission spectroscopy (ICP-OES) to see the efficiency ofdithizone extraction methods into seawater samples used. Dithizone extraction method used in extracting Pb element indicates a goodperformance. KW - Dithizone CR - Satyanarayanan M., Balaram V., Gnaneshwar T., Dasaram B., Ramesh S. L., Ramavati Mathur dan Drolia R. K.. 2006. Determination of trace metals in seawater by ICP-MS after preconcentration matrix separation by dithiocarbamate complexes. Indian Journal of Marine Sciences (36): 71-75. Hiraide M., Yoshida Y dan Mizuike A. 1976. Flotation of traces of heavy metals coprecipitated with aluminium hydroxide from water and seawater. Anal. Chim. Acta (81): 185-189. Sturgeon R. E. dan Berman S.S.. 1980. Preconcentration of trace metals from seawater for determination by graphite furnace atomic-absorption spectrometry. Talanta (27): 85-94. Danielsson L.G., Magnusson B., Westerlund S. dan Zhang K.. 1982. Trace metal determination in estuarine waters by electrothermal atomic absorption spectrometry after extraction with dithiocarbamate complexes from freon. Anal. Chim. Acta (144): 183-188. Sachhsenberg S., Klenrike Th., Krumbein W. E. dan Zeeck E., 1992. A back extraction procedure method: Rapid determination of metals in seawater matrices. Fresenius J. Anal. Chem (342): 163-166. Jan T. K. dan Young D. R.. 1978. Determination of microgram amounts of some transition metals in seawater by methyl isobutyl ketone-nitric acid successive extraction and flameless atomic absorption spectrophotometry. Anal. Chem. (50): 1250-1253. Wu J. dan Boyle E. A.. 1997. Low blank preconcentration technique for the determination of lead, copper and cadmium in a small volme seawater by isotope dilution ICPMS. Anal. Chem. (69): 2464-2470. Chandrasekhar K., Chary S. N., Kamala C. T. dan Apama V. 2003. Determination of trace metals in seawater by induced coupled mass spectrometry with preconcentration on silica-immobilized 8-hydroxyquinoline. Anal Chem. (57): 2907-2911. Jong M. L., Edward A., Boyle A., Yolanda Echegoyen-Sanz, Jessica N.,Fitzsimmons, Ruifeng Zhang dan Richard A. Kayser. 2010. Analysis of trace metals (Cu, Cd, Pb, and Fe) in seawater using single batch nitrilotriacetate resin extraction and isotope dilution inductively coupled plasma mass spectrometry. Anal. Chim. Acta. (686): 93-101. Mark L. Wells dan Kenneth W. Bruland. 1998. An improved method for rapid preconcentration and determination of bioactive trace metals in seawater using solid phase extraction and high resolution inductively coupled plasma mass spectrometry. Marine Chemistry (63): 145-153. Tessier A., Campbell P. G. C. dan Bisson M.. 1979. Sequential extraction procedure for the speciation of particulate trace metals. Analytical Chemistry (51): 844-851. Antun Kucak dan Maja Blanusa. 1998. Comparison of two extraction procedures for determination of trace metals in soil by atomic absorption spectrometry. Arh hig rada toksikol (49): 327-334. Bert L. Vanllee dan John G. Gibson. 1948. An improved method for the determination of small quantities of zinc in blood and tissue samples. Microdetermination of Zinc in Blood.: 435-449. UR - https://dergipark.org.tr/en/pub/epstem/issue//455977 L1 - https://dergipark.org.tr/en/download/article-file/528363 ER -