@article{article_464098, title={Photo-Isomerization and Decarboxilation of 2-Amino-5-Chlorobenzoic Acid in Argon Matrix}, journal={Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi}, volume={5}, pages={55–63}, year={2018}, author={Kuş, Nihal}, keywords={Matrix isolation IR spectroscopy,2-Amino-5-Chlorobenzoic Acid,Photoisomerization,Decarboxcylation}, abstract={<p> <span style="font-size:12pt;font-family:’Times New Roman’, serif;">In this paper, the
matrix isolation infrared spectroscopy technique is presented, and its
application to the work of photoisomerization reaction for
2-amino-5-chlorobenzoic acid (AClBA) was studied by matrix isolation
spectroscopy in argon matrix at 15 K. The considered photoreactions include
conformational isomerizations as well as bond-breaking/bond-forming structural
isomerizations. UV irradiation at </span> <span style="font-size:12pt;font-family:Symbol;">l </span> <span style="font-size:12pt;font-family:’Times New Roman’, serif;">
> 234 nm of the matrix-isolated compound was found to lead to conversion of
this conformer into the other conformers and also to decarboxylation of the
AClBA, producted with of CO <sub>2 </sub> and 2-amino-5-chlorobenzene (AClB). The
analysis of the experimental data on matrix isolated AClBA was supported by
extensive quantum chemical calculations. </span> <br /> </p>}, number={2}, publisher={Bilecik Seyh Edebali University}