TY  - JOUR
T1  - Schiff Bazlarının Dioksouranyum (VI) Komplekslerinin Sentezi ve Karakterizasyonu (Karışık Ligandlar Bölüm 1)
AU  - Canpolat, Erdal
PY  - 2014
DA  - June
DO  - 10.17798/beufen.41970
JF  - Bitlis Eren Üniversitesi Fen Bilimleri Dergisi
PB  - Bitlis Eren University
WT  - DergiPark
SN  - 2147-3129
SP  - 74
EP  - 80
VL  - 3
IS  - 1
LA  - tr
AB  - Schiff Bazları ve piridin, dimetilformamid, 2,2’-bipridin, 1,10-fenantrolin yada trietilamin ile dioksouranyum (VI)’un yeni seri karışık-ligand kompleksleri sentezlenmiştir. Komplekslerin sentezinde elementel analiz, İnfrared, proton NMR, karbon-13 NMR, elektronik spektrum, manyetik süssebtibilite ve termogravimetrik analiz kullanılmıştır. Komplekslerin genel formulü [(L1)(UO2)(OAc)(H2O)].2H2O (1), [(L2)(UO2)(OAc)(py)].H2O (2), [(L3)(UO2)(OAc)(DMF)].2H2O (3), [(L4)(UO2)(OAc)(bipy)].H2O (4), [(L5)(UO2)(OAc)(phen)].H2O (5) and [(L6)(UO2)(OAc)(Et3N)].3H2O (6). şeklindedir.
KW  - Schiff Bazları
KW  - Schiff Bazlarının UO2(VI) Kompleksleri
N2  - New series of mixed-ligands complexes of dioxouranium (VI) with the Schiff bases and H2O, py, DMF, bipy, phen and Et3N have been synthesized. The elemental analyses, IR, 1H-NMR and 13C-NMR spectra, electronic spectra, magnetic susceptibility measurements and thermogravimetric analyses were used in the synthesis of complexes. The general compositions of the complexes are [(L1)(UO2)(OAc)(H2O)].2H2O (1), [(L2)(UO2)(OAc)(py)].H2O [(L5)(UO2)(OAc)(phen)].H2O (5) and [(L6)(UO2)(OAc)(Et3N)].3H2O (6). (2),  [(L3)(UO2)(OAc)(DMF)].2H2O (3),  [(L4)(UO2)(OAc)(bipy)].H2O (4)
CR  - Patel K. M., Patel K. N., Patel N. H. Patel M. N. 2001. Synthesis, Characterization, and Antimicrobial Activities of some Transition Metal Complexes with a Tridentate Dibasic Schiff Base and Bidentate 2,2′-Bipyridylamine, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 31 (2): 239-246.
CR  - Syamal A., Maurya M. R. 1989. Coordination Chemistry of Schiff Base Complexes of Molybdenum, Coordination Chemistry Reviews, 95 (2): 183-238.
CR  - Agarwala B. V., Hingorani S., Puri V., Khetrapal C. L., Naganagowda G. A. 1994. Physicochemical Studies of (o-Vanillin Thiosemicarbazonato)-Nickel(II) Chelate, Transition Metal Chemistry, 19 (1): 25-27.
CR  - Maurya R. C., Patel P., Rajput S. 2003. Synthesis and Characterization of Mixed‐Ligand Complexes of Cu (II), Ni (II), Co (II), Zn (II), Sm (III), and U (VI)O2, with a Schiff Base Derived from the Sulfa Drug Sulfamerazine and 2,2′‐Bipyridine, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 33 (5): 801-816.
CR  - Osowole A. A., Kolawole G. A., Fagade O. E. 2008. Synthesis, Characterization and Biological Studies on Unsymmetrical Schiff-Base Complexes of Nickel (II), Copper (II) and Zinc (II) and Adducts with 2,2′-dipyridine and 1,10-phenanthroline, Journal of Coordination Chemistry, 61 (7): 1046-1055.
CR  - Sadeek S. A., Teleb S. M., Refat M. S., Elmosallamy M. A. F. 2005. Preparation, thermal and vibrational studies of [UO2(acac-o-phdn)(L)] (L=H2O, py, DMF and Et3N), Journal of Coordination Chemistry, 58 (12): 1077-1085.
CR  - Mohamed G. G., Zayed M. A., Abdallah S. M. 2010. Metal Complexes of a Novel Schiff Base Derived from Sulphametrole and Varelaldehyde. Synthesis, Spectral, Thermal Characterization and Biological Activity, Journal of Molecular Structure, 979 (1-3): 62-71.
CR  - Ramesh R., Sivagamasundari M. 2003. Synthesis, Spectral and Antifungal Activity of Ru(II) Mixed‐Ligand Complexes, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano- Metal Chemistry, 33 (5): 899-910.
CR  - Canpolat E., Kaya M. 2005. Studies on Mononuclear Chelates Derived from Substituted Schiff Bases Ligands (Part 1): Synthesis and Characterization of a new Salicyliden-p- aminoacetophenoneoxime and its Complexes with Co (II), Ni (II), Cu (II) and Zn (II), Polish Journal of Chemistry, 79(6): 959-965.
CR  - Canpolat E., Kaya M. 2005. Studies on Mononuclear Chelates Derived from Substituted Schiff Bases Ligands (Part 3): Synthesis and Characterization of a New 5-Nitrosalicyliden-p- aminoacetophenoneoxime and Its Complexes with Co(II), Ni(II), Cu(II) and Zn(II), Russian Journal of Coordination Chemistry, 31 (6): 415-419.
CR  - Canpolat E., Kaya M. 2005. Studies on Mononuclear Chelates Derived from Substituted Schiff- Base Ligands (Part 7): Synthesis and Characterization of a new Naphthyliden-p- aminoacetophenoneoxime and its Complexes with Co (II), Ni (II), Cu (II) and Zn (II), Journal of Coordination Chemistry, 58 (12): 1063-1069.
CR  - Tuna S., Canpolat E., Kaya M. 2006. Complexes of Cobalt(II), Nickel(II) and Copper(II) with 3- Hydroxysalicyliden-p-aminoacetophenoneoxime, Polish Journal of Chemistry, 80 (2): 227-234.
CR  - Canpolat E., Kaya M. 2002. Synthesis and Characterization of Ni (II), Cu (II), Zn (II) and Cd (II) Complexes of a New Vic-Dioxime Ligand, Journal of Coordination Chemistry, 55 (12): 1419- 1426.
CR  - Canpolat E., Kaya M. 2003. The Synthesis and Characterization of a Novel (E,E)-Dioxime and its Mononuclear Complexes Containing 1, 3-Dioxolane Moieties, Polish Journal of Chemistry, 77 (8): 961-967.
CR  - Mohamed G. G., Omar M. M., Ibrahim A. A. 2010. Preparation, Characterization and Biological Activity of Novel Metal-NNNN Donor Schiff Base Complexes, Spectrochimica Acta Part A, 75(2): 678–685.
CR  - Maurya R. C., Jaiswal M. N., Verma R., Shukla B. 1998. The Coordination Chemistry of Dioxouranium (VI): Studies on Some Novel Di- and Trinuclear Dioxouranium (VI) Complexes with Pyrazolone Based Schiff Bases, Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 28 (8): 1265-1281.
CR  - Nour E. M., Taha A. A., Alnaimi I. S. 1988. Infrared and Raman studies of [UO2(salen)(L)] (L=H2O and CH3OH), Inorganica. Chimica. Acta, 141 (1): 139-144.
CR  - Hingorani S., Agarwala B. V. 1993. Structural Elucidation of o-Vanillin Isonicotinoyl Hydrazone and its Metal Complexes, Transition Metal Chemistry, 18 (6): 576-578.
CR  - Jarrahpour A., Khalili D., Clercq E. D., Salmi C., Brunel J. M. 2007. Synthesis, Antibacterial, Antifungal and Antiviral Activity Evaluation of Some New bis-Schiff Bases of Isatin and Their Derivatives, Molecules, 12 (8): 1720-1730.
CR  - Canpolat E., Yazıcı A., Kaya M. 2007. Studies on Mononuclear Chelates Derived from
CR  - Substituted Schiff-Base Ligands (Part 10): Synthesis and Characterization of a new 4- Hydroxysalicyliden-p-aminoacetophenoneoxime and its Complexes with Co (II), Ni (II), Cu (II) and Zn (II), Journal of Coordination Chemistry, 60 (4): 473-480.
CR  - Tumer M., Deligönül N., Gölcü A., Akgün E., Dolaz M. 2006. Mixed-Ligand Copper (II) Complexes: Investigation of Their Spectroscopic, Catalysis, Antimicrobial and Potentiometric Properties, Transition Metal Chemistry, 31 (1): 1–12.
CR  - Bi C., Fan Y., Sun G., Chang J. 2000. Syntesis and Characterization of Th(IV) and U(VI)
CR  - Complexes with o-vanilin-p-phenylenediamine, Journal of Radioanalytical and Nuclear
CR  - Chemistry, 246 (1): 221-223.
UR  - https://doi.org/10.17798/beufen.41970
L1  - https://dergipark.org.tr/en/download/article-file/41698
ER  -