TY - JOUR T1 - Synthesis and Characterization of Zeolite Templated Carbon and Usage as Adsorbent for Removal of Pb(II) Ions from Solution AU - Tumsek, Fatma PY - 2018 DA - December JF - The Eurasia Proceedings of Science Technology Engineering and Mathematics JO - EPSTEM PB - ISRES Publishing WT - DergiPark SN - 2602-3199 SP - 87 EP - 93 IS - 4 LA - en AB - Inthis study, the porous carbon was prepared through templated synthesis methodusing the natural zeolite as template and sugar as carbon source. The porouscarbon was obtained at a carbonization temperature of 700oC with aweight ratio 1:1 for zeolite and sugar. The physical, structural and surfaceproperties of the porous carbon were characterized with the scanning electronmicroscope (SEM), transmission electron microscope (TEM), X-ray diffraction(XRD), elemental analysis and nitrogen (N2) adsorption. The specificsurface area and total pore volume of carbon were found as 412 m2/gand 0.5515 cm3/g, respectively. This carbon material was used forremoval of Pb2+ ions from solution. The effects of initial pH, temperatureand contact time on adsorption were studied. The maximum Pb2+removal was observed at pH=5. The adsorption was reached to the equilibrium in120 minutes. Various kinetic models were used for describing the adsorptionkinetic and the pseudo-second order kinetic model showed well fit. Langmuir,Freundlich and Temkin isotherm models were applied to the experimentalequilibrium data and Langmuir equation was found as best fitting isotherm.  KW - Templated carbon KW - Characterization KW - Adsorption KW - Lead CR - Bakandritsos, A., Kouvelos E., Streostis, Th., Petridis, D. (2004). Aqueous and gaseous adsorption from montmorillonite–carbon composites and from derived carbons. Langmuir, 21, 2349. Barata-Rodrigues, P.M., Mays, T.J., &Moggridge, G.D. (2003). S Structured carbon adsorbents from clay, zeolite and mesoporous aluminosilicate templates. Carbon, 41, 2231–2246. Barczak, M., Michalak-Zwierz, K., Gdula, K., Tyszczuk-Rotko, K., Dobrowolski, R., Dabrowski, A. (2015). Ordered mesoporous carbons as effective sorbents for removal of heavy metal ions. Microporous and Mesoporous Materials, 211, 162-173. Böhme, K., Einicke, W.D., &Kepel, O. (2005). Templated synthesis of mesoporous carbon from sucrose-the way from the silica pore filling to the carbon material. Carbon, 43, 1918-1925. Ma, Y.X., Kou, Y.L., Xing, D., Jin, P.S., Shao, W.J., Li, X., Du, X.Y., &La., P.Q. (2017). Synthesis of magnetic graphene oxide grafted polymaleicamide dendrimer nanohybrids for adsorption of Pb(II) in aqueous solution. Journal of Hazardous Materials, 340, 407-416. Pawar, R.R., Lalhmunsiama, Kim, M., Kim, J.G., Hong, S.M., Sawant, S.Y., &Lee, S.M. (2018). Efficient removal of hazardous lead, cadmium, and arsenic from aqueous environment by iron oxide modified clay-activated carbon composite beads. Applied Clay Science, 162, 339-350. Sakintuna, B., &Yürüm, Y. (2006). Preparation and characterization of mesoporous carbons using a Turkish natural zeolitic template/furfuryl alcohol system, Microporous and Mesoporous Materials, 93, 304-312. Santos, C., Andrade, M., Vieira, A.L., Martins, A., Pires, J., Freire, C., &Carvalho, A.P. (2010). Templated synthesis of carbon materials mediated by porous clay heterostructures. Carbon, 48, 4049–4056. Sawant, S.Y., Pawar, R.R., Lee, S.M., &Cho, M.H. (2017). Binder-free production od 3D N-doped porous carbon cubes for efficient Pb2+ removal through batch and fixed bed adsorption. Journal of Cleaner Production, 168, 290-301. Tang, N., Niu, C.G., Li, X.T., Liang, C., Guo, H., Lin, L.S., Zheng, C.W., &Zeng, G.M. (2018). Efficient removal of Cd2+ and Pb2+ from aqueous solution with amino- and thiol-functionalized activated carbon: Isotherm and kinetics modeling. Science of the Total Environment, 635, 1331-1344. UR - https://dergipark.org.tr/en/pub/epstem/issue//494350 L1 - https://dergipark.org.tr/en/download/article-file/592026 ER -