TY - JOUR T1 - Rheology of Iraqi Asphalt Modified with SBS, Polyphosphoric Acid and Sulfur AU - Saad, Doha Niethal AU - Ahmed, Eman İsmael PY - 2018 DA - December JF - The Eurasia Proceedings of Science Technology Engineering and Mathematics JO - EPSTEM PB - ISRES Publishing WT - DergiPark SN - 2602-3199 SP - 277 EP - 280 IS - 4 LA - en AB - Polymer modified asphalts (PMA) became of greatinterest over the last years because there are closely related to industrialand constructional fields. To increase the elasticity of asphalt,styrene-butadiene-styrene (SBS) type polymers are used which are elastomericblock copolymers. Although the addition of SBS type block copolymers haseconomic limits and can show serious technical limitations, it is probably themost appropriate polymer for asphalt modification. The present work seeks toidentify the changes on the rheological and physical properties of SBS modifiedwith Dora asphalt. So it is the first study using Iraqi asphalt with styrene-butadiene-styrene.In this paper polyphosphoric acid PPA and sulfur were used to improve the hightemperature property and storage stability of SBS modified asphalt.PPA canimprove the high temperature performance of the SBS modified Dura asphalt evidentlybut declain the storage stability. Owing to the gelation of PPA, the phaseseparation of SBS becomes more serious. KW - Polyphosphoric acid KW - Sulfur CR - ASTM D 113, (2007), “Standard Test Method for Ductility of Bituminous Materials”, Annual Book of ASTM Standards, V 4.03. ASTM D 36, (2009), “Standard Test Method for Softening Point of Bitumen (Ring-and Ball Apparatus)”, Annual Book Of ASTM Standards, V4.04. ASTM D 4124-09, Standard Test Method for separation of asphalt into four fractions. ASTM D 5, (2006), “Standard Test Method for Penetration of Bituminous Materials”, Annual Book of ASTM Standards, V 4.03. Babashak JF. US Patent 2005101702; 2005. Baumgardner G.L., Masson J.F., Hardee J.R., Menapace A.M., Williams A.G., Polyphosphoric acid modified asphalt: proposed mechanisms, J. Assoc. Asphalt Paving Technol. 74 (2005) 283–305. Holden G, Bisshop ET, Legge NR. Thermoplastic elastomers. J Polym Sci Part C 1969;31:26–8. Jameson R.F., 151. The composition of the ‘‘strong” phosphoric acids, J. Chem. Soc. (Resumed) (1959) 752–759. Lesueur D., The colloidal structure of bitumen: consequences on the rheology and on the mechanisms of bitumen modification, Adv. Colloid Interface Sci. 145 (1) (2009) 42–82. Lu X, Isacsson U. Rheological characterization of styrene–butadiene–styrene copolymer modified bitumens. Constr Build Mater 1997;11:23–32. Maldonado P. US Patent 2005101702 A1; 2005. Masson J.F., Brief review of the chemistry of polyphosphoric acid (PPA) and bitumen, Energy Fuels 22 (4) (2008) 2637–2640. Orange G., Dupuis D., Martin J.V., Farcas F., Such C., Marcant B., Chemical modification of bitumen through polyphosphoric acid: properties-microstructure relationship, in proceedings of the 3rd eurasphalt and eurobitume congress, vienna (vol. 1), May 2004. Peramanu, S. Pruden B.B., Rahimi P., Molecular weight and specific gravity distributions for Athabasca and Cold Lake bitumens and their saturate, aromatic, resin, and asphaltene fractions, Ind. Eng. Chem. Res. 38 (8) (1999) 3121–3130. Pfeiffer J.P., Saal R.N., Asphaltic bitumen as colloid system, J. Phys. Chem. 44 (2) (1940) 139–149. Shuler TS, Collins TH, Kirkpatrick JP. Polymer-modified asphalt properties related to asphalt concrete performance. Asphalt: Relationship to Mixture, ASTM STP 941 Amercian Society for Testing and Materials, Philadelphia; 1987. p. 179–182. Speight J.G., The Chemistry and Technology of Petroleum, CRC Press, 2014. Wang SF, Zhang Y, Zhang YX. SBS/carbon black compounds give asphalts with improved high-temperature storage stability. Polym Polym Compos 2003;11:477–85. Welborn JT. US Patent 4412019A; 1983. UR - https://dergipark.org.tr/en/pub/epstem/issue//498145 L1 - https://dergipark.org.tr/en/download/article-file/598409 ER -