TY - JOUR T1 - 1,3-dimetil-5-(3,5-dimetilfenil)aminometilenbarbitürat bor diflorür kompleksinin sentezi, karakterizasyonu ve fotofiziksel özelliklerinin incelenmesi TT - Synthesis, characterization of 1,3-dimethyl-5-(3,5-dimethylphenyl)aminomethylenebarbiturate boron difluoride complex and investigation of photophysical properties AU - Fırıncı, Erkan PY - 2019 DA - September Y2 - 2019 DO - 10.30728/boron.527576 JF - Journal of Boron PB - TENMAK Bor Araştırma Enstitüsü WT - DergiPark SN - 2149-9020 SP - 135 EP - 140 VL - 4 IS - 3 LA - tr AB - Sunulan çalışmada, barbitürik asitten türevlendirilen1,3-dimetil-5-(3,5-dimetilfenil)aminometilenbarbitürat ve1,3-dimetil-5-(3,5-dimetilfenil)aminometilenbarbitürat bor diflorür kompleksibaşarılı bir şekilde sentezlenmiştir. Sentezlenen bileşiklerin yapısalkarakterizasyonları elementel analiz, ATR FTIR ve NMR spektroskopilerikullanılarak yapılmıştır. Sentezlenen bileşiklerin lüminesans özelliğe sahipoldukları mor ötesi ve görünür bölge absorpsiyon spektroskopisi ve floresans emisyonspektroskopisi kullanılarak belirlenmiştir. Komplekste bulunan BF2grubunun emisyon bandını kırmızı bölgeye kaydırdığı tespit edilmiştir. Eldeedilen bulgular yeni lüminesans bor bileşiklerinin sentezlenebilmesi içinbarbitürat iskeletinin önemli bir potansiyele sahip olduğunu göstermiştir. KW - Barbitürik asit KW - Bor diflorür kompleksi KW - Spektroskopi N2 - In the present study, 1,3-dimethyl-5-(3,5-dimethylphenyl)aminomethylenebarbiturateand 1,3-dimethyl-5-(3,5-dimethylphenyl)aminomethylenebarbiturate borondifluoride complex were successesfully prepared. The characterizations ofsynthesized compounds were done by using elemental analysis, ATR FTIR and NMRspectroscopies. The synthesized compounds were determined to have luminescenceproperties by using ultraviolet-visible absorption and fluorescence emissionspectroscopies. 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