TY  - JOUR
T1  - ARITMA ÇAMURU, LÜLE TAŞI (SEPIYOLIT) VE YUMURTA KABUĞU ATIKLARININ POLİMER KOMPOZİT PLAKA ÜRETİMİNDE DEĞERLENDİRİLMESİ
TT  - EVALUATION of TREATMENT SLUDGE, SEPIOLITE and EGG SHELLS in THE PRODUCTION of POLYMER COMPOSITE PLATES
AU  - Uysal, Yağmur
PY  - 2019
DA  - November
DO  - 10.17780/ksujes.594973
JF  - Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi
JO  - KSU J. Eng. Sci.
PB  - Kahramanmaras Sutcu Imam University
WT  - DergiPark
SN  - 1309-1751
SP  - 70
EP  - 77
VL  - 22
LA  - tr
AB  - Bu çalışmanın amacı, kağıt endüstrisiarıtma çamurunun yine atık materyaller olan yumurta kabuğu ve lületaşı (sepiyolit)tozu ile birlikte polipropilen (PP) bazlı termoplastik plaka üretimindedeğerlendirilmesi ve elde edilen termoplastik kompozit plakanın radyasyongeçirgenlik ve mekanik dayanım (eğilme direnci, çekme direnci, dinamik eğilmedirenci, kopmada uzama ve darbe direnci) özelliklerinin belirlenmesidir. Atıkmateryaller kütlece %20-50 oranlarında kompozit levha üretimine katılmış, tümkompozit plakalar standart sıcak presleme yöntemi ile üretilmiş ve katkımaddeli polimer kompozitlerin özellikleri standart polipropilenden üretilenlevha ile karşılaştırılmıştır. Elde edilen sonuçlarda yumurta kabuğu katkılıkompozit levhanın radyasyon geçirgenliğini azalttığı, çekme direnciniartırdığı, arıtma çamurunun çekme direncini düşürdüğü ve arıtma çamurundabulunan liflerin ve lületaşı tozunun elastikiyet modülünü artırdığı tespitedilmiştir. Katkı maddeleri kompoziti daha gevrek hale getirerek kopmada uzamave eğilme direnci modülü değerlerini azaltmıştır. Eğilmede elastikiyet modülüdeğerleri ise arıma çamuru ve sepiyolit ilavesi ile artış göstermiştir. ÜretilenPP kompozitlerin tamamı ASTM D 6662’de istenilen değerlerden daha yüksek eğilmedirenci ve eğilmede elastikiyet modülü değerleri sağlamıştır. Bu çalışmanınsonuçları, günlük atılım miktarları çok yüksek olan arıtma çamuru, yumurtakabuğu ve lüle taşı gibi atık maddelerin “sıfır atık” yaklaşımı ile yenidendeğerlendirilmelerinin sağlayarak kompozit levha üretiminde kullanılabileceğinive ülke ekonomisi açısından faydalı malzeme üretiminingerçekleştirilebileceğini ortaya koymuştur.
KW  - Arıtma çamuru
KW  - Geri kazanım
KW  - Kompozit levha
KW  - Lüle taşı
KW  - Yumurta kabuğu
N2  - The aim of this study is to produce thermoplasticcomposite plates containing waste materials using additives such as industrialsewage sludge, eggshells and sepiolite, to determine the mechanical propertiesof these plates and to compare them with commercial polypropylene plates. Thesefillers were added to the polypropylene (PP) based composite in an amount of20-50% by weight (dry basis), and all composite plates were prepared using thehot compression molding method. Mechanical properties (tensile strength,tensile modulus of elasticity, flexural strength, elasticity of bendingcoefficient, elongation and impact strength at break) and radiationpermeability of composites were investigated and it was determined that fillertype had an effect on mechanical properties significantly. It was found thatthe addition of egg shells reduced the radiation permeability of the PP-basedcomposites and increased their tensile strength. Addition of sewage sludge tocomposite production decreased the tensile strength while, it caused toincrease elasticity modulus in flexure because of its fibrous structure withsepiolite. In the light of these results, it was determined that PP basedpolymer composites produced with waste additives provide sufficient mechanicalproperties than only PP based polymer composite plates.
CR  - Bajpai, P. (2015). Management of pulp and paper mill waste. In Management of Pulp and Paper Mill Waste. https://doi.org/10.1007/978-3-319-11788-1
CR  - Bootklad, M., & Kaewtatip, K. (2013). Biodegradation of thermoplastic starch/eggshell powder composites. Carbohydrate Polymers. https://doi.org/10.1016/j.carbpol.2013.05.030
CR  - Boumbimba, R. M., Wang, K., Hablot, E., Bahlouli, N., Ahzi, S., & Avérous, L. (2017). Renewable biocomposites based on cellulose fibers and dimer fatty acid polyamide: Experiments and modeling of the stress–strain behavior. Polymer Engineering and Science. https://doi.org/10.1002/pen.24390
CR  - Chan, C. M., Wu, J., Li, J. X., & Cheung, Y. K. (2002). Polypropylene/calcium carbonate nanocomposites. Polymer. https://doi.org/10.1016/S0032-3861(02)00120-9
CR  - Cho, Y. B., & Seo, G. (2010). High activity of acid-treated quail eggshell catalysts in the transesterification of palm oil with methanol. Bioresource Technology. https://doi.org/10.1016/j.biortech.2010.06.082
CR  - Deng, Q., Li, J., Yang, J., & Li, D. (2014). Optical and flexible α-chitin nanofibers reinforced poly(vinyl alcohol) (PVA) composite film: Fabrication and property. Composites Part A: Applied Science and Manufacturing. https://doi.org/10.1016/j.compositesa.2014.08.013
CR  - Gao, W., Ma, X., Liu, Y., Wang, Z., & Zhu, Y. (2013). Effect of calcium carbonate on PET physical properties and thermal stability. Powder Technology. https://doi.org/10.1016/j.powtec.2013.04.008
CR  - Glenn, G. M., Orts, W. J., & Nobes, G. A. R. (2001). Starch, fiber and CaCo3 effects on the physical properties of foams made by a baking process. Industrial Crops and Products. https://doi.org/10.1016/S0926-6690(01)00085-1
CR  - Hablot, E., Matadi, R., Ahzi, S., & Avérous, L. (2010). Renewable biocomposites of dimer fatty acid-based polyamides with cellulose fibres: Thermal, physical and mechanical properties. Composites Science and Technology. https://doi.org/10.1016/j.compscitech.2009.12.001
CR  - Islam, K. N., Bakar, M. Z. B. A., Noordin, M. M., Hussein, M. Z. Bin, Rahman, N. S. B. A., & Ali, M. E. (2011). Characterisation of calcium carbonate and its polymorphs from cockle shells (Anadara granosa). Powder Technology. https://doi.org/10.1016/j.powtec.2011.07.031
CR  - Ji, G., Zhu, H., Qi, C., & Zeng, M. (2009). Mechanism of interactions of eggshell microparticles with epoxy resins. Polymer Engineering and Science. https://doi.org/10.1002/pen.21339
CR  - Kargarzadeh, H., Huang, J., Lin, N., Ahmad, I., Mariano, M., Dufresne, A., … Gałęski, A. (2018). Recent developments in nanocellulose-based biodegradable polymers, thermoplastic polymers, and porous nanocomposites. Progress in Polymer Science. https://doi.org/10.1016/j.progpolymsci.2018.07.008
CR  - Klungsuwan, P., Jarerat, A., & Poompradub, S. (2013). Mechanical Properties and Biodegradability of Cuttlebone/NR Composites. Journal of Polymers and the Environment. https://doi.org/10.1007/s10924-012-0555-x
CR  - Liotier, P. J., Pucci, M. F., Le Duigou, A., Kervoelen, A., Tirilló, J., Sarasini, F., & Drapier, S. (2019). Role of interface formation versus fibres properties in the mechanical behaviour of bio-based composites manufactured by Liquid Composite Molding processes. Composites Part B: Engineering. https://doi.org/10.1016/j.compositesb.2018.10.103
CR  - Mahmood, T., & Elliott, A. (2006). A review of secondary sludge reduction technologies for the pulp and paper industry. Water Research. https://doi.org/10.1016/j.watres.2006.04.001
CR  - Matsuda, D. K. M., Verceheze, A. E. S., Carvalho, G. M., Yamashita, F., & Mali, S. (2013). Baked foams of cassava starch and organically modified nanoclays. Industrial Crops and Products. https://doi.org/10.1016/j.indcrop.2012.08.032
CR  - Mohamad, N., Latiff, A. A., Maulod, H. E. A., Azam, M. A., & Manaf, M. E. A. (2014). A Sustainable Polymer Composite from Recycled Polypropylene Filled with Shrimp Shell Waste. Polymer - Plastics Technology and Engineering. https://doi.org/10.1080/03602559.2013.843704
CR  - Nikolic, M. S., Petrovic, R., Veljovic, D., Cosovic, V., Stankovic, N., & Djonlagic, J. (2017). Effect of sepiolite organomodification on the performance of PCL/sepiolite nanocomposites. European Polymer Journal. https://doi.org/10.1016/j.eurpolymj.2017.10.010
CR  - Poompradub, S., Ikeda, Y., Kokubo, Y., & Shiono, T. (2008). Cuttlebone as reinforcing filler for natural rubber. European Polymer Journal. https://doi.org/10.1016/j.eurpolymj.2008.09.015
CR  - Pushpadass, H. A., Babu, G. S., Weber, R. W., & Hanna, M. A. (2008). Extrusion of starch-based loose-fill packaging foams#: Effects of temperature, moisture and talc on physical properties. Packaging Technology and Science. https://doi.org/10.1002/pts.809
CR  - Reulier, M., & Avérous, L. (2015). Elaboration, morphology and properties of renewable thermoplastics blends, based on polyamide and polyurethane synthesized from dimer fatty acids. European Polymer Journal. https://doi.org/10.1016/j.eurpolymj.2014.11.036
CR  - Reulier, M., Boumbimba, R. M., Rasselet, D., & Avérous, L. (2016). Renewable thermoplastic multiphase systems from dimer fatty acids, with mineral microfillers. Journal of Applied Polymer Science. https://doi.org/10.1002/app.43055
CR  - Son, J., Yang, H. S., & Kim, H. J. (2004). Physico-mechanical properties of paper sludge-thermoplastic polymer composites. Journal of Thermoplastic Composite Materials. https://doi.org/10.1177/0892705704038471
CR  - Tsai, W. T., Yang, J. M., Lai, C. W., Cheng, Y. H., Lin, C. C., & Yeh, C. W. (2006). Characterization and adsorption properties of eggshells and eggshell membrane. Bioresource Technology. https://doi.org/10.1016/j.biortech.2005.02.050
CR  - Yoo, S., Hsieh, J. S., Zou, P., & Kokoszka, J. (2009). Utilization of calcium carbonate particles from eggshell waste as coating pigments for ink-jet printing paper. Bioresource Technology. https://doi.org/10.1016/j.biortech.2009.06.112
CR  - Zhao, L., Zhang, Y., Miao, Y., & Nie, L. (2016). Controlled synthesis, characterization and application of hydrophobic calcium carbonate nanoparticles in PVC. Powder Technology. https://doi.org/10.1016/j.powtec.2015.11.001
UR  - https://doi.org/10.17780/ksujes.594973
L1  - https://dergipark.org.tr/en/download/article-file/858024
ER  -