TY  - JOUR
T1  - Synthesis, Investigation and X-Ray Powder Diffraction (XRD) of Some Oxadiazole Complexes
AU  - Ahmed Shaheen, Amerah Jihad
PY  - 2019
DA  - July
JF  - The Eurasia Proceedings of Science Technology Engineering and Mathematics
JO  - EPSTEM
PB  - ISRES Publishing
WT  - DergiPark
SN  - 2602-3199
SP  - 151
EP  - 161
VL  - 6
LA  - en
AB  - New ligand; 2-(1,1-dimethoxymethane) thio-5-(phenyl)-1,3,4-oxadiazole (L)(3) and its complexes with Mn(II), Fe(III),Co(II), Ni(II), Cd(II) and Zr(IV), have been synthesized and characterized onthe basis of physicochemical investigations including infrared and electronicspectroscopy,magnetic moment measurements, molar conductance and elementalanalysis. The structures of the compounds and some complexes have beeninvestigated by X-ray powder diffraction and H1NMR spectra. was recorded onbroker shield 300 MHz using deutrated DMSO-d6 as a solvent. for ligand. Theyhave been found to have the formula; [M L (H2O)3Cl]Cln; M= Mn(II ) n = 1, (4)and M=  Fe(III), n = 2  (5), [ML (H2O) Cl)] Cl , M=. Co(II) (7), Cd(II) (8)and [NiLCl2](6) ,[ZrOL(H2O)Cl2]Cl2 (9), in molar ratio 1:1. Infrared spectral data suggest that the ligandL: behaves as a, bidentate ligand with N,S, donor sequence towards the metalions. According to the above physicochemical data, octahedral and tetrahedralgeometries were assigned for the complexes.
KW  - Complexes
KW  - Oxadiazole
KW  - X-ray studies
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UR  - https://dergipark.org.tr/en/pub/epstem/issue//616948
L1  - https://dergipark.org.tr/en/download/article-file/802734
ER  -