TY  - JOUR
T1  - MISIR KOÇANINDA SÜLFÜRİK ASİT, HİDROJEN PEROKSİT VE ULTRASOUND ÖN İŞLEMLERİ İLE ÇÖZÜNMÜŞ ŞEKER ÜRETİMİNİN OPTİMİZASYONU
TT  - OPTIMIZATION OF SOLUBLE SUGAR PRODUCTION OF CORN COB BY SULFURIC ACID, HYDROGEN PEROXIDE AND ULTRASES DALGA PRETREATMENT
AU  - Deveci, Ece Ümmü
AU  - Gönen, Çağdaş
AU  - Çetin, Gözde
PY  - 2019
DA  - December
DO  - 10.17780/ksujes.645375
JF  - Kahramanmaraş Sütçü İmam Üniversitesi Mühendislik Bilimleri Dergisi
JO  - KSU J. Eng. Sci.
PB  - Kahramanmaras Sutcu Imam University
WT  - DergiPark
SN  - 1309-1751
SP  - 183
EP  - 198
VL  - 22
IS  - 4
LA  - tr
AB  - Bu çalışmada, Niğde ve çevre illerden teminedilen mısır koçanlarında, biyoyakıt potansiyelinin arttırılmasındafizikokimyasal (H2O2,H2O2+US, H2O2, H2O2+US) önişlemlerinetkisi belirlenmiştir. Uygulanan önişlemlerin optimizasyonu için istatistikimetot RSM (Response Surface Methods) Box-Behnken tasarımı kullanılmıştır.Tasarımda beklenen yanıtlar Toplam Şeker (TŞ) ve İndirgen Şeker (İŞ)konsantrasyonudur. Model sonuçlarına göre; H2SO4 önişlemi için 13,13 g/Lmaksimum TŞ, % 3 asit konsantrasyonu, 100 °C ve 180 dakika koşullarında;. 7,7g/L maksimum İŞ ise % 5 asit konsantrasyonu, 100 °C ve 180 dakikada eldeedilmiştir. H2SO4-US önişlemi için 10,72g/L g/L maksimum TŞ, % 3 asit konsantrasyonu, 100 kJ/kgDM US dozu ve 30 dakikakoşullarında; 3,16 g/L’ye maksimum İŞ ise % 4,24 asit konsantrasyonu, 100kJ/kgDM US dozu ve 27,7 dakikada elde edilmiştir. H2O2 önişleminde 1,70 g/L maksimum TŞ % 0,15 H2O2,0,38 mesh ve % 1,98 katı oranı koşullarında; 1,24 g/L’ye maksimum İŞ % 0,10 H2O2, 0,61 mesh ve % 2katı oranı koşullarında elde edilmiştir. H2O2-USönişlemi için 5,70 g/L maksimum TŞ % 1 H2O2,60 kJ/kgDM US dozu ve 5 dakika koşullarında;1,11 g/L maksimum İŞ % 0,1 H2O2,20 kJ/kgDM US dozu ve 17,5 dakika koşullarında elde edilmiştir. Çalışma sonucunda,lignoselülozik yapı çözünebilir yapıya dönüştürülmüştür.
KW  - Biyoyakıt Potansiyeli
KW  - Mısır Koçanı
KW  - İndirgen Şeker
KW  - Toplam şeker
N2  - In this study, the effect of physicochemical(H2SO4, H2SO4 + US, H2O2, H2O2+ US) pretreatments on increasing the biofuelpotential of corn cobs obtained from Niğde and surrounding provinces wasdetermined. The statistical method RSM (Response Surface Methods) Box-Behnkendesign was used to determine the optimization of the applied pretreatments. Theresponses used in the design are Total Sugar (TS) and Reducing Sugar (RS)concentration. According to model results; 13.13 g/L maximum TS was achieved3%acid concentration, 100 ° C and 180 min; maximum RS concentration of 7.7 g/Lwas achieved at 5 %acid concentration, 100°C and 180 min for H2SO4pretreatment. 10.72 g /L maximum TS was achieved 3%acid concentration, 100kJ/kg DM US dose and 30 min conditions; maximum RC concentration 3,16 g/L wasobtained that an acid concentration of 4.24%, a US dose of 100 kJ/kg DM, and27.7 minutes for H2O2-US pretreatment. 1.70 g/L maximum TS wasreach that 0.15%H2O2, 0.38 mesh and 1.98%solids conditions; 1.24g/L maximum was achieved under conditions of 0.10%H2O2, 0.61 mesh and 2%solids for H2O2pre-treatment. 5.70 g/L maximum TS was obtained undercondition 1%H2O2, 60 kJ/kg DM US dose and 5 min, 1.11 g/L maximum RCwas obtained under 0.1%H2O2, US dose of 20 kJ/kg DM and 17.5 minutes for H2O2-US pretreatment. As a result of this study, the lignocellulosicstructure was converted to soluble structure.
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UR  - https://doi.org/10.17780/ksujes.645375
L1  - https://dergipark.org.tr/en/download/article-file/907193
ER  -